Self-assembly of Hydrazide-based Heterodimers Driven by Hydrogen Bonding and Donor-Acceptor Interaction†

2006 ◽  
Vol 24 (9) ◽  
pp. 1200-1208 ◽  
Author(s):  
Dai-Jun Feng ◽  
Peng Wang ◽  
Xiao-Qiang Li ◽  
Zhan-Ting Li
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Acceptor Interaction ◽  
Donor Acceptor

scholarly journals {N 1-[2-(Butylselanyl)benzyl]-N 2,N 2-dimethylethane-1,2-diamine}dichloridomercury(II)

2018 ◽  
Vol 74 (8) ◽  
pp. 1151-1154
Author(s):  
Pushpendra Singh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly ◽  
Title Compound ◽  
Supramolecular Assembly ◽  
Molecular Geometry ◽  
The Self ◽  
Intermolecular Hydrogen Bonding ◽  
Hydrogen Bonding Interactions ◽  
Donor Acceptor

In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.

Donor–acceptor interaction-driven self-assembly of amphiphilic rod–coil molecules into supramolecular nanoassemblies

Nanoscale ◽  
2017 ◽  
Vol 9 (45) ◽  
pp. 17975-17982 ◽  
Author(s):  
Shengsheng Yu ◽  
Yuntian Yang ◽  
Tie Chen ◽  
Jingzhe Xu ◽  
Long Yi Jin
Keyword(s):  
Charge Transfer ◽  
Self Assembly ◽  
Acceptor Interaction ◽  
Donor Acceptor ◽  
Spherical Micelles

Pyrene-based amphiphiles self-assemble into nanofibers, spherical micelles and multilayer nanotubes. The addition of TNF allowed polymerization of these objects through charge-transfer interactions to form various supramolecular nanoassemblies.

Self-assembly of a new series of quadruply hydrogen bonded heterotrimers driven by the donor–acceptor interaction

Tetrahedron ◽  
2005 ◽  
Vol 61 (40) ◽  
pp. 9600-9610 ◽  
Author(s):  
Xiao-Qiang Li ◽  
Mu-Xin Jia ◽  
Xiao-Zhong Wang ◽  
Xi-Kui Jiang ◽  
Zhan-Ting Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
Acceptor Interaction ◽  
Donor Acceptor ◽  
Hydrogen Bonded

Self-assembly of fluorine-containing [2]catenanes based on donor–acceptor interaction

2000 ◽  
Vol 106 (2) ◽  
pp. 147-151 ◽  
Author(s):  
Cui-Qin Fan ◽  
Yi-Hua Yu ◽  
Yi Xia ◽  
Bo Tu ◽  
Zhan-Ting Li
Keyword(s):  
Self Assembly ◽  
Acceptor Interaction ◽  
Donor Acceptor

Supramolecular control of organic p/n-heterojunctions by complementary hydrogen bonding

2014 ◽  
Vol 174 ◽  
pp. 297-312 ◽  
Author(s):  
Hayden T. Black ◽  
Huaping Lin ◽  
Francine Bélanger-Gariépy ◽  
Dmitrii F. Perepichka
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Organic Semiconductors ◽  
Crystal Engineering ◽  
Self Assembly ◽  
Structural Control ◽  
Molecular Structures ◽  
Mutual Arrangement ◽  
Donor And Acceptor ◽  
Donor Acceptor

The supramolecular structure of organic semiconductors (OSCs) is the key parameter controlling their performance in organic electronic devices, and thus methods for controlling their self-assembly in the solid state are of the upmost importance. Recently, we have demonstrated the co-assembly of p- and n-type organic semiconductors through a three-point hydrogen-bonding interaction, utilizing an electron-rich dipyrrolopyridine (P2P) heterocycle which is complementary to naphthalenediimides (NDIs) both in its electronic structure and H bonding motif. The hydrogen-bonding-mediated co-assembly between P2P donor and NDI acceptor leads to ambipolar co-crystals and provides unique structural control over their solid-state packing characteristics. In this paper we expand our discussion on the crystal engineering aspects of H bonded donor–acceptor assemblies, reporting three new single co-crystal X-ray diffraction structures and analyzing the different packing characteristics that arise from the molecular structures employed. Particular attention is given toward understanding the formation of the two general motifs observed, segregated and mixed stacks. Co-assembly of the donor and acceptor components into a single, crystalline material, allows the creation of ambipolar semiconductors where the mutual arrangement of p- and n-conductive channels is engineered by supramolecular design based on complementary H bonding.

Self-assembly of a novel series of hetero-duplexes driven by donor–acceptor interaction

Tetrahedron ◽  
2005 ◽  
Vol 61 (30) ◽  
pp. 7117-7124 ◽  
Author(s):  
Qi-Zhong Zhou ◽  
Mu-Xin Jia ◽  
Xue-Bin Shao ◽  
Li-Zhu Wu ◽  
Xi-Kui Jiang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Acceptor Interaction ◽  
Donor Acceptor
Sign in / Sign up

Export Citation Format

Share Document