An Efficient Synthesis of 2-Oxazolidinones by Palladium- catalyzed Oxidative Carbonylation of β-Aminoalcohols and 2-Aminophenol under Mild Conditions

2005 ◽  
Vol 23 (5) ◽  
pp. 643-645 ◽  
Author(s):  
Li Fu-Wei ◽  
Peng Xin-Gao ◽  
Xia Chun-Gu ◽  
Hu Bin
Keyword(s):  
Oxidative Carbonylation ◽  
Efficient Synthesis ◽  
Mild Conditions ◽  
Palladium Catalyzed

scholarly journals Efficient Synthesis of Ureas by Direct Palladium-Catalyzed Oxidative Carbonylation of Amines.

ChemInform ◽  
2004 ◽  
Vol 35 (45) ◽  
Author(s):  
Bartolo Gabriele ◽  
Giuseppe Salerno ◽  
Raffaella Mancuso ◽  
Mirco Costa
Keyword(s):  
Oxidative Carbonylation ◽  
Efficient Synthesis ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Cross-Coupling of Gem-Bromofluoroalkenes with Alkylboronic Acids for the Synthesis of Alkylated Monofluoroalkenes

Molecules ◽  
2020 ◽  
Vol 25 (23) ◽  
pp. 5532
Author(s):  
Laëtitia Chausset-Boissarie ◽  
Nicolas Cheval ◽  
Christian Rolando
Keyword(s):  
Organic Synthesis ◽  
Functional Group ◽  
Materials Science ◽  
Cross Coupling ◽  
High Yield ◽  
Efficient Synthesis ◽  
Mild Conditions ◽  
Wide Range ◽  
Palladium Catalyzed ◽  
Novel Strategy

Monofluoroalkenes are versatile fluorinated synthons in organic synthesis, medicinal chemistry and materials science. In light of the importance of alkyl-substituted monofluoroalkenes efficient synthesis of these moieties still represents a synthetic challenge. Herein, we described a mild and efficient methodology to obtain monofluoroalkenes through a stereospecific palladium-catalyzed alkylation of gem-bromofluoroalkenes with primary and strained secondary alkylboronic acids under mild conditions. This novel strategy gives access to a wide range of functionalized tri- and tetrasubstituted monofluoroalkenes in high yield, with good functional group tolerance, independently from the gem-bromofluoroalkenes geometry.

Efficient Synthesis of Ureas by Direct Palladium-Catalyzed Oxidative Carbonylation of Amines

2004 ◽  
Vol 69 (14) ◽  
pp. 4741-4750 ◽  
Author(s):  
Bartolo Gabriele ◽  
Giuseppe Salerno ◽  
Raffaella Mancuso ◽  
Mirco Costa
Keyword(s):  
Oxidative Carbonylation ◽  
Efficient Synthesis ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Aerobic Oxidative Carbonylation of Arylboronate Esters under Mild Conditions.

ChemInform ◽  
2010 ◽  
Vol 41 (37) ◽  
pp. no-no
Author(s):  
Qiang Liu ◽  
Gang Li ◽  
Jun He ◽  
Jing Liu ◽  
Peng Li ◽  
...  
Keyword(s):  
Oxidative Carbonylation ◽  
Mild Conditions ◽  
Palladium Catalyzed

Palladium-Catalyzed Aerobic Oxidative Carbonylation of Arylboronate Esters under Mild Conditions

2010 ◽  
Vol 122 (19) ◽  
pp. 3443-3446 ◽  
Author(s):  
Qiang Liu ◽  
Gang Li ◽  
Jun He ◽  
Jing Liu ◽  
Peng Li ◽  
...  
Keyword(s):  
Oxidative Carbonylation ◽  
Mild Conditions ◽  
Palladium Catalyzed

Palladium-catalyzed oxidative carbonylation of hydrazides: synthesis of 1,3,4-oxadiazol-2(3H)-ones

2015 ◽  
Vol 51 (10) ◽  
pp. 1905-1907 ◽  
Author(s):  
Yu Wang ◽  
Xu Meng ◽  
Yuting Yang ◽  
Lutao Zhang ◽  
Shuaibo Guo ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Carbonyl Group ◽  
Intramolecular Cyclization ◽  
Oxidative Carbonylation ◽  
Amine Group ◽  
Mild Conditions ◽  
Carbonylation Reaction ◽  
Efficient Access ◽  
Wide Range ◽  
Palladium Catalyzed

A novel palladium-catalyzed oxidative carbonylation reaction was developed via the carbon monoxide insertions between the amine group and the carbonyl group to realize the intramolecular cyclization, which provides efficient access to 1,3,4-oxadiazol-2(3H)-ones with a wide range of substrates under mild conditions, resulting in good to excellent yields.

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