Relationship Between the Growth Rate of Forsterite Phase Transformation and Its Water Content: Implication for the Depth of Metastable Olivine

2012 ◽  
Vol 55 (2) ◽  
pp. 229-238 ◽  
Author(s):  
Shu-Guang WANG ◽  
Ya-Jing LIU ◽  
Jie-Yuan NING
Keyword(s):  
Growth Rate ◽  
Phase Transformation ◽  
Water Content ◽  
Metastable Olivine

scholarly journals Deep mantle melting, global water circulation and its implications for the stability of the ocean mass

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Shun-ichiro Karato ◽  
Bijaya Karki ◽  
Jeffrey Park
Keyword(s):  
Phase Transformation ◽  
Water Content ◽  
Sea Level ◽  
High Water ◽  
Water Circulation ◽  
Mantle Melting ◽  
High Water Content ◽  
Mineral Physics ◽  
Deep Mantle ◽  
Global Water

AbstractOceans on Earth are present as a result of dynamic equilibrium between degassing and regassing through the interaction with Earth’s interior. We review mineral physics, geophysical, and geochemical studies related to the global water circulation and conclude that the water content has a peak in the mantle transition zone (MTZ) with a value of 0.1–1 wt% (with large regional variations). When water-rich MTZ materials are transported out of the MTZ, partial melting occurs. Vertical direction of melt migration is determined by the density contrast between the melts and coexisting minerals. Because a density change associated with a phase transformation occurs sharply for a solid but more gradually for a melt, melts formed above the phase transformation depth are generally heavier than solids, whereas melts formed below the transformation depth are lighter than solids. Consequently, hydrous melts formed either above or below the MTZ return to the MTZ, maintaining its high water content. However, the MTZ water content cannot increase without limit. The melt-solid density contrast above the 410 km depends on the temperature. In cooler regions, melting will occur only in the presence of very water-rich materials. Melts produced in these regions have high water content and hence can be buoyant above the 410 km, removing water from the MTZ. Consequently, cooler regions of melting act as a water valve to maintain the water content of the MTZ near its threshold level (~ 0.1–1.0 wt%). Mass-balance considerations explain the observed near-constant sea-level despite large fluctuations over Earth history. Observations suggesting deep-mantle melting are reviewed including the presence of low-velocity anomalies just above and below the MTZ and geochemical evidence for hydrous melts formed in the MTZ. However, the interpretation of long-term sea-level change and the role of deep mantle melting in the global water circulation are non-unique and alternative models are reviewed. Possible future directions of studies on the global water circulation are proposed including geodynamic modeling, mineral physics and observational studies, and studies integrating results from different disciplines.

scholarly journals Solid Form and Phase Transformation Properties of Fexofenadine Hydrochloride during Wet Granulation Process

Pharmaceutics ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 802
Author(s):  
Suye Li ◽  
Hengqian Wu ◽  
Yanna Zhao ◽  
Ruiyan Zhang ◽  
Zhengping Wang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Phase Transformation ◽  
Water Content ◽  
Scale Up ◽  
Small Scale ◽  
Dissolution Behavior ◽  
Wet Granulation ◽  
Water Addition ◽  
Granulation Process ◽  
And Performance

The quality control of drug products during manufacturing processes is important, particularly the presence of different polymorphic forms in active pharmaceutical ingredients (APIs) during production, which could affect the performance of the formulated products. The objective of this study was to investigate the phase transformation of fexofenadine hydrochloride (FXD) and its influence on the quality and performance of the drug. Water addition was key controlling factor for the polymorphic conversion from Form I to Form II (hydrate) during the wet granulation process of FXD. Water-induced phase transformation of FXD was studied and quantified with XRD and thermal analysis. When FXD was mixed with water, it rapidly converted to Form II, while the conversion is retarded when FXD is formulated with excipients. In addition, the conversion was totally inhibited when the water content was <15% w/w. The relationship between phase transformation and water content was studied at the small scale, and it was also applicable for the scale-up during wet granulation. The effect of phase transition on the FXD tablet performance was investigated by evaluating granule characterization and dissolution behavior. It was shown that, during the transition, the dissolved FXD acted as a binder to improve the properties of granules, such as density and flowability. However, if the water was over added, it can lead to the incomplete release of the FXD during dissolution. In order to balance the quality attributes and the dissolution of granules, the phase transition of FXD and the water amount added should be controlled during wet granulation.

Water Stressed Nodal Roots of Wheat: Effects on Leaf Growth

1997 ◽  
Vol 24 (1) ◽  
pp. 49 ◽  
Author(s):  
K. M. Volkmar
Keyword(s):  
Growth Rate ◽  
Water Content ◽  
Relative Water Content ◽  
Leaf Growth ◽  
Seminal Root ◽  
Nodal Roots ◽  
Nodal Root ◽  
Relative Water ◽  
Seminal Roots ◽  
Leaf Relative Water Content

This experiment as undertaken to determine the efects of soil drying around the nodal and/or seminal root systems on the shoot growth of wheat (Triticum aestivum L.). Two split-root experiments were conducted, the first on newly emerged nodal roots of 18-day-old wheat plants, the second on 25-day-old plants. In both experiments, nodal and seminal roots were isolated from one another and water was withheld from either the nodal root chamber, the seminal root chamber, or both, over 6 days. In the first experiment, leaf growth was unaffected by withholding water from very short nodal roots, even though leaf relative water content of the droughted plants decreased. By comparison, both leaf elongation rate and relative water content decreased by withholding water from the seminal roots. On plants that were 1 week older, leaf growth rate and leaf relative water content decreased when nodal roots were drought-stressed. Leaf growth rate of seminal root droughted plants was more impaired than their nodal root counterparts, even though leaf relative water contents of the two treatments were the same. In both experiments, drought stress applied to the nodal root system enhanced nodal root growth more than seminal roots. These results suggest that seminal and nodal roots perceive and respond to drought stress differently with respect to the nature of the message conveyed to the shoots.

Experimental time constraints on the kinetic and chemistry of amphibole at deep crustal levels

2020 ◽  
Author(s):  
Barbara Bonechi ◽  
Cristina Perinelli ◽  
Mario Gaeta ◽  
Vanni Tecchiato ◽  
Alessandro Fabbrizio
Keyword(s):  
Growth Rate ◽  
Water Content ◽  
Growth Rates ◽  
Dwell Time ◽  
Current Knowledge ◽  
Campi Flegrei ◽  
Crystallization Time ◽  
Alkaline Basalt ◽  
Experimental Time ◽  
Lower Crustal

&lt;p&gt;Aiming to improve the current knowledge about amphibole growth kinetics at deep crustal levels, new amphibole growth rate data are provided. Our findings, indeed, may be useful to correctly interpret the textural features of amphibole-bearing mafic cumulates and rocks, and for a better constraining of the timescales of magmatic processes at upper mantle-lower crustal depths. Experiments were performed to determine the amphibole growth rates in a primitive alkaline basalt from Procida island (Campi Flegrei Volcanic District, southern Italy) at the following conditions: temperature of 1030 and 1080 &amp;#176;C, pressure of 0.8 GPa, water content in the range 3.3-4.2 wt%, and variable dwell time from 0.25 to 9 h. Amphibole growth rates range from 1.5&amp;#183;10&lt;sup&gt;-7&lt;/sup&gt; to 2.9&amp;#183;10&lt;sup&gt;-8&lt;/sup&gt; cm&amp;#183;s&lt;sup&gt;-1 &lt;/sup&gt;with increasing the duration of the experiments. It is observed that, keeping a constant dwell time, an increase of the experimental temperature or of the water content results in comparable growth rate increase. Coexisting synthetic amphibole and clinopyroxene show a faster growth rates in favour of amphibole regardless of the dwell time, since the chemical and structural similarities of these minerals cause kinetic competition. Moreover, the chemical composition of amphibole is influenced mainly by the experimental time; in detail, in the shortest (&amp;#8804;3 h) and low temperature runs edenite is the prevailing composition whereas the magnesiohastingsitic term becomes dominant at higher temperature and longer run duration. Based on the interpretation of the Fe-Mg exchange coefficient values between amphibole and coexisting liquid, the magnesiohastingsitic amphibole is considered to be the stable term at the investigated run conditions. Finally, the resulting growth rates have been applied to constrain the crystallization time of natural amphiboles and clinopyroxenes from the Oligo-Miocene cumulates of north-western Sardinia (i.e., Capo Marargiu &amp;#160;Volcanic District, Italy), yielding crystallization times in the range 1.46-3.12 yr.&lt;/p&gt;

Dependence of Dioscorea Tuber Growth Rate on Water Content of an Andept Soil

1980 ◽  
Vol 44 (6) ◽  
pp. 1298-1302 ◽  
Author(s):  
Ray F. Dawson ◽  
Jeffrey E. Shrum ◽  
Robert A. Mohammed
Keyword(s):  
Growth Rate ◽  
Water Content ◽  
Tuber Growth

Studies on Schistocephalus solidus

Parasitology ◽  
1965 ◽  
Vol 55 (2) ◽  
pp. 257-268 ◽  
Author(s):  
Morag L. O. McCaig ◽  
C. Adrian Hopkins
Keyword(s):  
Growth Rate ◽  
Water Content ◽  
Gasterosteus Aculeatus ◽  
Technical Assistance ◽  
Horse Serum ◽  
Electron Microscopic Examination ◽  
Dry Weight ◽  
Electron Microscopic ◽  
Schistocephalus Solidus

Schistocephalus plerocercoids in the weight range 2–200mg F.W. recovered from the perivisceral cavity of Gasterosteus aculeatus were cultured in various media. In a medium composed of 25% horse serum, 0·5% yeast extract, 0·65% glucose and Hanks's saline at pH 7·1, 21°C, 95% air +5% CO2, dry weight increases of up to 500% were recorded in 8 days. The specific growth rate of large plerocercoids was only one-tenth of the rate observed in small plerocercoids. A plerocercoid of double the weight of another had approximately half the specific growth rate.Worms after 8 days cultivation were found to have only slightly higher than normal glycogen and water content, and to be able to mature when heated to 40°C. However, the rate of growth slowed to zero by the 24th day in culture at 21°C. Electron microscopic examination showed a ‘deposit’ formed over the microvilli, thin at 8 days but dense after 21 days.The in vivo glycogen and water content of plerocercoids from 3–300 mg F.W. was determined. Glycogen rose from 24% in plerocercoids of 10mg F. W. to 50–55% in plerocercoids over 80mg F. W. The water content was found to mimic precisely this change, falling from 82% to a plateau of 67–69%.We wish to thank Professor Gareth Owen for permission to use the photograph shown in the Plate and for his help while using the electron microscope. It is also a pleasure to thank Miss Patricia Grant for her technical assistance.

Small Scale Sour Fatigue Testing With Dense Phase Gases

2012 ◽  
Author(s):  
Weiwei Yu ◽  
Pedro M. Vargas ◽  
Ben Crowder ◽  
Sam Mishael ◽  
Ramgopal Thodla
Keyword(s):  
Growth Rate ◽  
High Pressure ◽  
Water Content ◽  
Crack Growth ◽  
Growth Rates ◽  
Fatigue Performance ◽  
Small Scale ◽  
Dense Phase ◽  
High Crack ◽  
Crack Growth Rates

One way generally accepted by industry to evaluate the effect of sour environment on fatigue performance of girth welds is by small scale testing in sour brines. These tests are commonly done at room temperature and pressure and therefore can only contain a maximum of 14.7psia of H2S in a gaseous phase. In comparison, very little has been published about fatigue performance in sour environments where negligible amounts or no water is present. Such condition can be found for pipelines serving in a “dry” sour environment (H2S and other gases in dense phase) with high H2S concentration. This paper documents both small scale fatigue crack growth rate (FCGR) tests and S-N fatigue tests in a dense phase sour environment with ultra-low water content and high H2S concentration under high pressure. Fatigue life reduction factors were calculated from FCGR approach (with the name crack growth acceleration factor, CGAF) and S-N approach (with the name knockdown factor), respectively. Industry understanding today is that water is necessary for accelerating fatigue crack growth. Quite opposite to the expected effect of water content on crack growth, even ultra-low water content (<450ppm) resulted in high crack growth rates. Crack growth rates were comparable among tests with various water contents, all ultra low. Through limited testing, no temperature dependency on crack growth rate was identified. It is postulated that hydrogen dissociation due to high pressure and high concentration may be the cause for high crack growth rates on the absence of water. Small scale S-N tests on smooth specimens reveal that fatigue performance in ultra-low-water sour environments is the same as in air. We find that the dry gas environment dose not attack the metal surface preserving the fatigue performance.

Sign in / Sign up

Export Citation Format

Share Document