Intensification of carboxylic acid isolation from dilute aqueous feed by simultaneous conversion and liquid‐liquid extraction

2020 ◽  
Vol 92 (9) ◽  
pp. 1356-1356
Author(s):  
G. Rudelstorfer ◽  
A. Grafschafter ◽  
M. Siebenhofer
Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2277
Author(s):  
Piotr M. Kuś ◽  
Igor Jerković

Recently, we proposed a new sample preparation method involving reduced solvent and sample usage, based on dehydration homogeneous liquid–liquid extraction (DHLLE) for the screening of volatiles and semi-volatiles from honey. In the present research, the method was applied to a wide range of honeys (21 different representative unifloral samples) to determine its suitability for detecting characteristic honey compounds from different chemical classes. GC-FID/MS disclosed 130 compounds from different structural and chemical groups. The DHLLE method allowed the extraction and identification of a wide range of previously reported specific and nonspecific marker compounds belonging to different chemical groups (including monoterpenes, norisoprenoids, benzene derivatives, or nitrogen compounds). For example, DHLLE allowed the detection of cornflower honey chemical markers: 3-oxo-retro-α-ionols, 3,4-dihydro-3-oxoedulan, phenyllactic acid; coffee honey markers: theobromine and caffeine; linden honey markers: 4-isopropenylcyclohexa-1,3-diene-1-carboxylic acid and 4-(2-hydroxy-2-propanyl)cyclohexa-1,3-diene-1-carboxylic acid, as well as furan derivatives from buckwheat honey. The obtained results were comparable with the previously reported data on markers of various honey varieties. Considering the application of much lower volumes of very common reagents, DHLLE may provide economical and ecological advantages as an alternative sample preparation method for routine purposes.


2001 ◽  
Vol 89 (2) ◽  
Author(s):  
K. V. Chetty ◽  
V. Sagar ◽  
R. Swarup

Liquid-liquid extraction studies of plutonium and americium from aqueous carbonate medium using a high molecular weight carboxylic acid namely cekanoic acid in different diluents has been carried out. The distribution ratio (D) values for Pu(IV) and Am(III) under various parameters such as concentration of extractant, Na


Langmuir ◽  
2005 ◽  
Vol 21 (16) ◽  
pp. 7280-7284 ◽  
Author(s):  
Tatsuya Oshima ◽  
Hiroaki Higuchi ◽  
Keisuke Ohto ◽  
Katsutoshi Inoue ◽  
Masahiro Goto

2016 ◽  
Vol 164 ◽  
pp. 362-371 ◽  
Author(s):  
Rey Eliseo C. Torrejos ◽  
Grace M. Nisola ◽  
Ho Seong Song ◽  
Jeong Woo Han ◽  
Chosel P. Lawagon ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document