Dry Reforming and Reverse Water Gas Shift: Alternatives for Syngas Production?

2015 ◽  
Vol 87 (4) ◽  
pp. 347-353 ◽  
Author(s):  
Ekkehard Schwab ◽  
Andrian Milanov ◽  
Stephan Andreas Schunk ◽  
Axel Behrens ◽  
Nicole Schödel
Keyword(s):  
Dry Reforming ◽  
Water Gas Shift ◽  
Syngas Production ◽  
Reverse Water Gas Shift ◽  
Water Gas

scholarly journals Dry Reforming of Methane over CNT-Supported CeZrO2, Ni and Ni-CeZrO2 Catalysts

Catalysts ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 741
Author(s):  
Agata Łamacz ◽  
Paulina Jagódka ◽  
Michalina Stawowy ◽  
Krzysztof Matus
Keyword(s):  
Dry Reforming ◽  
Water Gas Shift ◽  
Dry Reforming Of Methane ◽  
Water Gas Shift Reaction ◽  
Catalyst Composition ◽  
Co2 Consumption ◽  
Reverse Water Gas Shift ◽  
Shift Reaction ◽  
Water Gas ◽  
First Time

In this work, the carbon nanotubes (CNT)-supported nanosized, well-dispersed, CeZrO2 and Ni-CeZrO2 catalysts were obtained and tested for the first time in the reaction of methane dry reforming (DRM). The performance of the hybrid materials was compared with the performance of Ni/CNT catalyst. The mechanism of the DRM reaction and the occurrence of reverse water gas shift reaction (RWGS) and CO2 deoxidation were discussed in terms of catalysts composition. The contribution of RWGS and CO2 deoxidation in the DRM process, demonstrating an increased CO2 consumption when compared to CH4, and H2/CO < 1, varied depending on the catalyst composition, was also studied.

CO2 green technologies in CO2 capture and direct utilization processes: methanation, reverse water-gas shift, and dry reforming of methane

2020 ◽  
Vol 4 (11) ◽  
pp. 5543-5549
Author(s):  
Seong Bin Jo ◽  
Jin Hyeok Woo ◽  
Jong Heon Lee ◽  
Tae Young Kim ◽  
Hu In Kang ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Dry Reforming ◽  
Water Gas Shift ◽  
Dry Reforming Of Methane ◽  
Green Technologies ◽  
Reverse Water Gas Shift ◽  
Water Gas

CO2 green technologies, such as methanation, reverse water-gas shift (rWGS), and dry reforming of methane (DRM) in CO2 capture and direct utilization process are developed using Ni/CaO catal-sorbents.

scholarly journals Versatile Ni-Ru catalysts for gas phase CO2 conversion: Bringing closer dry reforming, reverse water gas shift and methanation to enable end-products flexibility

Fuel ◽  
2022 ◽  
Vol 315 ◽  
pp. 123097
Author(s):  
Loukia-Pantzechroula Merkouri ◽  
Estelle le Saché ◽  
Laura Pastor-Pérez ◽  
Melis S. Duyar ◽  
Tomas Ramirez Reina
Keyword(s):  
Gas Phase ◽  
Dry Reforming ◽  
Water Gas Shift ◽  
Co2 Conversion ◽  
Ru Catalysts ◽  
Reverse Water Gas Shift ◽  
End Products ◽  
Water Gas

New approaches for Mars in-situ resource utilization based on the reverse water gas shift

1997 ◽  
Author(s):  
Robert Zubrin ◽  
Mitchell Clapp ◽  
Tom Meyer ◽  
Robert Zubrin ◽  
Mitchell Clapp ◽  
...  
Keyword(s):  
Resource Utilization ◽  
Water Gas Shift ◽  
New Approaches ◽  
Reverse Water Gas Shift ◽  
Water Gas

scholarly journals Production of Fuels and Chemicals from a CO2/H2 Mixture

Reactions ◽  
2020 ◽  
Vol 1 (2) ◽  
pp. 130-146
Author(s):  
Yali Yao ◽  
Baraka Celestin Sempuga ◽  
Xinying Liu ◽  
Diane Hildebrandt
Keyword(s):  
Co2 Hydrogenation ◽  
Water Gas Shift ◽  
Liquid Fuels ◽  
Saturated Hydrocarbons ◽  
Reverse Water Gas Shift ◽  
Cu Catalyst ◽  
In Series ◽  
Fuels And Chemicals ◽  
Water Gas ◽  
Aspen Simulation

In order to explore co-production alternatives, a once-through process for CO2 hydrogenation to chemicals and liquid fuels was investigated experimentally. In this approach, two different catalysts were considered; the first was a Cu-based catalyst that hydrogenates CO2 to methanol and CO and the second a Fisher–Tropsch (FT) Co-based catalyst. The two catalysts were loaded into different reactors and were initially operated separately. The experimental results show that: (1) the Cu catalyst was very active in both the methanol synthesis and reverse-water gas shift (R-WGS) reactions and these two reactions were restricted by thermodynamic equilibrium; this was also supported by an Aspen plus simulation of an (equilibrium) Gibbs reactor. The Aspen simulation results also indicated that the reactor can be operated adiabatically under certain conditions, given that the methanol reaction is exothermic and R-WGS is endothermic. (2) the FT catalyst produced mainly CH4 and short chain saturated hydrocarbons when the feed was CO2/H2. When the two reactors were coupled in series and the presence of CO in the tail gas from the first reactor (loaded with Cu catalyst) significantly improves the FT product selectivity toward higher carbon hydrocarbons in the second reactor compared to the standalone FT reactor with only CO2/H2 in the feed.

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