Asymmetric transfer hydrogenation of prochiral ketones in aqueous media with chiral water-soluble and heterogenized bifunctional catalysts of the RhCp*-type ligand

Chirality ◽  
2010 ◽  
Vol 23 (2) ◽  
pp. 178-184 ◽  
Author(s):  
Angélica Barrón-Jaime ◽  
Oscar F. Narvaez-Garayzar ◽  
Jorge González ◽  
Valentín Ibarra-Galván ◽  
Gerardo Aguirre ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Water Soluble ◽  
Transfer Hydrogenation ◽  
Bifunctional Catalysts ◽  
Asymmetric Transfer Hydrogenation ◽  
Prochiral Ketones

Surfactant-accelerated asymmetric transfer hydrogenation with recyclable water-soluble catalyst in aqueous media

RSC Advances ◽  
2013 ◽  
Vol 3 (6) ◽  
pp. 1825-1834 ◽  
Author(s):  
Jiahong Li ◽  
Xuefeng Li ◽  
Yaping Ma ◽  
Jiashou Wu ◽  
Fei Wang ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Water Soluble ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

scholarly journals Asymmetric transfer hydrogenation of prochiral ketones catalyzed by aminosulfonamide-ruthenium complexes in ionic liquid

2011 ◽  
Vol 9 (1) ◽  
pp. 175-179 ◽  
Author(s):  
Zhongqiang Zhou ◽  
Yong Sun ◽  
Aiqing Zhang
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Prochiral Ketones

AbstractChiral aminosulfonamides containing imidazolium group were used as ligands for the ruthenium(II)-catalyzed asymmetric transfer hydrogenation of prochiral ketones in ionic liquid, affording good to excellent conversions and enantiomeric excesses. The catalytic system could be easily recovered and reused several times.

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