ChemInform Abstract: Hydrogen Bond-Assisted Crystallization: Structure, Growth and Characterization of a New Mixed-Anion Transition Metal Fluoride Na3 NH4 (TiF6 ) (SO4 )·H2 O.

ChemInform ◽  
2016 ◽  
Vol 47 (47) ◽  
Author(s):  
Dongdong Xu ◽  
Fangfang Zhang ◽  
Yanzhou Sun ◽  
Zhihua Yang ◽  
Xiaoyu Dong ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Metal Fluoride ◽  
Crystallization Structure

Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na3NH4(TiF6)(SO4)·H2O

2016 ◽  
Vol 40 (9) ◽  
pp. 7407-7413 ◽  
Author(s):  
Dongdong Xu ◽  
Fangfang Zhang ◽  
Yanzhou Sun ◽  
Zhihua Yang ◽  
Xiaoyu Dong ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Hydrothermal Method ◽  
Metal Fluoride ◽  
Facile Hydrothermal Method ◽  
New Type ◽  
Crystallization Structure

A new type of mixed-anion TM fluoride was grown with a size up to 5.0 × 2.5 × 1.0 mm3 by a facile hydrothermal method.

Synthesis and physical characterization of new d-transition metal fluoride GICSs

1991 ◽  
Vol 54 (1-3) ◽  
pp. 416
Author(s):  
A. Tressaud ◽  
K. Amine ◽  
J. Grannec ◽  
S. Mayorga
Keyword(s):  
Transition Metal ◽  
Physical Characterization ◽  
Metal Fluoride

Synthesis and Physical Characterization of New d-Transition Metal Fluoride/GICs

1992 ◽  
Vol 91-93 ◽  
pp. 62-62
Author(s):  
A. Tressaud ◽  
K. Amine ◽  
J. Grannec ◽  
S. Mayorga
Keyword(s):  
Transition Metal ◽  
Physical Characterization ◽  
Metal Fluoride

Catalytic Fluorination of Boron Compounds at a Bismuth Redox Platform

2019 ◽  
Author(s):  
Oriol Planas ◽  
Feng Wang ◽  
Markus Leutzsch ◽  
Josep Cornella
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Group Element ◽  
Oxidation States ◽  
Boron Compounds ◽  
Main Text ◽  
Main Group Element ◽  
Rational Ligand Design ◽  
Supplementary Material

The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mimicking the canonical organometallic steps associated to a transition metal, is an elusive and unprecedented approach in the field of homogeneous catalysis. Herein we present a catalytic protocol based on bismuth, a benign and sustainable main-group element, capable of performing every organometallic step in the context of oxidative fluorination of boron compounds; a territory reserved to transition metals. A rational ligand design featuring hypervalent coordination together with a mechanistic understanding of the fundamental steps, permitted a catalytic fluorination protocol based on a Bi(III)/Bi(V) redox couple, which represents a unique example where a main-group element is capable of outperforming its transition metal counterparts.<br>A main text and supplementary material have been attached as pdf files containing all the methodology, techniques and characterization of the compounds reported.<br>

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