ChemInform Abstract: Synthesis of Thiophenes in a Deep Eutectic Solvent: Heterocyclodehydration and Iodocyclization of 1-Mercapto-3-yn-2-ols in a Choline Chloride/Glycerol Medium.

ChemInform ◽  
2016 ◽  
Vol 47 (43) ◽  
Author(s):  
Raffaella Mancuso ◽  
Asif Maner ◽  
Luciana Cicco ◽  
Filippo M. Perna ◽  
Vito Capriati ◽  
...  
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Glycerol Medium

Synthesis of thiophenes in a deep eutectic solvent: heterocyclodehydration and iodocyclization of 1-mercapto-3-yn-2-ols in a choline chloride/glycerol medium

Tetrahedron ◽  
2016 ◽  
Vol 72 (29) ◽  
pp. 4239-4244 ◽  
Author(s):  
Raffaella Mancuso ◽  
Asif Maner ◽  
Luciana Cicco ◽  
Filippo M. Perna ◽  
Vito Capriati ◽  
...  
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Glycerol Medium

Silver nanoparticles synthesized by laser ablation confined in urea choline chloride deep-eutectic solvent

2016 ◽  
Vol 12 ◽  
pp. 1-4 ◽  
Author(s):  
David O. Oseguera-Galindo ◽  
Roberto Machorro-Mejia ◽  
Nina Bogdanchikova ◽  
Josue D. Mota-Morales
Keyword(s):  
Silver Nanoparticles ◽  
Laser Ablation ◽  
Choline Chloride ◽  
Deep Eutectic Solvent

A Utilization of Choline Chloride-Based Deep Eutectic Solvent Integrated with Alkaline Earth Metal Hexahydrate in the Pretreatment of Oil Palm Fronds

2021 ◽  
Vol 60 (5) ◽  
pp. 2011-2026
Author(s):  
Eng Kein New ◽  
Ta Yeong Wu ◽  
Khai Shing Voon ◽  
Alessandra Procentese ◽  
Katrina Pui Yee Shak ◽  
...  
Keyword(s):  
Oil Palm ◽  
Alkaline Earth ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Oil Palm Fronds ◽  
Palm Fronds

scholarly journals Comparison of Corn Stover Pretreatments with Lewis Acid Catalyzed Choline Chloride, Glycerol and Choline Chloride-Glycerol Deep Eutectic Solvent

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1170
Author(s):  
Yuan Zhu ◽  
Benkun Qi ◽  
Xinquan Liang ◽  
Jianquan Luo ◽  
Yinhua Wan
Keyword(s):  
Corn Stover ◽  
Lewis Acid ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Enzymatic Saccharification ◽  
Glycerol Solution ◽  
Cellulose Conversion ◽  
Biomass Processing ◽  
Acid Catalyzed ◽  
Highly Correlated

Herein, corn stover (CS) was pretreated by less corrosive lewis acid FeCl3 acidified solutions of neat and aqueous deep eutectic solvent (DES), aqueous ChCl and glycerol at 120 °C for 4 h with single FeCl3 pretreatment as control. It was unexpected that acidified solutions of both ChCl and glycerol were found to be more efficient at removing lignin and xylan, leading to higher enzymatic digestibility of pretreated CS than acidified DES. Comparatively, acidified ChCl solution exhibited better pretreatment performance than acidified glycerol solution. In addition, 20 wt% water in DES dramatically reduced the capability of DES for delignification and xylan removal and subsequent enzymatic cellulose saccharification of pretreated CS. Correlation analysis showed that enzymatic saccharification of pretreated CS was highly correlated to delignification and cellulose crystallinity, but lowly correlated to xylan removal. Recyclability experiments of different acidified pretreatment solutions showed progressive decrease in the pretreatment performance with increasing recycling runs. After four cycles, the smallest decrease in enzymatic cellulose conversion (22.07%) was observed from acidified neat DES pretreatment, while the largest decrease (43.80%) was from acidified ChCl pretreatment. Those findings would provide useful information for biomass processing with ChCl, glycerol and ChCl-glycerol DES.

scholarly journals Esterification of Lignin Isolated by Deep Eutectic Solvent Using Fatty Acid Chloride, and Its Composite Film with Poly(lactic acid)

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2149
Author(s):  
Chan-Woo Park ◽  
Song-Yi Han ◽  
Rajkumar Bandi ◽  
Ramakrishna Dadigala ◽  
Eun-Ah Lee ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Fatty Acid ◽  
Composite Film ◽  
Acid Chloride ◽  
Pinus Densiflora ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Morphological Characteristics ◽  
Poly Lactic Acid ◽  
Fatty Acid Chloride

In this study, the effect of lignin esterification with fatty acid chloride on the properties of lignin and lignin/poly(lactic acid) (PLA) composites was investigated. Lignocellulose (Pinus densiflora S. et Z.) was treated using a deep eutectic solvent (DES) with choline chloride (ChCl)/lactic acid (LA). From the DES-soluble fraction, DES-lignin (DL) was isolated by a regeneration process. Lignin esterification was conducted with palmitoyl chloride (PC). As the PC loading increased for DL esterification, the Mw of esterified DL (EDL) was increased, and the glass transition temperature (Tg) was decreased. In DL or EDL/PLA composite films, it was observed that EDL/PLA had cleaner and smoother morphological characteristics than DL/PLA. The addition of DL or EDL in a PLA matrix resulted in a deterioration of tensile properties as compared with neat PLA. The EDL/PLA composite film had a higher tensile strength and elastic modulus than the DL/PLA composite film. DL esterification decreased water absorption with lower water diffusion coefficients. The effect of lignin esterification on improving the compatibility of lignin and PLA was demonstrated. These results are expected to contribute to the development of high-strength lignin composites.

Toxico-metabolomics study of a deep eutectic solvent comprising choline chloride and urea suggests in vivo toxicity involving oxidative stress and ammonia stress

2021 ◽  
Vol 23 (3) ◽  
pp. 1300-1311 ◽  
Author(s):  
Dasom Jung ◽  
Jae Back Jung ◽  
Seulgi Kang ◽  
Ke Li ◽  
Inseon Hwang ◽  
...  
Keyword(s):  
Oxidative Stress ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Deep Eutectic Solvents ◽  
In Vivo Toxicity ◽  
Metabolomics Study ◽  
Ammonia Stress

The in vitro and in vivo studies suggest that choline chloride-based deep eutectic solvents may not be considered as pure, safe mixtures even if they consist of safe compounds.

Cellulose nanocrystalline hydrogel based on a choline chloride deep eutectic solvent as wearable strain sensor for human motion

2021 ◽  
Vol 255 ◽  
pp. 117443
Author(s):  
Huiqiang Wang ◽  
Jiachen Li ◽  
Xin Yu ◽  
Guihua Yan ◽  
Xing Tang ◽  
...  
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Strain Sensor ◽  
Human Motion

scholarly journals Cold‐spray ionization mass spectrometry of the choline chloride‐urea deep eutectic solvent (reline)

2021 ◽  
Vol 56 (5) ◽  
Author(s):  
Lucie Percevault ◽  
Thomas Delhaye ◽  
Alain Chaumont ◽  
Rachel Schurhammer ◽  
Ludovic Paquin ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Cold Spray ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Ionization Mass Spectrometry ◽  
Ionization Mass

scholarly journals Deep Eutectic Solvents Based Choline Chloride for Enzymatic Biodiesel Production from Degumming Palm Oil

2020 ◽  
Vol 32 (4) ◽  
pp. 733-738 ◽  
Author(s):  
R. Manurung ◽  
Taslim ◽  
A.G.A. Siregar
Keyword(s):  
Palm Oil ◽  
Raw Materials ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Deep Eutectic Solvents ◽  
Biodiesel Production ◽  
Chloride Salt ◽  
Enzymatic Reactions ◽  
Potential Applications ◽  
Palm Oil Biodiesel

Deep eutectic solvents (DESs) have numerous potential applications as cosolvents. In this study, use of DES as organic solvents for enzymatic biodiesel production from degumming palm oil (DPO) was investigated. Deep eutectic solvent was synthesized using choline chloride salt (ChCl) compounds with glycerol and 1,2-propanediol. Deep eutectic solvent was characterized by viscosity, density, pH and freezing values, which were tested for effectiveness by enzymatic reactions for the production of palm biodiesel with raw materials DPO. Deep eutectic solvent of ChCl and glycerol produced the highest biodiesel yield (98.98%); weight of DES was only 0.5 % of that of the oil. In addition, the use of DES maintained the activity and stability of novozym enzymes, which was assessed as the yield until the 6th usage, which was 95.07 % biodiesel yield compared with the yield without using DES. Hence, using DES, glycerol in enzymatic biodiesel production had high potentiality as an organic solvent for palm oil biodiesel production

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