ChemInform Abstract: Marriage of Heavy Main Group Elements with π-Conjugated Materials for Optoelectronic Applications

ChemInform ◽  
2016 ◽  
Vol 47 (37) ◽  
Author(s):  
Sarah M. Parke ◽  
Michael P. Boone ◽  
Eric Rivard
Keyword(s):  
Main Group ◽  
Conjugated Materials ◽  
Main Group Elements ◽  
Optoelectronic Applications

Marriage of heavy main group elements with π-conjugated materials for optoelectronic applications

2016 ◽  
Vol 52 (61) ◽  
pp. 9485-9505 ◽  
Author(s):  
Sarah M. Parke ◽  
Michael P. Boone ◽  
Eric Rivard
Keyword(s):  
Recent Work ◽  
Main Group ◽  
The Novel ◽  
Inorganic Elements ◽  
Conjugated Materials ◽  
Main Group Elements ◽  
Optoelectronic Applications

This review showcases recent work devoted to placing heavy inorganic elements within π-conjugated frameworks and the novel properties that can arise.

Ladder π-Conjugated Materials with Main Group Elements

ChemInform ◽  
2006 ◽  
Vol 37 (36) ◽  
Author(s):  
Shigehiro Yamaguchi ◽  
Caihong Xu ◽  
Toshihiro Okamoto
Keyword(s):  
Main Group ◽  
Conjugated Materials ◽  
Main Group Elements

Ladder π-Conjugated Materials Containing Main-Group Elements

2009 ◽  
Vol 4 (9) ◽  
pp. 1386-1400 ◽  
Author(s):  
Aiko Fukazawa ◽  
Shigehiro Yamaguchi
Keyword(s):  
Main Group ◽  
Conjugated Materials ◽  
Main Group Elements

F Perfluorohalogenoorgano Compounds of Main Group Elements

1987 ◽  
Author(s):  
Alois Haas ◽  
Dieter Koschel ◽  
Ulrich Niemann
Keyword(s):  
Main Group ◽  
Main Group Elements

To Bend or Not to Bend, the Dilemma of Multiple Bonds

2019 ◽  
Author(s):  
Michele Pizzocchero ◽  
Matteo Bonfanti ◽  
Rocco Martinazzo
Keyword(s):  
First Principles ◽  
2D Materials ◽  
Main Group ◽  
First Principles Calculations ◽  
Group 14 ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
Structural Distortions

The manuscript addresses the issue of the structural distortions occurring at multiple bonds between high main group elements, focusing on group 14. These distortions are known as trans-bending in silenes, disilenes and higher group analogues, and buckling in 2D materials likes silicene and germanene. A simple but correlated \sigma + \pi model is developed and validated with first-principles calculations, and used to explain the different behaviour of second- and higher- row elements.

The use of main-group elements to mimic catalytic behavior of transition metals I: reduction of dinitrogen to ammonia catalyzed by bis(Lewis base)borylenium diradicals

2020 ◽  
Vol 22 (48) ◽  
pp. 28423-28433
Author(s):  
Yu Wang ◽  
Chun-Guang Liu
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Lewis Base ◽  
Main Group Elements ◽  
Catalytic Behavior ◽  
Metal Free

An emerging class of compounds, bis(Lewis base)borylenium diradicals with an electron-rich boron(i) center, are potential metal-free catalysts for dinitrogen activation and reduction.

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