ChemInform Abstract: Advances in Transition-Metal Catalyzed Thioetherification Reactions of Aromatic Compounds

ChemInform ◽  
2016 ◽  
Vol 47 (37) ◽  
Author(s):  
Arash Ghaderi
Keyword(s):  
Transition Metal ◽  
Aromatic Compounds ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition metal catalyzed meta-C–H functionalization of aromatic compounds

2015 ◽  
Vol 13 (7) ◽  
pp. 1930-1941 ◽  
Author(s):  
Jiong Yang
Keyword(s):  
Transition Metal ◽  
Aromatic Compounds ◽  
Synthetic Methods ◽  
Directing Group ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes synthetic methods for directing group guided, transition metal catalyzed meta-C–H functionalization of aromatic compounds.

scholarly journals Recent Progress in Transition Metal Catalyzed Sulfonamidation of Aromatic Compounds

2020 ◽  
Vol 40 (5) ◽  
pp. 1188
Author(s):  
Banlai Ouyang ◽  
Yanxia Zheng ◽  
Kejian Xia ◽  
Xiaoling Xu ◽  
Yi Wang
Keyword(s):  
Transition Metal ◽  
Aromatic Compounds ◽  
Recent Progress ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

Monodentate Trialkylphosphines: Privileged Ligands in Metal-catalyzed Crosscoupling Reactions

2020 ◽  
Vol 24 (3) ◽  
pp. 231-264 ◽  
Author(s):  
Kevin H. Shaughnessy
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Aryl Bromides ◽  
Wide Range ◽  
Sterically Demanding ◽  
Transition Metal Catalyzed ◽  
Catalyzed Reactions ◽  
Metal Catalyzed

Phosphines are widely used ligands in transition metal-catalyzed reactions. Arylphosphines, such as triphenylphosphine, were among the first phosphines to show broad utility in catalysis. Beginning in the late 1990s, sterically demanding and electronrich trialkylphosphines began to receive attention as supporting ligands. These ligands were found to be particularly effective at promoting oxidative addition in cross-coupling of aryl halides. With electron-rich, sterically demanding ligands, such as tri-tertbutylphosphine, coupling of aryl bromides could be achieved at room temperature. More importantly, the less reactive, but more broadly available, aryl chlorides became accessible substrates. Tri-tert-butylphosphine has become a privileged ligand that has found application in a wide range of late transition-metal catalyzed coupling reactions. This success has led to the use of numerous monodentate trialkylphosphines in cross-coupling reactions. This review will discuss the general properties and features of monodentate trialkylphosphines and their application in cross-coupling reactions of C–X and C–H bonds.

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