ChemInform Abstract: New Mechanistic Insights on the Selectivity of Transition-Metal-Catalyzed Organic Reactions: The Role of Computational Chemistry

ChemInform ◽  
2016 ◽  
Vol 47 (33) ◽  
Author(s):  
Xinhao Zhang ◽  
Lung Wa Chung ◽  
Yun-Dong Wu
Keyword(s):  
Transition Metal ◽  
Computational Chemistry ◽  
Organic Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Transition metal-catalyzed organic reactions in undivided electrochemical cells

2021 ◽  
Author(s):  
Cong Ma ◽  
Ping Fang ◽  
Dong Liu ◽  
Ke-Jin Jiao ◽  
Pei-Sen Gao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Research Area ◽  
Metal Catalysts ◽  
Organic Reactions ◽  
Electrochemical Cells ◽  
Organic Electrochemistry ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Abstract: Transition metal-catalyzed organic electrochemistry is a rapidly growing research area owing in part of the ability of metal catalysts to alter the selectivity of a given transformation. This conversion...

DESs: Green solvents for transition metal catalyzed organic reactions

2019 ◽  
Vol 30 (12) ◽  
pp. 2151-2156 ◽  
Author(s):  
Lifen Peng ◽  
Zhifang Hu ◽  
Qichao Lu ◽  
Zilong Tang ◽  
Yinchun Jiao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Organic Reactions ◽  
Green Solvents ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Non-Classical Anionic Naked N-Heterocyclic Carbenes: Fundamental Properties and Emerging Applications in Synthesis and Catalysis

Catalysts ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 620 ◽  
Author(s):  
Mei Leow ◽  
Curtis Ho ◽  
Michael Gardiner ◽  
Alex Bissember
Keyword(s):  
Transition Metal ◽  
Heterocyclic Carbenes ◽  
Molecular Scaffolds ◽  
Ongoing Research ◽  
Fundamental Properties ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Ongoing research exploring the chemistry of N-heterocyclic carbenes (NHCs) has led to the development and discovery of new NHC subclasses that deviate beyond Arduengo’s prototypical N,N′-disubstituted imidazol-2-ylidene-based structures. These systems continue to enable and extend the fundamental role of NHC ligands in synthesis and catalysis. In this regard, the advent of protic NHCs has garnered particular interest. This derives in part from their applications to the selective preparation of unique molecular scaffolds and their unprecedented bifunctional reactivity, which can be exploited in transition metal-catalyzed processes. In comparison, the synthetic applications of closely related anionic naked NHCs remain rather underexplored. With this in mind, this review highlights the interesting fundamental properties of non-classical anionic naked NHCs, and focuses on their emerging applications in synthesis and catalysis.

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