ChemInform Abstract: Ligand-Controlled Monoselective C-Aryl Glycoside Synthesis via Palladium-Catalyzed C-H Functionalization of N-Quinolyl Benzamides with 1-Iodoglycals.

ChemInform ◽  
2016 ◽  
Vol 47 (33) ◽  
Author(s):  
Minglong Liu ◽  
Youhong Niu ◽  
Yan-Fen Wu ◽  
Xin-Shan Ye
Keyword(s):  
Glycoside Synthesis ◽  
Palladium Catalyzed ◽  
Aryl Glycoside

C-Glycoside synthesis by palladium-catalyzed iodoaglycon-glycal coupling

1990 ◽  
Vol 9 (12) ◽  
pp. 3151-3156 ◽  
Author(s):  
Roger N. Farr ◽  
Robert A. Outten ◽  
Jane Chi Ya Cheng ◽  
G. Doyle Daves
Keyword(s):  
Glycoside Synthesis ◽  
Palladium Catalyzed

scholarly journals Unified strategy for the synthesis of C-aryl glycosides

2003 ◽  
Vol 75 (1) ◽  
pp. 63-70 ◽  
Author(s):  
S. F. Martin
Keyword(s):  
Unified Approach ◽  
Formal Synthesis ◽  
Palladium Catalyzed ◽  
Acid Catalyzed ◽  
Integrated Approaches ◽  
Aryl Glycosides ◽  
Aryl Glycoside

A unified approach for the synthesis of the four major groups of C-aryl glycosides has been developed. The strategy incorporates two integrated approaches, the first of which features the [4+2] cycloaddition of a glycosyl furan with a substituted benzyne followed by the acid-catalyzed opening of the resultant adduct. The second route involves the sequential palladium-catalyzed opening of a benzyne-furan cycloadduct with an iodo glycal followed by oxidation of the resultant dihydronaphthol ring and reduction of the glycal moiety. The utility of this strategy has been established by a concise formal synthesis of the C-aryl glycoside antibiotic galtamycinone.

Rhodium-Catalyzed Alkyne Cyclotrimerization Strategies for C-Aryl Glycoside Synthesis

1995 ◽  
Vol 117 (24) ◽  
pp. 6605-6606 ◽  
Author(s):  
Frank E. McDonald ◽  
Hugh Y. H. Zhu ◽  
Christopher R. Holmquist
Keyword(s):  
Glycoside Synthesis ◽  
Aryl Glycoside

ChemInform Abstract: C-Glycoside Synthesis by Palladium-Catalyzed Iodoaglycon-Glycal Coupling.

ChemInform ◽  
2010 ◽  
Vol 22 (13) ◽  
pp. no-no
Author(s):  
R. N. FARR ◽  
R. A. OUTTEN ◽  
J. C.-Y. CHENG ◽  
G. D. JUN. DAVES
Keyword(s):  
Glycoside Synthesis ◽  
Palladium Catalyzed

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

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