ChemInform Abstract: Cationic Pd(II)-Catalyzed C-H Activation/Cross-Coupling Reactions at Room Temperature: Synthetic and Mechanistic Studies.

ChemInform ◽  
2016 ◽  
Vol 47 (31) ◽  
Author(s):  
Takashi Nishikata ◽  
Alexander R Abela ◽  
Shenlin Huang ◽  
Bruce H Lipshutz
Keyword(s):  
Room Temperature ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Mechanistic Studies ◽  
Cross Coupling Reactions

Conjugated Polymer Nanoparticles by Suzuki–Miyaura Cross-Coupling Reactions in an Emulsion at Room Temperature

2014 ◽  
Vol 47 (19) ◽  
pp. 6531-6539 ◽  
Author(s):  
Duangratchaneekorn Muenmart ◽  
Andrew B. Foster ◽  
Alan Harvey ◽  
Ming-Tsz Chen ◽  
Oscar Navarro ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Room Temperature ◽  
Cross Coupling ◽  
Polymer Nanoparticles ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Conjugated Polymer Nanoparticles

ChemInform Abstract: Pd(OAc)2in WERSA: A Novel Green Catalytic System for Suzuki-Miyaura Cross-Coupling Reactions at Room Temperature.

ChemInform ◽  
2015 ◽  
Vol 46 (47) ◽  
pp. no-no
Author(s):  
Preeti Rekha Boruah ◽  
Abdul Aziz Ali ◽  
Mitali Chetia ◽  
Bishwajit Saikia ◽  
Diganta Sarma
Keyword(s):  
Catalytic System ◽  
Room Temperature ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Protocol for Palladium/N-Heterocyclic Carbene-Catalyzed Suzuki–Miyaura Cross-Coupling of Amides by N–C(O) Activation

Synthesis ◽  
2020 ◽  
Author(s):  
Peng Lei ◽  
Guangchen Li ◽  
Michal Szostak ◽  
Yun Ling ◽  
Jie An ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
Room Temperature ◽  
Bond Activation ◽  
Process Development ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Amide Bonds ◽  
Cross Coupling Reactions ◽  
Synthetic Procedure ◽  
Operational Simplicity

AbstractAmides are among the most important and ubiquitous functional groups in organic chemistry and process development. In this Practical Synthetic Procedure, a protocol for the Suzuki–Miyaura cross-coupling of amides by selective N–C(O) bond activation catalyzed by commercially available, air- and moisture-stable palladium/N-heterocyclic carbene (NHC) complexes is described. The procedure described involves [Pd(IPr)(cin)Cl] [IPr = 2,6-(diisopropylphenyl)imidazol-2-ylidene, cin = cinnamyl] at 0.10 mol% at room temperature and is performed on decagram scale. Furthermore, a procedure for the synthesis of amide starting materials is accomplished via selective N-tert-butoxycarbonylation, which is the preferred method over N-acylation. The present protocol carries advantages of operational simplicity, commercial availability of catalysts, and excellent conversions at low catalyst loadings. The method is generally useful for activation of N–C(O) amide bonds in a broad spectrum of amide precursors. The protocol should facilitate the implementation of amide cross-coupling reactions.

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