ChemInform Abstract: Molecular Switching Involving Metastable States: Molecular Thermal Hysteresis and Sensing of Environmental Changes by Chiral Helicene Oligomeric Foldamers

ChemInform ◽  
2016 ◽  
Vol 47 (20) ◽  
Author(s):  
Masanori Shigeno ◽  
Yo Kushida ◽  
Masahiko Yamaguchi
Keyword(s):  
Environmental Changes ◽  
Thermal Hysteresis ◽  
Metastable States ◽  
Molecular Switching

Molecular switching involving metastable states: molecular thermal hysteresis and sensing of environmental changes by chiral helicene oligomeric foldamers

2016 ◽  
Vol 52 (28) ◽  
pp. 4955-4970 ◽  
Author(s):  
Masanori Shigeno ◽  
Yo Kushida ◽  
Masahiko Yamaguchi
Keyword(s):  
Thermodynamic Properties ◽  
Environmental Changes ◽  
Thermal Hysteresis ◽  
Metastable States ◽  
Equilibrium Thermodynamic ◽  
Molecular Switching ◽  
Non Equilibrium

Molecular switching involving metastable states by chiral helicene oligomeric foldamers exhibits notable non-equilibrium thermodynamic properties, which can be used for sensing environmental changes.

Energy Aspects of Thermal Molecular Switching: Molecular Thermal Hysteresis of Helicene Oligomers

ChemPhysChem ◽  
2015 ◽  
Vol 16 (10) ◽  
pp. 2076-2083 ◽  
Author(s):  
Masanori Shigeno ◽  
Yo Kushida ◽  
Masahiko Yamaguchi
Keyword(s):  
Thermal Hysteresis ◽  
Molecular Switching ◽  
Energy Aspects

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

2021 ◽  
Author(s):  
Cyril Rajnák ◽  
Romana Mičová ◽  
Ján Moncoľ ◽  
Ľubor Dlháň ◽  
Christoph Krüger ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Mononuclear Complex ◽  
Hysteresis Width ◽  
Thermally Induced

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

Linking transcription, RNA polymerase II elongation and alternative splicing

2020 ◽  
Vol 477 (16) ◽  
pp. 3091-3104 ◽  
Author(s):  
Luciana E. Giono ◽  
Alberto R. Kornblihtt
Keyword(s):  
Gene Expression ◽  
Alternative Splicing ◽  
Rna Polymerase Ii ◽  
Environmental Changes ◽  
Transcription Elongation ◽  
Single Gene ◽  
Regulation Of Gene Expression ◽  
Regulation Of Transcription ◽  
Stepping Stones ◽  
Eukaryotic Transcription

Gene expression is an intricately regulated process that is at the basis of cell differentiation, the maintenance of cell identity and the cellular responses to environmental changes. Alternative splicing, the process by which multiple functionally distinct transcripts are generated from a single gene, is one of the main mechanisms that contribute to expand the coding capacity of genomes and help explain the level of complexity achieved by higher organisms. Eukaryotic transcription is subject to multiple layers of regulation both intrinsic — such as promoter structure — and dynamic, allowing the cell to respond to internal and external signals. Similarly, alternative splicing choices are affected by all of these aspects, mainly through the regulation of transcription elongation, making it a regulatory knob on a par with the regulation of gene expression levels. This review aims to recapitulate some of the history and stepping-stones that led to the paradigms held today about transcription and splicing regulation, with major focus on transcription elongation and its effect on alternative splicing.

Seeking to uncover biology's chemical roots

2019 ◽  
Vol 3 (5) ◽  
pp. 435-443 ◽  
Author(s):  
Addy Pross
Keyword(s):  
Environmental Changes ◽  
Biological Systems ◽  
Significant Development ◽  
The Road ◽  
Physical Chemical ◽  
Systems Chemistry ◽  
Biological World ◽  
Inanimate Matter ◽  
The Origin Of Life ◽  
Opening Up

Despite the considerable advances in molecular biology over the past several decades, the nature of the physical–chemical process by which inanimate matter become transformed into simplest life remains elusive. In this review, we describe recent advances in a relatively new area of chemistry, systems chemistry, which attempts to uncover the physical–chemical principles underlying that remarkable transformation. A significant development has been the discovery that within the space of chemical potentiality there exists a largely unexplored kinetic domain which could be termed dynamic kinetic chemistry. Our analysis suggests that all biological systems and associated sub-systems belong to this distinct domain, thereby facilitating the placement of biological systems within a coherent physical/chemical framework. That discovery offers new insights into the origin of life process, as well as opening the door toward the preparation of active materials able to self-heal, adapt to environmental changes, even communicate, mimicking what transpires routinely in the biological world. The road to simplest proto-life appears to be opening up.

Nature of thermal hysteresis of martensitic transformation in aged Cu-Mn-A1 alloy

2003 ◽  
Vol 112 ◽  
pp. 495-498
Author(s):  
V. V. Kokorin ◽  
L. E. Kozlova ◽  
A. N. Titenko
Keyword(s):  
Martensitic Transformation ◽  
Thermal Hysteresis

LASER-INDUCED METASTABLE STATES IN AMORPHOUS SEMICONDUCTORS

1981 ◽  
Vol 42 (C4) ◽  
pp. C4-395-C4-398 ◽  
Author(s):  
M. Wautelet ◽  
R. Andrew ◽  
M. Failly-Lovato ◽  
L. D. Laude
Keyword(s):  
Amorphous Semiconductors ◽  
Metastable States

Holocene diatom assemblages from Dunderbukhta sediments, West Svalbard

2019 ◽  
pp. 242-245
Author(s):  
Ksenya V. Poleshchuk ◽  
Zinaida V. Pushina ◽  
Sergey R. Verkulich
Keyword(s):  
Environmental Changes ◽  
Ecological Groups ◽  
Diatom Assemblages ◽  
Diatom Analysis ◽  
Diatom Flora ◽  
Sediment Samples ◽  
Ecological Zones ◽  
Middle Holocene ◽  
Temperature Trends

The diatom analysis results of sediment samples from Dunderbukta area (Wedel Jarlsberg Land, West Svalbard) are presented in this paper. The diatom flora consists of four ecological groups, which ratio indicates three ecological zones. These zones show environmental changes of the area in early–middle Holocene that is demonstrating periods of regression and temperature trends.

DIVERSITY OF FISH LARVAE AROUND THE ESTUARY OF THE BANYUASIN RIVER, SOUTH SUMATERA PROVINCE

2020 ◽  
Vol 6 (2) ◽  
Author(s):  
Moh. Rasyid Ridho ◽  
Enggar Patriono ◽  
Sarno Sarno ◽  
Sahira Wirda
Keyword(s):  
Initial Phase ◽  
Sampling Method ◽  
Environmental Changes ◽  
Negative Impact ◽  
Fish Larvae ◽  
River Estuary ◽  
Sampling Technique ◽  
Critical Phase ◽  
Morisita Index ◽  
Index Value

The initial phase of the fish life cycle is a critical phase associated with high mortality due to sensitivity to predators, food availability, and also environmental changes that occur in nature. Disruption of the initial stages of fish life has a negative impact on fish populations. Until now there has been no information about fish larvae around the Banyuasin River Estuary. Therefore, research is needed on the diversity of fish larvae around the Banyuasin River Estuary, South Sumatra Province. This research were used purposive sampling method, sampling technique in the form of Cruise Track Design with continuous parallel survey trajectory. Based on the results of the study found as many as 10 families consisting of 1483 individuals of fish larvae in March and 1013 individuals of fish larvae in May consisting of Engraulidae 1,601 individuals of fish larvae, Mungiloidei as many as 109 individuals, Leiognathidae 50 individuals, Chanidae 453 individuals, Scatophagidae 20 individuals , Belonidae 39 individuals, Gobioididae 5 individuals, Chandidae 183 individuals, Syngnatihidae 6 individuals, and Gobiidae 30 individuals fish larvae. The index value of fish larvae diversity is classified as medium category (March 1.02 and May 1.12), Morisita index shows the distribution pattern of fish larvae classified as a group (March 0-14.17 and May 2.43-10.40 ), and the evenness index value is in the medium category (March 0.437 and May 0.521).

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