ChemInform Abstract: I2-Promoted Aerobic Oxidative Coupling of Acetophenes with Amines under Metal-Free Conditions: Facile Access to α-Ketoamides.

ChemInform ◽  
2016 ◽  
Vol 47 (20) ◽  
Author(s):  
Shiyu Guo ◽  
Zheng Fang ◽  
Zhao Yang ◽  
Chengkou Liu ◽  
Zhongxue Dai ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Metal Free

A Three Component Iodine-Catalyzed Oxidative Coupling Reaction: A Heterodifunction of 3-Methylindole

2021 ◽  
Author(s):  
Wei Zhang ◽  
Shiqun Xiang ◽  
Weibin Fan ◽  
Jiang Jin ◽  
Yinghua Li ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Coupling Reaction ◽  
Peroxy Radicals ◽  
Metal Free ◽  
Tert Butyl ◽  
Oxidative Coupling Reaction

A metal-free synthesis of heterodifunctional indole derivaties is developed through TBHP/KI-mediated oxidative coupling. The reaction constructs C-O and C-C bonds in succession with the help of tert-butyl peroxy radicals generated...

ChemInform Abstract: Metal Free Oxidative Coupling of Aryl Formamides with Alcohols for the Synthesis of Carbamates.

ChemInform ◽  
2014 ◽  
Vol 45 (35) ◽  
pp. no-no
Author(s):  
N. Veera Reddy ◽  
K. Rajendra Prasad ◽  
P. Sudhir Reddy ◽  
M. Lakshmi Kantam ◽  
K. Rajender Reddy
Keyword(s):  
Oxidative Coupling ◽  
Metal Free

ChemInform Abstract: Direct Oxidative Coupling of Enamines and Electron-Deficient Amines: TBAI/TBHP-Mediated Synthesis of Substituted Diaminoalkenes under Metal-Free Conditions.

ChemInform ◽  
2015 ◽  
Vol 46 (14) ◽  
pp. no-no
Author(s):  
Yucheng Yuan ◽  
Wenjuan Hou ◽  
Daisy Zhang-Negrerie ◽  
Kang Zhao ◽  
Yunfei Du
Keyword(s):  
Oxidative Coupling ◽  
Metal Free

KI-Promoted Oxidative Coupling of Styrenes with Indoles under Metal-Free Conditions: Facile Access to C-3 Dicarbonyl Indoles

Synthesis ◽  
2019 ◽  
Vol 51 (18) ◽  
pp. 3511-3519
Author(s):  
Bochao Zhou ◽  
Shiyu Guo ◽  
Zheng Fang ◽  
Zhao Yang ◽  
Chengkou Liu ◽  
...  
Keyword(s):  
Efficient Method ◽  
Oxidative Coupling ◽  
Isotope Labeling ◽  
Cross Coupling ◽  
Metal Free ◽  
Broad Scope ◽  
Plausible Mechanism ◽  
Isotope Labeling Experiments

A new and efficient method for the synthesis of C-3 dicarbonyl indoles via oxidative cross-coupling of styrenes with indoles under metal-free conditions has been developed. Moreover, a broad scope of C-3 dicarbonyl indoles in moderate to good yields were obtained, and a plausible mechanism is proposed based on control and isotope-labeling experiments.

I2/TBHP-Promoted Approach to α-Keto Esters from Trifluoromethyl β-Diketones and Alcohols via C–C Bond Cleavage

Synlett ◽  
2017 ◽  
Vol 28 (15) ◽  
pp. 2018-2023 ◽  
Author(s):  
Xiang Fang ◽  
Xueyan Yang ◽  
Tongle Shao ◽  
Jun Zhou ◽  
Chen Jin ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Bond Cleavage ◽  
Bond Formation ◽  
Coupling Reaction ◽  
Mechanistic Studies ◽  
Metal Free ◽  
Oxidation Pathway ◽  
Keto Esters ◽  
Oxidative Coupling Reaction

A metal-free oxidative coupling reaction of trifluoromethyl β-diketones with alcohols for the synthesis of α-keto esters in good to excellent yields has been developed. Preliminary mechanistic studies suggest that an I2/TBHP promoted sequential iodination, C–C bond cleavage, C–O bond formation and oxidation pathway is involved in this reaction.

I2-promoted aerobic oxidative coupling of acetophenes with amines under metal-free conditions: facile access to α-ketoamides

RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1503-1507 ◽  
Author(s):  
Shiyu Guo ◽  
Zheng Fang ◽  
Zhao Yang ◽  
Chengkou Liu ◽  
Zhongxue Dai ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Oxidative Coupling ◽  
Environmentally Friendly ◽  
Metal Free

A novel and efficient I2-promoted oxidative coupling of acetophenes with amines to α-ketoamides is presented, which employs molecular oxygen as an environmentally friendly oxidant under metal-free conditions.

Functions of Phytic Acid in Fabricating Metal‐Free Carbocatalyst for Oxidative Coupling of Benzylamines †

2020 ◽  
Vol 38 (11) ◽  
pp. 1292-1298
Author(s):  
Chuanchuan Zhao ◽  
Yongjun Gao ◽  
Ziyi Zhang ◽  
Ding Ma
Keyword(s):  
Phytic Acid ◽  
Oxidative Coupling ◽  
Metal Free

Iodine mediated oxidative cross coupling of 2-aminopyridine and aromatic terminal alkyne: a practical route to imidazo[1,2-a]pyridine derivatives

2019 ◽  
Vol 17 (26) ◽  
pp. 6441-6449 ◽  
Author(s):  
Surya Kanta Samanta ◽  
Mrinal K. Bera
Keyword(s):  
Transition Metal ◽  
Oxidative Coupling ◽  
Cross Coupling ◽  
Terminal Alkyne ◽  
Pyridine Derivatives ◽  
Metal Free

A novel, transition-metal free route leading to imidazo[1,2-a]pyridine derivatives via iodine mediated oxidative coupling between 2-aminopyridine and aromatic terminal alkyne has been demonstrated.

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