ChemInform Abstract: A Highly Diastereoselective “Super Silyl” Governed Aldol Reaction: Synthesis of α,β-Dioxyaldehydes and 1,2,3-Triols.

ChemInform ◽  
2016 ◽  
Vol 47 (18) ◽  
Author(s):  
Wafa Gati ◽  
Hisashi Yamamoto
Keyword(s):  
Aldol Reaction ◽  
Reaction Synthesis ◽  
Super Silyl

scholarly journals A highly diastereoselective “super silyl” governed aldol reaction: synthesis of α,β-dioxyaldehydes and 1,2,3-triols

2016 ◽  
Vol 7 (1) ◽  
pp. 394-399 ◽  
Author(s):  
Wafa Gati ◽  
Hisashi Yamamoto
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Aldol Reaction ◽  
Reaction Synthesis ◽  
Lewis Acid Catalysis ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol ◽  
Super Silyl

“Super silyl” governed diastereoselective Mukaiyama aldol reaction for the construction of protected α,β-dioxyaldehydes and 1,2,3-triols via Lewis acid catalysis.

Direct Catalytic Asymmetric Aldol Reaction:  Synthesis of Eithersyn- oranti-α,β-Dihydroxy Ketones

2001 ◽  
Vol 123 (10) ◽  
pp. 2466-2467 ◽  
Author(s):  
Naoki Yoshikawa ◽  
Naoya Kumagai ◽  
Shigeki Matsunaga ◽  
Guido Moll ◽  
Takashi Ohshima ◽  
...  
Keyword(s):  
Aldol Reaction ◽  
Reaction Synthesis ◽  
Asymmetric Aldol ◽  
Asymmetric Aldol Reaction ◽  
Catalytic Asymmetric

A novel poly(N-isopropyl-acrylamine-co-l-proline) catalyst for aldol reaction: synthesis, catalytic performance and recyclability

RSC Advances ◽  
2014 ◽  
Vol 4 (92) ◽  
pp. 50412-50416 ◽  
Author(s):  
Yubing Liu ◽  
Qing Tong ◽  
Liya Ge ◽  
Yu Zhang ◽  
Lin Hua ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Circular Dichroism ◽  
Aldol Reaction ◽  
Catalytic Performance ◽  
Reaction Synthesis ◽  
Circular Dichroism Spectra ◽  
Excellent Activity ◽  
Circular Dichroïsm

A novel homogeneous copolymer catalyst, poly(N-isopropyl-acrylamine-co-l-proline), possesses excellent activity and stereoselectivities. Even after ten cycles, the catalytic activity and stereoselectivities remained almost unchanged. The circular dichroism spectra of the copolymer catalyst are apparently different from the corresponding monomer.

Chemoselective silyl transfer in the Mukaiyama aldol reaction promoted by super silyl Lewis acid

2014 ◽  
Vol 50 (96) ◽  
pp. 15206-15208 ◽  
Author(s):  
Masahiro Sai ◽  
Matsujiro Akakura ◽  
Hisashi Yamamoto
Keyword(s):  
Lewis Acid ◽  
Aldol Reaction ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol ◽  
Super Silyl

scholarly journals Direct Catalytic Asymmetric Aldol Reaction:  Synthesis of Eithersyn- oranti-α,β-Dihydroxy Ketones  [J. Am. Chem. Soc.2001,123, 2466−2467].

2001 ◽  
Vol 123 (16) ◽  
pp. 3856-3856
Author(s):  
Naoki Yoshikawa ◽  
Naoya Kumagai ◽  
Shigeki Matsunaga ◽  
Guido Moll ◽  
Takashi Ohshima ◽  
...  
Keyword(s):  
Aldol Reaction ◽  
Reaction Synthesis ◽  
Asymmetric Aldol ◽  
Asymmetric Aldol Reaction ◽  
Catalytic Asymmetric
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