ChemInform Abstract: Enantioselective Palladium-Catalyzed Arylation of N-Tosylarylimines with Arylboronic Acids Using a Chiral 2,2′-Bipyridine Ligand.

ChemInform ◽  
2016 ◽  
Vol 47 (17) ◽  
Author(s):  
Xiang Gao ◽  
Bo Wu ◽  
Zhong Yan ◽  
Yong-Gui Zhou
2016 ◽  
Vol 14 (1) ◽  
pp. 55-58 ◽  
Author(s):  
Xiang Gao ◽  
Bo Wu ◽  
Zhong Yan ◽  
Yong-Gui Zhou

An enantioselective palladium-catalyzed arylation of N-tosylarylimines with arylboronic acids was developed by using an axially chiral 2,2′-bipyridine ligand C3-ACBP, affording chiral diarylmethamines with up to 94% ee under exogenous-base-free conditions.


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