ChemInform Abstract: Enantioselective Synthesis of Fused Heterocycles with Contiguous Stereogenic Centers by Chiral Phosphoric Acid Catalyzed Symmetry Breaking.

ChemInform ◽  
2016 ◽  
Vol 47 (13) ◽  
pp. no-no
Author(s):  
Keiji Mori ◽  
Ayaka Miyake ◽  
Takahiko Akiyama
Keyword(s):  
Symmetry Breaking ◽  
Phosphoric Acid ◽  
Enantioselective Synthesis ◽  
Fused Heterocycles ◽  
Chiral Phosphoric Acid ◽  
Stereogenic Centers ◽  
Acid Catalyzed

Enantioselective synthesis of fused heterocycles with contiguous stereogenic centers by chiral phosphoric acid catalyzed symmetry breaking

2015 ◽  
Vol 51 (89) ◽  
pp. 16107-16110 ◽  
Author(s):  
Keiji Mori ◽  
Ayaka Miyake ◽  
Takahiko Akiyama
Keyword(s):  
Symmetry Breaking ◽  
Phosphoric Acid ◽  
Enantioselective Synthesis ◽  
Fused Heterocycles ◽  
Chiral Phosphoric Acid ◽  
Stereogenic Centers ◽  
Acid Catalyzed

Highly enantioselective synthesis of fused-heterocycles was achieved by chiral phosphoric acid catalyzed symmetry breaking.

scholarly journals Catalytic Enantioselective Synthesis of 4-Amino-1,2,3,4-tetrahydropyridine Derivatives from Intramolecular Nucleophilic Addition Reaction of Tertiary Enamides

Synlett ◽  
2018 ◽  
Vol 30 (04) ◽  
pp. 483-487 ◽  
Author(s):  
Shuo Tong ◽  
Mei-Xiang Wang
Keyword(s):  
Phosphoric Acid ◽  
Asymmetric Catalysis ◽  
Nucleophilic Addition ◽  
Addition Reaction ◽  
Enantioselective Synthesis ◽  
Chiral Phosphoric Acid ◽  
Substrate Engineering ◽  
Nucleophilic Addition Reaction ◽  
Engineering Strategy ◽  
Acid Catalyzed

A general and efficient method for the synthesis of highly enantiopure 4-amino-1,2,3,4-tetradydropyridine derivatives based on chiral phosphoric acid catalyzed intramolecular nucleophilic addition of tertiary enamides to imines has been developed. We have also demonstrated a substrate engineering strategy to significantly improve the enantioselectivity of asymmetric catalysis

Highly Diastereo- and Enantioselective Synthesis of Cyclohepta[b ]indoles by Chiral-Phosphoric-Acid-Catalyzed (4+3) Cycloaddition

2018 ◽  
Vol 130 (37) ◽  
pp. 12297-12301 ◽  
Author(s):  
Coralie Gelis ◽  
Guillaume Levitre ◽  
Jérémy Merad ◽  
Pascal Retailleau ◽  
Luc Neuville ◽  
...  
Keyword(s):  
Phosphoric Acid ◽  
Enantioselective Synthesis ◽  
Chiral Phosphoric Acid ◽  
Acid Catalyzed

Enantioselective synthesis of isoquinoline-1,3(2H,4H)-dione derivatives via a chiral phosphoric acid catalyzed aza-Friedel–Crafts reaction

2019 ◽  
Vol 55 (58) ◽  
pp. 8478-8481 ◽  
Author(s):  
Yong You ◽  
Wen-Ya Lu ◽  
Ke-Xin Xie ◽  
Jian-Qiang Zhao ◽  
Zhen-Hua Wang ◽  
...  
Keyword(s):  
Phosphoric Acid ◽  
Enantioselective Synthesis ◽  
Chiral Phosphoric Acid ◽  
Acid Catalyzed

A class of structurally new ketimines were prepared and used for the first enantioselective synthesis of isoquinoline-1,3(2H,4H)-dione derivatives.

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