ChemInform Abstract: A Simple One-Pot Methodology for the Synthesis of Substituted Benzoylguanidines from Benzoylthioureas Using tert-Butyl Hydroperoxide.

ChemInform ◽  
2016 ◽  
Vol 47 (13) ◽  
pp. no-no
Author(s):  
Henrique Esteves ◽  
Angelo de Fatima ◽  
Rosane de P. Castro ◽  
Fernando Jr. Macedo ◽  
Tiago Oliveira Brito
Keyword(s):  
One Pot ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

NH4I/tert-Butyl Hydroperoxide-Promoted Oxidative C–N Cleavage of Tertiary Amines Leading to Nitroaromatic Compounds

2017 ◽  
Vol 41 (9) ◽  
pp. 504-508 ◽  
Author(s):  
Ying Shao ◽  
Hao Zheng ◽  
Zhuhong Wu ◽  
Lei Huang ◽  
Jingjing Tong ◽  
...  
Keyword(s):  
Nitroaromatic Compounds ◽  
Tertiary Amines ◽  
One Pot ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

A NH4I/ tert-butyl hydroperoxide-promoted oxidation of tertiary N-aryl- N,N-dialkylamines in DMSO has been developed to access nitroaromatic compounds. This methodology involves sequential N-dealkylation reactions in one-pot and a radical pathway is proposed.

One Pot Deprotective Oxidation of O-Allyl Ethers Using 70% tert-Butyl Hydroperoxide and Catalytic CrO3

Synlett ◽  
1999 ◽  
Vol 1999 (7) ◽  
pp. 1063-1064 ◽  
Author(s):  
S. Chandrasekhar ◽  
Pradyumna K. Mohanty ◽  
T. Ramachander
Keyword(s):  
One Pot ◽  
Butyl Hydroperoxide ◽  
Allyl Ethers ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

scholarly journals A simple one-pot methodology for the synthesis of substituted benzoylguanidines from benzoylthioureas using tert-butyl hydroperoxide

2015 ◽  
Vol 56 (49) ◽  
pp. 6872-6874 ◽  
Author(s):  
Henrique Esteves ◽  
Ângelo de Fátima ◽  
Rosane de P. Castro ◽  
José R. Sabino ◽  
Fernando Macedo ◽  
...  
Keyword(s):  
One Pot ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition

RSC Advances ◽  
2016 ◽  
Vol 6 (104) ◽  
pp. 102023-102027 ◽  
Author(s):  
Xiuling Chen ◽  
Yan Li ◽  
Minghu Wu ◽  
Haibing Guo ◽  
Longqiang Jiang ◽  
...  
Keyword(s):  
Efficient Method ◽  
Bond Cleavage ◽  
Bond Formation ◽  
One Pot ◽  
Free Condition ◽  
Butyl Hydroperoxide ◽  
Metal Free ◽  
Tert Butyl ◽  
Butyl Esters ◽  
Tert Butyl Hydroperoxide

A novel protocol to synthesize tert-butyl esters from benzyl cyanides and tert-butyl hydroperoxide has been successfully achieved. Csp3–H bond oxidation, C–CN bond cleavage and C–O bond formation proceeded smoothly in one pot under the metal-free condition.

Copper and N-heterocyclic carbene (NHC) catalyzed oxidative amidation of aldehydes with amines

Synlett ◽  
2020 ◽  
Author(s):  
Ashmita Singh ◽  
Anudeep Kumar Narula
Keyword(s):  
Heterocyclic Carbenes ◽  
Oxidative Process ◽  
One Pot ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Oxidative Amidation

A one-pot two-step oxidative process using tert-butyl hydroperoxide (TBHP) mediated transformation of aldehydes and amines into amides catalyzed by Copper (I) - Iodide and N-heterocyclic carbenes is developed. The process utilized is additive-free, which does not require the amines to be transformed into their hydrochloride salts. The method reported herein is facile and practicable, has a broad substrate scope, and also utilizes the economic, feasible, and abundant reagents.

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