ChemInform Abstract: Magnetic α-Fe2O3Nanofibers: An Efficient and Recyclable Catalyst for Solvent-Free Selective Oxidation of Benzylic Alcohols.

ChemInform ◽  
2016 ◽  
Vol 47 (1) ◽  
Author(s):  
Hakimeh Ziyadi ◽  
Akbar Heydari ◽  
Fatemeh Nikbakht
Keyword(s):  
Selective Oxidation ◽  
Recyclable Catalyst ◽  
Solvent Free ◽  
Benzylic Alcohols

ChemInform Abstract: An Efficient and Selective Oxidation of Benzylic Alcohols to the Corresponding Carbonyl Compounds under Solvent-Free Conditions.

ChemInform ◽  
2010 ◽  
Vol 31 (24) ◽  
pp. no-no
Author(s):  
Abdol Reza Hajipour ◽  
Shadpour E. Mallakpour ◽  
Iraj Mohammadpoor-Baltork ◽  
Sepideh Khoee
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Solvent Free ◽  
Benzylic Alcohols ◽  
Solvent Free Conditions

An Efficient and Selective Oxidation of Benzylic Alcohols to the Corresponding Carbonyl Compounds under Solvent-Free Conditions

2000 ◽  
Vol 29 (2) ◽  
pp. 120-121 ◽  
Author(s):  
Abdol Reza Hajipour ◽  
Shadpour E. Mallakpour ◽  
Iraj Mohammadpoor-Baltork ◽  
Sepideh Khoee
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Solvent Free ◽  
Benzylic Alcohols ◽  
Solvent Free Conditions

ChemInform Abstract: Microwave Assisted Selective Oxidation of Benzylic Alcohols with Calcium Hypochlorite under Solvent-Free Conditions.

ChemInform ◽  
2010 ◽  
Vol 32 (34) ◽  
pp. no-no
Author(s):  
Mohammad M. Mojtahedi ◽  
Mohammad R. Saidi ◽  
Mohammad Bolourtchian ◽  
Jafar S. Shirzi
Keyword(s):  
Selective Oxidation ◽  
Solvent Free ◽  
Calcium Hypochlorite ◽  
Benzylic Alcohols ◽  
Microwave Assisted ◽  
Solvent Free Conditions

A Solvent Free Synthetic Route for Cerium(IV) Metal-Organic Frame-works with UiO-66 Architecture and Their Photocatalytic Application

2019 ◽  
Author(s):  
Matteo Campanelli ◽  
Tiziana Del Giacco ◽  
Filippo De Angelis ◽  
Edoardo Mosconi ◽  
Marco Taddei ◽  
...  
Keyword(s):  
Density Functional ◽  
Chemical Oxidation ◽  
Solvent Free ◽  
Cerium Ammonium Nitrate ◽  
Benzylic Alcohols ◽  
Near Ultraviolet ◽  
Photocatalytic Application ◽  
Activity Density ◽  
Ultraviolet Light Irradiation ◽  
Metal Organic

<div> <p>A novel solvent-free synthesis for Ce-UiO-66 metal-organic frameworks (MOFs) is presented. The MOFs are obtained by simply grinding the reagents, cerium ammonium nitrate (CAN) and the carboxylic linkers, in a mortar for few minutes with the addition of a small amount of acetic acid (AcOH) as modulator (1.75 eq, o.1 ml). The slurry is then transferred into a 1 ml vial and heated at 120°C for 1 day. The MOFs have been characterized for their composition, crystallinity and porosity and employed as heterogenous catalysts for the photo-oxidation reaction of substituted benzylic alcohols to benzaldaldehydes under near ultraviolet light irradiation. The catalytic performances, such as yield, conversion and kinetics, exceed those of similar systems studied by chemical oxidation and using Ce-MOF as catalyst. Moreover, the MOFs were found to be reusable up to three cycles without loss of activity. Density functional theory (DFT) calculations gave an estimation of the band-gap shift due to the different nature of the linkers used and provide useful information on the catalytic activity experimentally observed.</p> </div>

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