ChemInform Abstract: A Modified Procedure for the Palladium Catalyzed Borylation/Suzuki-Miyaura Cross-Coupling of Aryl and Heteroaryl Halides Utilizing Bis-boronic Acid.

ChemInform ◽  
2015 ◽  
Vol 46 (47) ◽  
pp. no-no
Author(s):  
Gary A. Molander ◽  
Sarah L.J. Trice ◽  
Brittany Tschaen
Keyword(s):  
Boronic Acid ◽  
Cross Coupling ◽  
Palladium Catalyzed

Palladium-catalyzed 3-Thiomethyltriazine-boronic Acid Cross Coupling: Easy Access to 3-Substituted-1,2,4-triazines

Synlett ◽  
2002 ◽  
Vol 2002 (03) ◽  
pp. 0447-0450 ◽  
Author(s):  
France-Aimée Alphonse ◽  
Franck Suzenet ◽  
Anne Keromnes ◽  
Bruno Lebret ◽  
Gérald Guillaumet
Keyword(s):  
Boronic Acid ◽  
Cross Coupling ◽  
Easy Access ◽  
Palladium Catalyzed

scholarly journals Recent Advances in the Applications of the Intramolecular Suzuki Cross-coupling Reaction in Cyclization and Heterocyclization: An Update

2020 ◽  
Vol 23 (22) ◽  
pp. 2469-2488 ◽  
Author(s):  
Majid M. Heravi ◽  
Masoumeh Malmir ◽  
Razieh Moradi
Keyword(s):  
Organic Chemistry ◽  
Boronic Acid ◽  
Heterocyclic Compounds ◽  
Aryl Halide ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Synthetic Organic Chemistry ◽  
Previous Review ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

: The palladium-catalyzed reaction of aryl halide and boronic acid for the formation of C–C bonds so-called Suzuki–Miyaura cross-coupling reaction has many applications in Modern Synthetic Organic Chemistry. In 2013, we emphasized the applications of the intramolecular Suzuki cross-coupling reaction in cyclization and heterocyclization. Due to a plethora relevant papers appeared in the chemical literature, herein, we wish to cover by updating our previous review, the applications of the intramolecular Suzuki cross-coupling reaction in cyclization and heterocyclization leading to various homocyclic and heterocyclic compounds reported during a period of 2013 to 2018.

Palladium-catalyzed Suzuki cross-couplings of N′-mesyl arylhydrazines via C–N bond cleavage

RSC Advances ◽  
2014 ◽  
Vol 4 (49) ◽  
pp. 25576-25579 ◽  
Author(s):  
He-Ping Zhou ◽  
Jin-Biao Liu ◽  
Jian-Jun Yuan ◽  
Yi-Yuan Peng
Keyword(s):  
Boronic Acid ◽  
Bond Cleavage ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Mild Conditions ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed ◽  
High Yields ◽  
Aryl Boronic Acid ◽  
Biaryl Compounds

An efficient palladium-catalyzed Suzuki cross-coupling reaction of N′-mesyl arylhydrazine with aryl boronic acid is described, which affords the corresponding biaryl compounds in high yields. This transformation proceeds through C–N bond cleavage under mild conditions.

ChemInform Abstract: The Palladium-Catalyzed Cross-Coupling Reactions of Trifluoroethyl Iodide with Aryl and Heteroaryl Boronic Acid Esters.

ChemInform ◽  
2012 ◽  
Vol 43 (50) ◽  
pp. no-no
Author(s):  
Apeng Liang ◽  
Xinjian Li ◽  
Dongfeng Liu ◽  
Jingya Li ◽  
Dapeng Zou ◽  
...  
Keyword(s):  
Boronic Acid ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed ◽  
Acid Esters

The palladium-catalyzed cross-coupling reactions of trifluoroethyl iodide with aryl and heteroaryl boronic acid esters

2012 ◽  
Vol 48 (66) ◽  
pp. 8273 ◽  
Author(s):  
Apeng Liang ◽  
Xinjian Li ◽  
Dongfeng Liu ◽  
Jingya Li ◽  
Dapeng Zou ◽  
...  
Keyword(s):  
Boronic Acid ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed ◽  
Acid Esters

Palladium-Catalyzed Boronic Acid Cross-Coupling Reactions of β-Ethoxy β-Trifluoromethyl Vinyl Bromides

Synthesis ◽  
1998 ◽  
Vol 1998 (06) ◽  
pp. 847-850 ◽  
Author(s):  
Lydie Allain ◽  
Jean-Pierre Bégué ◽  
Danièle Bonnet-Delpon ◽  
Denis Bouvet
Keyword(s):  
Boronic Acid ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed

scholarly journals 2′-Chloro-4-(1-methyl-1H-imidazol-2-yl)-2,4′-bipyridine

Molbank ◽  
10.3390/m1040 ◽  
2018 ◽  
Vol 2019 (1) ◽  
pp. M1040 ◽  
Author(s):  
Dhafer Zinad ◽  
Dunya AL-Duhaidahaw ◽  
Ahmed Al-Amiery
Keyword(s):  
Mass Spectrometry ◽  
Boronic Acid ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Gas Chromatography Mass Spectrometry ◽  
Target Compound ◽  
Chromatography Mass Spectrometry ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed ◽  
Layer Chromatography

The compound 2′-chloro-4-(1-methyl-1H-imidazol-2-yl)-2,4′-bipyridine was obtained with a good yield by the reaction of 2-chloro-4-(1-methyl-1H-imidazol-2-yl)pyridine with (2-chloropyridin-4-yl)boronic acid and structurally characterized by nuclear magnetic resonance (1H-NMR and 13C-NMR), thin-layer chromatography–mass spectrometry (TLC–MS), HPLC, gas chromatography–mass spectrometry (GC–MS), and elemental analysis. The functionalization of the pyridine was achieved by the palladium-catalyzed Suzuki–Miyaura carbon–carbon cross-coupling reaction that afforded the target compound.

Aryl-Decarboxylation Reactions Catalyzed by Palladium: Scope and Mechanism

Synthesis ◽  
2019 ◽  
Vol 52 (03) ◽  
pp. 365-377 ◽  
Author(s):  
Ryan A. Daley ◽  
Joseph J. Topczewski
Keyword(s):  
Carboxylic Acids ◽  
Boronic Acid ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Heck Reactions ◽  
Cross Coupling Reactions ◽  
Related Family ◽  
Organometallic Precursor ◽  
Palladium Catalyzed ◽  
Catalyzed Reactions

Palladium-catalyzed cross-couplings and related reactions have enabled many transformations essential to the synthesis of pharmaceuticals, agrochemicals, and organic materials. A related family of reactions that have received less attention are decarboxylative functionalization reactions. These reactions replace the preformed organometallic precursor (e.g., boronic acid or organostannane) with inexpensive and readily available carboxylic acids for many palladium-catalyzed reactions. This review focuses on catalyzed reactions where the elementary decarboxylation step is thought to occur at a palladium center. This review does not include decarboxylative reactions where decarboxylation is thought to be facilitated by a second metal (copper or silver) and is specifically limited to (hetero)arenecarboxylic acids. This review includes a discussion of oxidative Heck reactions, protodecarboxylation reactions, and cross-coupling reactions among others.1 Introduction2 Oxidative Heck Reactions3 Protodecarboxylation Reactions4 Cross-Coupling Reactions5 Other Reactions6 Conclusion

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