ChemInform Abstract: Diglycolamide-Based Solvent Systems in Room Temperature Ionic Liquids for Actinide Ion Extraction: A Review

ChemInform ◽  
2015 ◽  
Vol 46 (46) ◽  
pp. no-no
Author(s):  
Prasanta Kumar Mohapatra
2015 ◽  
Vol 10 (2) ◽  
pp. 135-145 ◽  
Author(s):  
Prasanta Kumar Mohapatra

Abstract This review article gives a comprehensive account of the extraction of actinide ions using room temperature ionic liquid-based solvent systems containing diglycolamide (DGA) or functionalized DGA extractants. These extractants include multiple DGA-functionalized ligands such as tripodal DGA (T-DGA) and DGA-functionalized calix [4]arenes (C4DGA). Apart from metal ion extraction behaviour, other important features of the ionic liquid-based solvent systems such as separation behaviour, luminescence spectroscopic results, thermodynamics of extraction and radiolytic stability of the ionic liquid-based solvents are also reviewed. Results from studies on DGA-functionalized task-specific ionic liquids (TSIL) are also included in this review article.


2017 ◽  
Vol 46 (6) ◽  
pp. 1730-1747 ◽  
Author(s):  
Prasanta Kumar Mohapatra

Studies on the extraction of actinide ions from radioactive wastes have great relevance in nuclear fuel cycle activities, mainly in the back end processes focused on reprocessing and waste management.


Molecules ◽  
2020 ◽  
Vol 25 (24) ◽  
pp. 5812
Author(s):  
Gonçalo A. O. Tiago ◽  
Inês A. S. Matias ◽  
Ana P. C. Ribeiro ◽  
Luísa M. D. R. S. Martins

In this review, the roles of room temperature ionic liquids (RTILs) and RTIL based solvent systems as proposed alternatives for conventional organic electrolyte solutions are described. Ionic liquids are introduced as well as the relevant properties for their use in electrochemistry (reduction of ohmic losses), such as diffusive molecular motion and ionic conductivity. We have restricted ourselves to provide a survey on the latest, most representative developments and progress made in the use of ionic liquids as electrolytes, in particular achieved by the cyclic voltammetry technique. Thus, the present review comprises literature from 2015 onward covering the different aspects of RTILs, from the knowledge of these media to the use of their properties for electrochemical processes. Out of the scope of this review are heat transfer applications, medical or biological applications, and multiphasic reactions.


2015 ◽  
Vol 305 (2) ◽  
pp. 521-528 ◽  
Author(s):  
Ajay B. Patil ◽  
P. N. Pathak ◽  
V. S. Shinde ◽  
M. Yu. Alyapyshev ◽  
V. A. Babain ◽  
...  

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