ChemInform Abstract: Electrochemical Sensing Using Boronic Acids

ChemInform ◽  
2015 ◽  
Vol 46 (45) ◽  
pp. no-no
Author(s):  
Meng Li ◽  
Weihong Zhu ◽  
Frank Marken ◽  
Tony D. James
Keyword(s):  
Boronic Acids ◽  
Electrochemical Sensing

Electrochemical sensing using boronic acids

2015 ◽  
Vol 51 (78) ◽  
pp. 14562-14573 ◽  
Author(s):  
Meng Li ◽  
Weihong Zhu ◽  
Frank Marken ◽  
Tony D. James
Keyword(s):  
Boronic Acids ◽  
Electrochemical Sensing ◽  
Lewis Bases ◽  
Cyclic Complexes

Boronic acids can bind with 1,2- or 1,3-diols to form five or six-membered cyclic complexes and also can interact with Lewis bases to generate boronate anions, making them suitable for the electrochemical sensing of these species

Electrochemical Sensing System for Detection of Tricresyl-phosphate

2011 ◽  
Author(s):  
Xiaoyun Yang ◽  
Ruel Overfelt ◽  
Alice Zitova ◽  
Aleksandr Simonian ◽  
Jeffrey Kirsch ◽  
...  
Keyword(s):  
Electrochemical Sensing ◽  
Tricresyl Phosphate ◽  
Sensing System

A Mild and Simple Method for Making MIDA Boronates

2020 ◽  
Author(s):  
Aidan Kelly ◽  
Peng-Jui (Ruby) Chen ◽  
Jenna Klubnick ◽  
Daniel J. Blair ◽  
Martin D. Burke
Keyword(s):  
Organic Synthesis ◽  
Boronic Acids ◽  
Simple Method ◽  
Direct Preparation ◽  
Synthesis Procedure ◽  
Harsh Conditions

<div> <div> <div> <p>Existing methods for making MIDA boronates require harsh conditions and complex procedures to achieve dehydration. Here we disclose that a pre-dried form of MIDA, MIDA anhydride, acts as both a source of the MIDA ligand and an in situ desiccant to enable a mild and simple MIDA boronate synthesis procedure. This method expands the range of sensitive boronic acids that can be converted into their MIDA boronate counterparts. Further utilizing unique properties of MIDA boronates, we have developed a MIDA Boronate Maker Kit which enables the direct preparation and purification of MIDA boronates from boronic acids using only heating and centrifuge equipment that is widely available in labs that do not specialize in organic synthesis. </p> </div> </div> </div>

Neoglycopeptide Synthesis by Suzuki-Miyaura Couplings between Glycosyl Aryl Boronic Acids and Iodopeptides

2014 ◽  
Vol 21 (10) ◽  
pp. 1004-1010
Author(s):  
Guohua Chen ◽  
Xiangying Gu ◽  
Lin Chen ◽  
Xin Wang ◽  
Yue-Lei Chen ◽  
...  
Keyword(s):  
Boronic Acids

Electrochemical sensing of Sudan I using the modified graphite screen-printed electrode

2020 ◽  
pp. 1-14
Author(s):  
Somayeh Tajik ◽  
Hadi Beitollahi ◽  
Fariba Garkani Nejad ◽  
Mohadeseh Safaei ◽  
Peyman Mohammadzadeh Jahani
Keyword(s):  
Electrochemical Sensing ◽  
Screen Printed Electrode ◽  
Sudan I ◽  
Screen Printed

scholarly journals Simultaneous electrochemical sensing of dihydroxy benzene isomers at cost-effective allura red polymeric film modified glassy carbon electrode

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Pattan-Siddappa Ganesh ◽  
Ganesh Shimoga ◽  
Seok-Han Lee ◽  
Sang-Youn Kim ◽  
Eno E. Ebenso
Keyword(s):  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Limit Of Detection ◽  
Tap Water ◽  
Differential Pulse ◽  
Oxidation Potential ◽  
Electrochemical Sensing ◽  
Carbon Electrode ◽  
Buffer Solution ◽  
Allura Red

Abstract Background A simple and simultaneous electrochemical sensing platform was fabricated by electropolymerization of allura red on glassy carbon electrode (GCE) for the interference-free detection of dihydroxy benzene isomers. Methods The modified working electrode was characterized by electrochemical and field emission scanning electron microscopy methods. The modified electrode showed excellent electrocatalytic activity for the electrooxidation of catechol (CC) and hydroquinone (HQ) at physiological pH of 7.4 by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. Results The effective split in the overlapped oxidation signal of CC and HQ was achieved in a binary mixture with peak to peak separation of 0.102 V and 0.103 V by CV and DPV techniques. The electrode kinetics was found to be adsorption-controlled. The oxidation potential directly depends on the pH of the buffer solution, and it witnessed the transfer of equal number of protons and electrons in the redox phenomenon. Conclusions The limit of detection (LOD) for CC and HQ was calculated to be 0.126 μM and 0.132 μM in the linear range of 0 to 80.0 μM and 0 to 110.0 μM, respectively, by ultra-sensitive DPV technique. The practical applicability of the proposed sensor was evaluated for tap water sample analysis, and good recovery rates were observed. Graphical abstract Electrocatalytic interaction of ALR/GCE with dihydroxy benzene isomers.

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