ChemInform Abstract: Transition-Metal Catalyzed Synthesis of Organosulfur Compounds Using Single Bond Metathesis Reaction

ChemInform ◽  
2015 ◽  
Vol 46 (43) ◽  
pp. no-no
Author(s):  
Mieko Arisawa
Keyword(s):  
Transition Metal ◽  
Organosulfur Compounds ◽  
Single Bond ◽  
Metathesis Reaction ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition-metal-catalyzed synthesis of organosulfur compounds

2008 ◽  
Vol 80 (5) ◽  
pp. 993-1003 ◽  
Author(s):  
Mieko Arisawa ◽  
Masahiko Yamaguchi
Keyword(s):  
Transition Metal ◽  
Addition Reaction ◽  
Organosulfur Compounds ◽  
Rhodium Complexes ◽  
Single Bond ◽  
Unsaturated Compounds ◽  
Metathesis Reactions ◽  
Metal Catalyzed ◽  
Inorganic Molecules ◽  
Allyl Sulfides

Rhodium complexes are efficient catalysts for the synthesis of organosulfur compounds. They catalyze the addition reaction of organosulfur groups to unsaturated compounds, the substitution of C-H with organosulfur groups, and single-bond metathesis reactions. They cleave S-S bonds and transfer the organosulfur groups to various organic and inorganic molecules, including alkynes, allenes, disulfides, sulfur, isonitriles, imines, diphosphines, thiophosphinites, hydrogen, 1-alkylthio-1-alkynes, thioesters, and allyl sulfides.

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

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