ChemInform Abstract: Palladium-Catalyzed Vicinal Amino Alcohols Synthesis from Allyl Amines by in situ Tether Formation and Carboetherification.

ChemInform ◽  
2015 ◽  
Vol 46 (35) ◽  
pp. no-no
Author(s):  
Ugo Orcel ◽  
Jerome Waser
Keyword(s):  
Amino Alcohols ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Functionalization of Olefins and Alkynes: From Oxyalkynylation to Tethered Dynamic Kinetic Asymmetric Transformations (DYKAT)

Synlett ◽  
2020 ◽  
Author(s):  
Stefano Nicolai ◽  
Ugo Orcel ◽  
Bastian Muriel ◽  
Phillip D. G. Greenwood ◽  
Luca Buzzetti ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Amino Alcohols ◽  
Chiral Auxiliary ◽  
Allylic Alcohols ◽  
Personal Account ◽  
Allylic Amines ◽  
Asymmetric Transformations ◽  
Palladium Catalyzed ◽  
Asymmetric Transformation

AbstractThis review presents an account of the palladium-catalyzed functionalizations of alkenes and alkynes developed at the Laboratory of Catalysis and Organic Synthesis (LCSO). Starting from the intramolecular oxy- and aminoalkynylation of alkenes, tethered methods were then developed to functionalize allylic amines and alcohols, as well as propargylic amines. Finally, a new dynamic kinetic asymmetric transformation was developed based on the use of a ‘one-arm’ Trost-type ligand, giving access to enantiopure amino alcohols. Each section is a personal account by the researcher(s) who performed the work.1 Introduction,2 Oxy- and Aminoalkynylation of Olefins,3 In Situ Tethering Strategies for the Synthesis of Vicinal Amino Alcohols and Diamines,4 Carboamination of Allylic Alcohols,5 Carbooxygenation of Propargylic Amines,6 Enantioselective Carboetherification/Hydrogenation via a Catalytically Formed Chiral Auxiliary,7 Conclusion

Palladium-Catalyzed One-Pot Synthesis of C2-Quaternary Indolin-3-ones via 1H -indole-3-sulfonates Generated in Situ from 2-Alkynyl Arylazides and Sulfonic Acids

2017 ◽  
Vol 359 (23) ◽  
pp. 4147-4152 ◽  
Author(s):  
Xiaoxiang Zhang ◽  
Ping Li ◽  
Chang Lyu ◽  
Wanxiong Yong ◽  
Jing Li ◽  
...  
Keyword(s):  
Sulfonic Acids ◽  
One Pot ◽  
One Pot Synthesis ◽  
Palladium Catalyzed
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