ChemInform Abstract: Copper-Catalyzed Tandem Reactions of 2-Iodobenzamides with Sodium Azide: An Efficient Synthesis of [1,2,3]Triazolo[1,5-a][1,4]-benzodiazepin-6(5H)-ones.

ChemInform ◽  
2015 ◽  
Vol 46 (33) ◽  
pp. no-no
Author(s):  
Wanli Chen ◽  
Haitao Li ◽  
Xiaoling Gu ◽  
Yinghong Zhu
Keyword(s):  
Sodium Azide ◽  
Tandem Reactions ◽  
Efficient Synthesis

Copper(I) Iodide Catalyzed Tandem Reactions of N-Propargyl-N-(2-iodoaryl)amides with Sodium Azide: An Efficient Synthesis of [1,2,3]Triazolo[1,5-a]quinoxalines

Synlett ◽  
2021 ◽  
Vol 32 (08) ◽  
pp. 805-809
Author(s):  
Yinghong Zhu ◽  
Wanli Chen ◽  
Xiangtu Tu ◽  
Mingxia Xu ◽  
Youqun Chu
Keyword(s):  
Efficient Method ◽  
Sodium Azide ◽  
Tandem Reactions ◽  
Efficient Synthesis ◽  
Mild Conditions ◽  
Type Coupling ◽  
Catalyzed Reactions

AbstractCopper-catalyzed reactions of N-propargyl-N-(2-iodoaryl)amides with sodium azide have been developed, providing a novel and efficient method for the synthesis of [1,2,3]triazolo[1,5-a]quinoxaline compounds under mild conditions in moderate yields by tandem copper-catalyzed azide-alkyne cycloaddition and Ullmann-type coupling.

CuI/Et2NH-Catalyzed One-Pot Highly Efficient Synthesis of 1,4-Disubstituted 1,2,3-Triazoles in Green Solvent Glycerol

Synthesis ◽  
2018 ◽  
Vol 50 (11) ◽  
pp. 2191-2199 ◽  
Author(s):  
Yongde Zhao ◽  
Shengqiang Guo ◽  
Yang Zhou ◽  
Bencai Dai ◽  
Cuimeng Huo ◽  
...  
Keyword(s):  
Catalytic System ◽  
Sodium Azide ◽  
Room Temperature ◽  
Green Solvent ◽  
Efficient Synthesis ◽  
One Pot ◽  
Highly Efficient ◽  
Three Component Reaction ◽  
Efficient Route ◽  
Terminal Acetylenes

A concise one-pot three-component reaction of organic halides­, terminal acetylenes, and sodium azide provided an efficient route for the synthesis of 1,2,3-triazoles. A variety of 1,2,3-triazoles were prepared in good to excellent yields with green solvent glycerol. This procedure used CuI and diethylamine, which are two easily available reagents as the new catalytic system at room temperature.

Diversified Synthesis of 2-(4-Oxo[1,2,3]triazolo[1,5-a]quinoxalin-5(4H)-yl)acetamide Derivatives through Ugi-4-CR and Copper-Catalyzed Tandem Reactions

Synthesis ◽  
2017 ◽  
Vol 49 (17) ◽  
pp. 3863-3873 ◽  
Author(s):  
Yu An ◽  
Huan He ◽  
Tiantian Liu ◽  
Yong Zhang ◽  
Xiaoyun Lu ◽  
...  
Keyword(s):  
Sodium Azide ◽  
Tandem Reaction ◽  
Tandem Reactions ◽  
Rapid Access

A diversified synthesis of 2-(4-oxo[1,2,3]triazolo-[1,5-a]quin­oxalin-5(4H)-yl)acetamide derivatives is demonstrated. The protocol employs a Ugi four-component reaction for the assembling of N-(2-haloaryl)propynamide intermediates and followed by a copper-catalyzed tandem reaction of the synthetic N-(2-haloaryl)propynamides with sodium azide. Such a method provides rapid access to structurally varied and complex fused tricyclic scaffolds through readily available starting materials.

Efficient Synthesis of Isothiocyanates Based on the Tandem Staudinger/Aza-Wittig Reactions and Mechanistic Consideration of the Tandem Reactions.

ChemInform ◽  
2007 ◽  
Vol 38 (16) ◽  
Author(s):  
Takeshi Isoda ◽  
Kazuhiko Hayashi ◽  
Satoshi Tamai ◽  
Toshio Kumagai ◽  
Yoshimitsu Nagao
Keyword(s):  
Tandem Reactions ◽  
Efficient Synthesis ◽  
Wittig Reactions
Sign in / Sign up

Export Citation Format

Share Document