ChemInform Abstract: Catalyst- and Solvent-Free Stereoselective Addition of Secondary Phosphine Chalcogenides to Alkynes.

ChemInform ◽  
2015 ◽  
Vol 46 (24) ◽  
pp. no-no
Author(s):  
Alexander V. Artem'ev ◽  
Svetlana F. Malysheva ◽  
Nina K. Gusarova ◽  
Nataliya A. Belogorlova ◽  
Vladimir A. Shagun ◽  
...  
Keyword(s):  
Solvent Free ◽  
Secondary Phosphine ◽  
Stereoselective Addition ◽  
Secondary Phosphine Chalcogenides ◽  
Phosphine Chalcogenides

Catalyst- and Solvent-Free Stereoselective Addition of Secondary Phosphine Chalcogenides to Alkynes

Synthesis ◽  
2014 ◽  
Vol 47 (02) ◽  
pp. 263-271
Author(s):  
Boris Trofimov ◽  
Alexander Artem’ev ◽  
Svetlana Malysheva ◽  
Nina Gusarova ◽  
Nataliya Belogorlova ◽  
...  
Keyword(s):  
Solvent Free ◽  
Secondary Phosphine ◽  
Stereoselective Addition ◽  
Secondary Phosphine Chalcogenides ◽  
Phosphine Chalcogenides

Solvent-free synthesis of 4-chalcogenophosphorylpyridines via SNHAr reaction of pyridines with secondary phosphine chalcogenides

2018 ◽  
Vol 28 (6) ◽  
pp. 582-583 ◽  
Author(s):  
Pavel A. Volkov ◽  
Nina I. Ivanova ◽  
Kseniya O. Khrapova ◽  
Anton A. Telezhkin ◽  
Tatyana N. Borodina ◽  
...  
Keyword(s):  
Solvent Free ◽  
Secondary Phosphine ◽  
Secondary Phosphine Chalcogenides ◽  
Solvent Free Synthesis ◽  
Phosphine Chalcogenides

Catalyst- and Solvent-Free Addition of the P–H Species to Alkenes and Alkynes: A Green Methodology for C–P Bond Formation

Synthesis ◽  
2017 ◽  
Vol 49 (21) ◽  
pp. 4783-4807 ◽  
Author(s):  
Boris Trofimov ◽  
Nina Gusarova ◽  
Nataliya Chernysheva
Keyword(s):  
Organophosphorus Compounds ◽  
Bond Formation ◽  
Solvent Free ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Secondary Phosphine Chalcogenides ◽  
Vinyl Sulfides ◽  
Radical Initiators ◽  
Phosphine Chalcogenides ◽  
Secondary Phosphines

Traditional methods for C–P bond formation via direct addition of P–H species to unsaturated compounds are usually implemented in the presence of base and metal catalysts or radical initiators in various organic solvents. During the last five years, a novel efficient and general catalyst/initiator- and solvent-free version of the hydrophosphination and hydrophosphinylation of multiple C–C bonds with H-phosphines and their chalcogenides has begun to develop and it is attracting growing attention. This approach corresponds to the recently emerged pot-, atom-, and step-economy (PASE) green paradigm. This review covers the literature on the synthesis of useful and in-demand organophosphorus compounds via catalyst- and solvent-free addition of P–H species to alkenes and alkynes.1 Introduction2 Addition of Secondary Phosphines to Alkenes3 Hydrophosphinylation of Alkenes with Secondary Phosphine Chalcogenides3.1 Oxidative Addition of Phosphine Oxides to Vinyl Sulfides3.2 Addition of Secondary Phosphine Sulfides and Phosphine Selenides to Alkenes3.3 Addition of Secondary Phosphine Sulfides and Phosphine Selenides to Divinyl Chalcogenides3.4 Hydrophosphinylation of Alkenes with Secondary Phosphine/Chalcogen Pair (Three-Component Reactions)4 Addition of Secondary Phosphines to Alkynes5 Addition of Secondary Phosphine Chalcogenides to Alkynes6 Conclusion

Non-catalyzed addition of secondary phosphine chalcogenides to divinyl chalcogenides under solvent-free conditions

2016 ◽  
Vol 37 (5) ◽  
pp. 488-500
Author(s):  
Nina K. Gusarova ◽  
Nataliya A. Chernysheva ◽  
Svetlana V. Yas’ko ◽  
Lyudmila V. Klyba ◽  
Boris A. Trofimov
Keyword(s):  
Solvent Free ◽  
Secondary Phosphine ◽  
Secondary Phosphine Chalcogenides ◽  
Solvent Free Conditions ◽  
Phosphine Chalcogenides

Catalyst- and Solvent-Free Rapid Addition of Secondary Phosphine Chalcogenides to Aldehydes: Another Click Chemistry

Synthesis ◽  
2015 ◽  
Vol 47 (11) ◽  
pp. 1611-1622 ◽  
Author(s):  
Nina Gusarova ◽  
Nina Ivanova ◽  
Pavel Volkov ◽  
Kseniya Khrapova ◽  
Luydmila Larina ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Solvent Free ◽  
Secondary Phosphine ◽  
Efficient Catalyst ◽  
Mild Conditions ◽  
Secondary Phosphine Chalcogenides ◽  
Phosphine Chalcogenides

An efficient catalyst- and solvent-free method for the synthesis of tertiary α-hydroxyphosphine chalcogenides, via the almost quantitative addition of secondary phosphine chalcogenides to diverse aldehydes under mild conditions (20–52 °C, from 10 min to 5 h), is reported.

ChemInform Abstract: Catalyst- and Solvent-Free Rapid Addition of Secondary Phosphine Chalcogenides to Aldehydes: Another Click Chemistry.

ChemInform ◽  
2015 ◽  
Vol 46 (41) ◽  
pp. no-no
Author(s):  
Nina K. Gusarova ◽  
Nina I. Ivanova ◽  
Pavel A. Volkov ◽  
Kseniya O. Khrapova ◽  
Luydmila I. Larina ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Solvent Free ◽  
Secondary Phosphine ◽  
Secondary Phosphine Chalcogenides ◽  
Phosphine Chalcogenides

An Expedient Access to γ-Ketophosphine Chalcogenides via the Chemo- and Regioselective Addition of Secondary Phosphine Chalcogenides to β,γ-Ethylenic Ketones

2015 ◽  
Vol 26 (6) ◽  
pp. 455-462 ◽  
Author(s):  
Alexander V. Artem'ev ◽  
Svetlana F. Malysheva ◽  
Nataliya A. Belogorlova ◽  
Nadezhda I. Protzuk ◽  
Alexander I. Albanov ◽  
...  
Keyword(s):  
Secondary Phosphine ◽  
Secondary Phosphine Chalcogenides ◽  
Regioselective Addition ◽  
Phosphine Chalcogenides

One-pot reductive N-vinylation and C(4)-phosphorylation of pyridines with alkyl propiolates and secondary phosphine chalcogenides

2015 ◽  
Vol 56 (33) ◽  
pp. 4804-4806 ◽  
Author(s):  
Nina K. Gusarova ◽  
Pavel A. Volkov ◽  
Nina I. Ivanova ◽  
Svetlana N. Arbuzova ◽  
Kseniya O. Khrapova ◽  
...  
Keyword(s):  
Secondary Phosphine ◽  
One Pot ◽  
Secondary Phosphine Chalcogenides ◽  
Alkyl Propiolates ◽  
Phosphine Chalcogenides

ChemInform Abstract: One-Pot Reductive N-Vinylation and C(4)-Phosphorylation of Pyridines with Alkylpropiolates and Secondary Phosphine Chalcogenides.

ChemInform ◽  
2015 ◽  
Vol 46 (47) ◽  
pp. no-no
Author(s):  
Nina K. Gusarova ◽  
Pavel A. Volkov ◽  
Nina I. Ivanova ◽  
Svetlana N. Arbuzova ◽  
Kseniya O. Khrapova ◽  
...  
Keyword(s):  
Secondary Phosphine ◽  
One Pot ◽  
Secondary Phosphine Chalcogenides ◽  
Phosphine Chalcogenides
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