ChemInform Abstract: Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation.

ChemInform ◽  
2015 ◽  
Vol 46 (22) ◽  
pp. no-no
Author(s):  
Katerina M. Korch ◽  
Christian Eidamshaus ◽  
Douglas C. Behenna ◽  
Sangkil Nam ◽  
David Horne ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Asymmetric

scholarly journals Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation

2014 ◽  
Vol 54 (1) ◽  
pp. 179-183 ◽  
Author(s):  
Katerina M. Korch ◽  
Christian Eidamshaus ◽  
Douglas C. Behenna ◽  
Sangkil Nam ◽  
David Horne ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Asymmetric

scholarly journals Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation

2014 ◽  
Vol 127 (1) ◽  
pp. 181-185 ◽  
Author(s):  
Katerina M. Korch ◽  
Christian Eidamshaus ◽  
Douglas C. Behenna ◽  
Sangkil Nam ◽  
David Horne ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Asymmetric

Novel Chiral Ligands for Palladium-catalyzed Asymmetric Allylic Alkylation/ Asymmetric Tsuji-Trost Reaction: A Review

2019 ◽  
Vol 23 (11) ◽  
pp. 1168-1213 ◽  
Author(s):  
Samar Noreen ◽  
Ameer Fawad Zahoor ◽  
Sajjad Ahmad ◽  
Irum Shahzadi ◽  
Ali Irfan ◽  
...  
Keyword(s):  
Asymmetric Catalysis ◽  
Enantioselective Synthesis ◽  
Chiral Ligands ◽  
Allylic Alkylation ◽  
Research Groups ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Potential ◽  
Long Time ◽  
Palladium Catalyzed ◽  
Alkylation Reactions

Background: Asymmetric catalysis holds a prestigious role in organic syntheses since a long time and chiral inductors such as ligands have been used to achieve the utmost desired results at this pitch. The asymmetric version of Tsuji-Trost allylation has played a crucial role in enantioselective synthesis. Various chiral ligands have been known for Pdcatalyzed Asymmetric Allylic Alkylation (AAA) reactions and exhibited excellent catalytic potential. The use of chiral ligands as asymmetric inductors has widened the scope of Tsuji-Trost allylic alkylation reactions. Conclusion: Therefore, in this review article, a variety of chiral inductors or ligands have been focused for palladium catalyzed asymmetric allylic alkylation (Tsuji-Trost allylation) and in this regard, recently reported literature (2013-2017) has been described. The use of ligands causes the induction of enantiodiscrimination to the allylated products, therefore, the syntheses of various kinds of ligands have been targeted by many research groups to employ in Pd-catalyzed AAA reactions.

Catalytic Asymmetric Allylic Alkylation of 3-Arylated Piperidin-2-ones

2013 ◽  
Vol 2013 (22) ◽  
pp. 4979-4985 ◽  
Author(s):  
Christophe Michon ◽  
Aurélien Béthegnies ◽  
Frédéric Capet ◽  
Pascal Roussel ◽  
Arnault de Filippis ◽  
...  
Keyword(s):  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Asymmetric

A C(aryl)N(amine) bond atropisomeric aminophosphine: preparation and use as a ligand in a catalytic asymmetric allylic alkylation

2003 ◽  
Vol 14 (17) ◽  
pp. 2503-2506 ◽  
Author(s):  
Takashi Mino ◽  
Youichi Tanaka ◽  
Toshihiro Yabusaki ◽  
Daisuke Okumura ◽  
Masami Sakamoto ◽  
...  
Keyword(s):  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Asymmetric

A C(Aryl)—N(Amine) Bond Atropisomeric Aminophosphine: Preparation and Use as a Ligand in a Catalytic Asymmetric Allylic Alkylation.

ChemInform ◽  
2003 ◽  
Vol 34 (52) ◽  
Author(s):  
Takashi Mino ◽  
Youichi Tanaka ◽  
Toshihiro Yabusaki ◽  
Daisuke Okumura ◽  
Masami Sakamoto ◽  
...  
Keyword(s):  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Asymmetric
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