ChemInform Abstract: Polymer Anchored Ruthenium Complex: A Highly Active and Recyclable Catalyst for One-Pot Azide-Alkyne Cycloaddition and Transfer-Hydrogenation of Ketones under Mild Conditions.

ChemInform ◽  
2015 ◽  
Vol 46 (22) ◽  
pp. no-no
Author(s):  
Rostam Ali Molla ◽  
Anupam Singha Roy ◽  
Kajari Ghosh ◽  
Noor Salam ◽  
Md Asif Iqubal ◽  
...  
2017 ◽  
Vol 4 (8) ◽  
pp. 1636-1639 ◽  
Author(s):  
Bin Cheng ◽  
Bian Bao ◽  
Yanhe Chen ◽  
Ning Wang ◽  
Yun Li ◽  
...  

A new route to arylhydrazides involving the reaction of two highly active intermediates, the 1,3-zwitterion generated in situ from the Mitsunobu reagent and arynes, under mild conditions has been developed.


2020 ◽  
Vol 16 ◽  
pp. 482-491
Author(s):  
Faïma Lazreg ◽  
Marie Vasseur ◽  
Alexandra M Z Slawin ◽  
Catherine S J Cazin

A new catalytic strategy for the one-pot synthesis of N-sulfonylamidines is described. The cationic copper(I) complexes were found to be highly active and efficient under mild conditions in air and in the absence of solvent. A copper acetylide is proposed as key intermediate in this transformation.


RSC Advances ◽  
2014 ◽  
Vol 4 (79) ◽  
pp. 42155-42158 ◽  
Author(s):  
Siyavash Kazemi Movahed ◽  
Noushin Farajinia Lehi ◽  
Minoo Dabiri

A novel gold nanoparticle supported on graphene oxide with ionic liquid framework was used as a highly active and recyclable catalyst for novel domino oxidative A3-coupling reaction.


Synthesis ◽  
2020 ◽  
Vol 52 (22) ◽  
pp. 3439-3445
Author(s):  
Lu Ouyang ◽  
Renshi Luo ◽  
Nianhua Luo ◽  
Yuhong Zhong ◽  
Ji-Tian Liu

A practical and efficient method for the synthesis of alcohols in one pot from readily available alkynes via a tandem process by formic acid promoted hydration and metal-ligand bifunctional iridium-catalyzed­ transfer hydrogenation under mild conditions has been described. This transformation is simple, efficient, and can be performed with a variety of alkynes in good yields and with excellent stereoselectivities. Experimental results showed high catalytic activity, and turnover frequency (TOF) up to 25000. Importantly, this transformation can be conducted in water, and is thus green and environmentally friendly.


RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 93463-93469 ◽  
Author(s):  
Bo Qiao ◽  
Le Zhang ◽  
Rong Li

A new simple catalytic system consisting of copper-aluminium and hydrotalcite (CuAl–HT) has been developed using a facile one-pot method without harm to the environment.


2016 ◽  
Vol 45 (27) ◽  
pp. 11162-11171 ◽  
Author(s):  
Bhaskar Paul ◽  
Kaushik Chakrabarti ◽  
Sabuj Kundu

A rare example of a highly active bifunctional Ru(ii) catalyst containing only one 2-hydroxypyridine (2-HP) unit is presented which exhibited exceptionally high catalytic activity in transfer hydrogenation of ketones and nitriles.


2016 ◽  
Vol 40 (1) ◽  
pp. 372-376 ◽  
Author(s):  
Weidong Jiang ◽  
Zhen Xiang ◽  
Bin Xu ◽  
Xiaojing Li ◽  
Fuan Liu ◽  
...  

Highly active Pd/RGO (RGO, reduced graphene oxide) was easily prepared by a one pot co-reduction of Pd ions and GO using NaBH4. The as-prepared catalyst exhibited excellent reactivity towards the degradation of chlorophenols under mild conditions without additives.


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