ChemInform Abstract: Transition-Metal-Free Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones under Neutral Conditions: A Simple Access to 1,3-Diketones.

ChemInform ◽  
2015 ◽  
Vol 46 (22) ◽  
pp. no-no
Author(s):  
Zhen He ◽  
Xiaotian Qi ◽  
Shiqing Li ◽  
Yinsong Zhao ◽  
Ge Gao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Free ◽  
Decarboxylative Coupling ◽  
Neutral Conditions

Transition-metal-free cross-dehydrogenative alkylation of pyridines under neutral conditions

2013 ◽  
Vol 37 (6) ◽  
pp. 1704 ◽  
Author(s):  
Xin Li ◽  
Hao-Yuan Wang ◽  
Zhang-Jie Shi
Keyword(s):  
Transition Metal ◽  
Metal Free ◽  
Neutral Conditions

Lactamization of sp2 C–H bonds with CO2 under transition-metal-free and redox-neutral conditions: a computational mechanistic study

2018 ◽  
Vol 5 (14) ◽  
pp. 2189-2201 ◽  
Author(s):  
Weiyi Li ◽  
Caiqin Li ◽  
Yajing Lyu
Keyword(s):  
Transition Metal ◽  
Stage Ii ◽  
Mechanistic Study ◽  
Primary Role ◽  
Metal Free ◽  
Neutral Conditions

Bases play the primary role in Stages (I) and (III). CO2 serves as an atomic oxidant [O] acceptor in Stage (II).

Transition-metal free direct C–H functionalization of quinoxalin-2(1H)-ones with oxamic acids leading to 3-carbamoyl quinoxalin-2(1H)-ones

2020 ◽  
Vol 7 (2) ◽  
pp. 273-285 ◽  
Author(s):  
Jin-Wei Yuan ◽  
Jun-Liang Zhu ◽  
Hu-Lin Zhu ◽  
Fang Peng ◽  
Liang-Yu Yang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Coupling Reaction ◽  
Metal Free ◽  
Mild Conditions ◽  
Decarboxylative Coupling

A practical transition-metal free decarboxylative coupling reaction of oxamic acids with quinoxalin-2(1H)-ones has been developed under mild conditions.

Transition-metal-free synthesis of vinyl sulfones via tandem cross-decarboxylative/coupling reactions of sodium sulfinates and cinnamic acids

2014 ◽  
Vol 16 (8) ◽  
pp. 3720-3723 ◽  
Author(s):  
Yanli Xu ◽  
Xiaodong Tang ◽  
Weigao Hu ◽  
Wanqing Wu ◽  
Huanfeng Jiang
Keyword(s):  
Transition Metal ◽  
Coupling Reactions ◽  
Cinnamic Acids ◽  
Metal Free ◽  
Decarboxylative Coupling

A transition-metal-free synthesis of vinyl sulfones, utilizing sodium sulfinates and cinnamic acids through tandem cross-decarboxylative/coupling reactions, has been developed.

Transition-Metal-Free Decarboxylative Coupling Reactions for the Synthesis of Propargyl Alcohols

2016 ◽  
Vol 5 (9) ◽  
pp. 1148-1154 ◽  
Author(s):  
Francis Mariaraj Irudayanathan ◽  
Jimin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Transition Metal ◽  
Coupling Reactions ◽  
Metal Free ◽  
Decarboxylative Coupling ◽  
Propargyl Alcohols
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