ChemInform Abstract: Catalytic Enantioselective Organic Transformations via Visible Light Photocatalysis

ChemInform ◽  
2015 ◽  
Vol 46 (20) ◽  
pp. no-no
Author(s):  
Chengfeng Wang ◽  
Zhan Lu
Keyword(s):  
Visible Light ◽  
Visible Light Photocatalysis ◽  
Organic Transformations

Rhodamines as Photocatalyst in Organic Synthesis

2020 ◽  
Vol 07 ◽  
Author(s):  
Avik K. Bagdi ◽  
Papiya Sikdar
Keyword(s):  
Visible Light ◽  
Organic Synthesis ◽  
Organic Dyes ◽  
Transition Metal Catalysts ◽  
Visible Light Photocatalysis ◽  
Eosin Y ◽  
Organic Transformations ◽  
The Sustainable Development ◽  
Mechanistic Pathway ◽  
Green Model

Abstract:: Organic synthesis under environment friendly conditions has great impact in the sustainable development. In this context, visible light photocatalysis has emerged as a green model as this offers an energy-efficient pathway towards the organic transformation. Different transition-metal catalysts (Ir-, Ru-, Cu- etc) and organic dyes (eosin Y, rose bengal, methylene blue etc) are well-known photocatalysts in organic synthesis. Apart from the well-known organophotoredox catalysts, rhodamines (Rhodamine B and Rhodamine 6G) have been also employed as efficient photocatalysts for different organic transformations. In this review, we will focus on the photocatalysis by rhodamines in organic synthesis. Mechanistic pathway of the methodologies will also be discussed. We believe this review will stimulate the employment of rhodamines in the visible light photocatalysis for efficient organic transformations in the future.

A recyclable self-assembled composite catalyst consisting of Fe3O4-rose bengal-layered double hydroxides for highly efficient visible light photocatalysis in water

2018 ◽  
Vol 54 (96) ◽  
pp. 13587-13590 ◽  
Author(s):  
Yuxing Huang ◽  
Zhuo Xin ◽  
Wenlong Yao ◽  
Qi Hu ◽  
Zhuohua Li ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Rose Bengal ◽  
Layered Double Hydroxides ◽  
Self Assembly ◽  
High Efficiency ◽  
Composite Catalyst ◽  
Visible Light Photocatalysis ◽  
Organic Transformations ◽  
Double Hydroxides

A novel recyclable composite catalyst (Fe3O4-RB/LDH) formed by stable self-assembly of Fe3O4 NPs, rose bengal, and layered double hydroxides can catalyze various organic transformations with high efficiency in water under visible light irradiation.

scholarly journals Controlling the Optical and Catalytic Properties of Artificial Metalloenzyme Photocatalysts Using Chemogenetic Engineering

2022 ◽  
Author(s):  
Yasmine S Zubi ◽  
Bingqing Liu ◽  
Yifan Gu ◽  
Dipankar Sahoo ◽  
Jared C Lewis
Keyword(s):  
Energy Transfer ◽  
Visible Light ◽  
Catalytic Properties ◽  
Single Electron ◽  
Visible Light Photocatalysis ◽  
Organic Transformations ◽  
Polypyridyl Complexes ◽  
Artificial Metalloenzyme

Visible light photocatalysis enables a broad range of organic transformations that proceed via single electron or energy transfer. Metal polypyridyl complexes are among the most commonly employed visible light photocatalysts....

scholarly journals Heterogeneous visible light photocatalysis for selective organic transformations

2014 ◽  
Vol 43 (1) ◽  
pp. 473-486 ◽  
Author(s):  
Xianjun Lang ◽  
Xiaodong Chen ◽  
Jincai Zhao
Keyword(s):  
Visible Light ◽  
Visible Light Photocatalysis ◽  
Organic Transformations

Catalytic enantioselective organic transformations via visible light photocatalysis

2015 ◽  
Vol 2 (2) ◽  
pp. 179-190 ◽  
Author(s):  
Chengfeng Wang ◽  
Zhan Lu
Keyword(s):  
Visible Light ◽  
Visible Light Photocatalysis ◽  
Strong Impact ◽  
Organic Transformations

Enantioselective transformations via visible light photocatalysis are discussed and could have a strong impact on asymmetric photoreactions.

Carbon quantum dot-sensitized hollow TiO2 spheres for high-performance visible light photocatalysis

2021 ◽  
Author(s):  
Xianfeng Zhang ◽  
Zongqun Li ◽  
Shaowen Xu ◽  
Yaowen Ruan
Keyword(s):  
Quantum Dots ◽  
Quantum Dot ◽  
Visible Light ◽  
Photocatalytic Degradation ◽  
High Performance ◽  
Carbon Quantum Dots ◽  
Visible Light Photocatalysis ◽  
Carbon Quantum Dot ◽  
Visible Light Photocatalytic

TiO2/CQD composites were synthesized through carbon quantum dots covalently attached to the surface of hollow TiO2 spheres for visible light photocatalytic degradation of organics.

A Donor–Acceptor [2]Catenane for Visible Light Photocatalysis

2021 ◽  
Author(s):  
Yang Jiao ◽  
Luka Đorđević ◽  
Haochuan Mao ◽  
Ryan M. Young ◽  
Tyler Jaynes ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Photocatalysis ◽  
Donor Acceptor

scholarly journals Mizoroki–Heck type reactions and synthesis of 1,4-dicarbonyl compounds by heterogeneous organic semiconductor photocatalysis

2021 ◽  
Vol 23 (5) ◽  
pp. 2017-2024
Author(s):  
Jagadish Khamrai ◽  
Saikat Das ◽  
Aleksandr Savateev ◽  
Markus Antonietti ◽  
Burkhard König
Keyword(s):  
Visible Light ◽  
Vinyl Acetate ◽  
Organic Semiconductor ◽  
Alkyl Halides ◽  
Visible Light Photocatalysis ◽  
Dicarbonyl Compounds ◽  
Semiconductor Photocatalysis ◽  
Type Coupling ◽  
Styrene Derivatives ◽  
Tertiary Alkyl

We report the synthesis of 1,4-dicarbonyl compounds and substituted alkenes (Mizoroki–Heck type coupling) starting from secondary and tertiary alkyl halides and vinyl acetate or styrene derivatives using visible-light photocatalysis.

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