A facile route for the chemo-selective synthesis of pyrrolo[2,3,4-kl]acridin-1-ones via ring-opening or amidic C–N bond cleavage of isatin under microwave irradiation using Ag NPs/rGO composite as an effective and robust catalyst has been described.
Aluminium-mediated selective synthesis of benzo[f]tetraphenes or benzo[g]chrysenes was achieved via aromatic C–F bond cleavage and regioselective C–C bond formation.
A reduction and sequential silver-mediated Appel reaction/C–Br cleavage/double rearrangement cascade strategy was developed for the selective synthesis of chromeno[4,3-b]quinolines and spirobenzofuran-3,3′-quinolines.