ChemInform Abstract: An Efficient and Reusable Vanadium Based Catalytic System for Room Temperature Oxidation of Alcohols to Aldehydes and Ketones.

ChemInform ◽  
2015 ◽  
Vol 46 (7) ◽  
pp. no-no
Author(s):  
Gayatri Sarmah ◽  
Saitanya K. Bharadwaj ◽  
Anindita Dewan ◽  
Ankur Gogoi ◽  
Utpal Bora
2014 ◽  
Vol 55 (36) ◽  
pp. 5029-5032 ◽  
Author(s):  
Gayatri Sarmah ◽  
Saitanya K. Bharadwaj ◽  
Anindita Dewan ◽  
Ankur Gogoi ◽  
Utpal Bora

RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 103088-103094 ◽  
Author(s):  
Jesús Sanmartín-Matalobos ◽  
Concepcion González-Bello ◽  
Lucía Briones-Miguéns ◽  
Matilde Fondo ◽  
Ana M. García-Deibe

The degradation under ambient humidity and room temperature of Pd(OAc)2(NEt3), which is an efficient catalyst for the aerobic oxidation of alcohols, to diethylamine and acetaldehyde derivatives is disclosed.


2001 ◽  
Vol 123 (28) ◽  
pp. 6826-6833 ◽  
Author(s):  
Arné Dijksman ◽  
Arturo Marino-González ◽  
Antoni Mairata i Payeras ◽  
Isabel W. C. E. Arends ◽  
Roger A. Sheldon

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Fatemeh Azimi ◽  
Ahmad Poursattar Marjani ◽  
Sajjad Keshipour

AbstractManipulation of materials is considered as one of the eminent strategies to create desirable catalysts. In this regard, increasing surface area and decreasing dimensions of catalysts have been widely employed on account of effectiveness of these methods. Herein, aerogel form of chitosan as a sustainable, and high aspect ratio compound is employed as a green support for the catalytic purposes. Chitosan aerogel was modified with Fe(II)-phthalocyanine to produce a heterogeneous catalyst for oxidation reactions. The synthesized catalyst promoted the oxidation reactions of alcohols and alkyl arenes to the corresponding aldehydes and ketones using H2O2 as an oxidant in 24 h. The reactions for aliphatic and aromatic alcohols gave turnover numbers of 106–109 at 80 °C and 106–117 at room temperature, respectively. The oxidations of alkyl arenes were carried out with turnover numbers laying in the range of 106–117 at 100 °C. The low toxicity, inexpensive nature, and recycling possibility of the catalyst accompanied by the reaction mild conditions, clean oxidant, and excellent yields offer chitosan aerogel modified with Fe(II)-phthalocyanine as a promising catalyst for oxidation reactions.


ChemInform ◽  
2010 ◽  
Vol 32 (44) ◽  
pp. no-no
Author(s):  
Arne Dijksman ◽  
Artuoro Marino-Gonzalez ◽  
Antoni Mairata i Payeras ◽  
Isabel W. C. E. Arends ◽  
Roger A. Sheldon

RSC Advances ◽  
2021 ◽  
Vol 11 (52) ◽  
pp. 32942-32954
Author(s):  
Ravi Kumar Cheedarala ◽  
Ramasamy R. Chidambaram ◽  
Ayyanar Siva ◽  
Jung Il Song

We have reported an aerobic oxidation of primary and secondary alcohols to respective aldehydes and ketones using a bipyridyl-cinchona alkaloid based palladium catalytic system (PdAc-5) using oxygen at moderate pressure.


2016 ◽  
Vol 6 (9) ◽  
pp. 3208-3213 ◽  
Author(s):  
McKenzie L. Campbell ◽  
Dino Sulejmanovic ◽  
Jacqueline B. Schiller ◽  
Emily M. Turner ◽  
Shiou-Jyh Hwu ◽  
...  

Herein we present some initial results demonstrating the room temperature oxidation of secondary alcohols catalyzed by the reduced salt-inclusion polyoxometalate, Cs5(V14As8O42Cl).


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