ChemInform Abstract: Stimuli-Responsive Metallo-Supramolecular Polymer Films: Design, Synthesis and Device Fabrication

ChemInform ◽  
2014 ◽  
Vol 45 (52) ◽  
pp. no-no
Author(s):  
Masayoshi Higuchi
Keyword(s):  
Polymer Films ◽  
Device Fabrication ◽  
Supramolecular Polymer ◽  
Stimuli Responsive ◽  
Design Synthesis ◽  
Abstract Stimuli

Stimuli-responsive metallo-supramolecular polymer films: design, synthesis and device fabrication

2014 ◽  
Vol 2 (44) ◽  
pp. 9331-9341 ◽  
Author(s):  
Masayoshi Higuchi
Keyword(s):  
Polymer Films ◽  
Chemical Properties ◽  
Device Fabrication ◽  
Supramolecular Polymer ◽  
Stimuli Responsive ◽  
Design Synthesis ◽  
Metal Interactions ◽  
Metal Metal ◽  
Metal Ligand

Based on the metal–ligand or metal–metal interactions, metallo-supramolecular polymer films showed stimuli-responsive electro- and photo-chemical properties such as electrochromism.

Sensitive Mechanocontrolled Luminescence in Cross-Linked Polymer Films

2019 ◽  
Author(s):  
Ayumu Karimata ◽  
Pradnya Patil ◽  
Eugene Khaskin ◽  
Sébastien Lapointe ◽  
robert fayzullin ◽  
...  
Keyword(s):  
Mechanical Stress ◽  
Polymer Films ◽  
Soft Matter ◽  
Small Strain ◽  
Visual Methods ◽  
Photoluminescence Intensity ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Highly Sensitive ◽  
Mechanical Stretching

Direct translation of mechanical force into changes in chemical behavior on a molecular level has important implication not only for the fundamental understanding of mechanochemical processes, but also for the development of new stimuli-responsive materials. In particular, detection of mechanical stress in polymers via non-destructive methods is important in order to prevent material failure and to study the mechanical properties of soft matter. Herein, we report that highly sensitive changes in photoluminescence intensity can be observed in response to the mechanical stretching of cross-linked polymer films when using stable, (pyridinophane)Cu-based dynamic mechanophores. Upon stretching, the luminescence intensity increases in a fast and reversible manner even at small strain (< 50%) and applied stress (< 0.1 MPa) values. Such sensitivity is unprecedented when compared to previously reported systems based on organic mechanophores. The system also allows for the detection of weak mechanical stress by spectroscopic measurements or by direct visual methods.<br>

Dual-Stimuli-Responsive Fluorescent Supramolecular Polymer Based on a Diselenium-Bridged Pillar[5]arene Dimer and an AIE-Active Tetraphenylethylene Guest

2017 ◽  
Vol 50 (15) ◽  
pp. 5759-5766 ◽  
Author(s):  
Yan Wang ◽  
Ming-Zhe Lv ◽  
Nan Song ◽  
Zeng-Jie Liu ◽  
Chunyu Wang ◽  
...  
Keyword(s):  
Supramolecular Polymer ◽  
Stimuli Responsive

ChemInform Abstract: Stimuli-Responsive Nanogel Composites and Their Application in Nanomedicine

ChemInform ◽  
2015 ◽  
Vol 46 (42) ◽  
pp. no-no
Author(s):  
Maria Molina ◽  
Mazdak Asadian-Birjand ◽  
Juan Balach ◽  
Julian Bergueiro ◽  
Enrico Miceli ◽  
...  
Keyword(s):  
Stimuli Responsive ◽  
Abstract Stimuli

Dual Stimuli-Responsive Cross-Linked AIE Supramolecular Polymer Constructed through Hierarchical Self-Assembly

2018 ◽  
Vol 58 (11) ◽  
pp. 1265-1272 ◽  
Author(s):  
Chang-Wei Zhang ◽  
Shu-Ting Jiang ◽  
Guang-Qiang Yin ◽  
Xiaopeng Li ◽  
Xiao-Li Zhao ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Polymer ◽  
Stimuli Responsive

Multi-stimuli-responsive supramolecular gel constructed by pillar[5]arene-based pseudorotaxanes for efficient detection and separation of multi-analytes in aqueous solution

Soft Matter ◽  
2018 ◽  
Vol 14 (42) ◽  
pp. 8529-8536 ◽  
Author(s):  
You-Ming Zhang ◽  
Yong-Fu Li ◽  
Hu Fang ◽  
Jun-Xia He ◽  
Bi-Rong Yong ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Polymer Network ◽  
Water Soluble ◽  
Supramolecular Polymer ◽  
Stimuli Responsive ◽  
Supramolecular Gel ◽  
Efficient Detection ◽  
Detection And Separation

A novel pseudorotaxanes-type crosslinker of a supramolecular polymer network (WP5-PN) was constructed based on water-soluble pillar[5]arene (WP5) and naphthalene dimethylamine derivative (PN) via host-guest interactions.

Transparency and AIE tunable supramolecular polymer hydrogel acts as TEA–HCl vapor controlled smart optical material

Soft Matter ◽  
2020 ◽  
Vol 16 (24) ◽  
pp. 5734-5739 ◽  
Author(s):  
Xiao-Wen Sun ◽  
Zhong-Hui Wang ◽  
Ying-Jie Li ◽  
Hai-Long Yang ◽  
Guan-Fei Gong ◽  
...  
Keyword(s):  
Polymer Material ◽  
Potential Application ◽  
Optical Material ◽  
Supramolecular Polymer ◽  
Stimuli Responsive ◽  
Smart Window ◽  
Polymer Hydrogel ◽  
Vapor Treatment

A novel stimuli-responsive supramolecular polymer material was constructed by a tripodal gelator, which could act as an optical material and shows potential application in smart window or display materials, with TEA and HCl vapor treatment.

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