ChemInform Abstract: Synthesis of C3-Substituted Enantiopure 2-(p-Tolylsulfinyl)-furans: The Sulfoxide Group as a Chiral Inductor for Furan Dienes as Precursors of a Wide Variety of Chiral Intermediates.

ChemInform ◽  
2014 ◽  
Vol 45 (41) ◽  
pp. no-no
Author(s):  
Angel M. Montana ◽  
Pedro M. Grima ◽  
Consuelo Batalla ◽  
Gabriele Kociok-Koehn
Keyword(s):  
Chiral Intermediates ◽  
Sulfoxide Group

Carbohydrates as chiral intermediates in organic synthesis. Two functionalized chemical precursors comprising eight of the ten chiral centers of erythronolide A

1977 ◽  
Vol 55 (6) ◽  
pp. 1111-1113 ◽  
Author(s):  
Stephen Hanessian ◽  
Georges Rancourt
Keyword(s):  
Organic Synthesis ◽  
Chiral Intermediates ◽  
Chiral Centers ◽  
Branched Chain

Two appropriately functionalized branched-chain sugars have been synthesized as potentially useful chemical precursors to erythronolide A, encompassing its C-1–C-6 and C-9–C-15 segments respectively.

Synthesis of Valuable Chiral Intermediates by Isolated Ketoreductases: Application in the Synthesis of α-Alkyl-β-hydroxy Ketones and 1,3-Diols

2006 ◽  
Vol 348 (14) ◽  
pp. 1958-1969 ◽  
Author(s):  
Dimitris Kalaitzakis ◽  
J. David Rozzell ◽  
Ioulia Smonou ◽  
Spiros Kambourakis
Keyword(s):  
Chiral Intermediates ◽  
Hydroxy Ketones

scholarly journals Camphorae: chiral intermediates for the total synthesis of steroids

1977 ◽  
Vol 99 (18) ◽  
pp. 6105-6106 ◽  
Author(s):  
Robert V. Stevens ◽  
Fred C. A. Gaeta
Keyword(s):  
Total Synthesis ◽  
Chiral Intermediates

Chiral intermediates, edited by Cynthia A. Challener

Chirality ◽  
2002 ◽  
Vol 14 (10) ◽  
pp. 819-819
Author(s):  
Christopher J. Welch
Keyword(s):  
Chiral Intermediates

Chemoselective oxidation of phenoxathiin-based thiacalix[4]arene and the stereoselective alkylation of products

2018 ◽  
Vol 42 (24) ◽  
pp. 20074-20086 ◽  
Author(s):  
T. Landovský ◽  
H. Dvořáková ◽  
V. Eigner ◽  
M. Babor ◽  
M. Krupička ◽  
...  
Keyword(s):  
Reaction Conditions ◽  
High Yields ◽  
Exhaustive Oxidation ◽  
Sulfoxide Group

Phenoxathiin-based thiacalix[4]arene was subjected to exhaustive oxidation. Depending on the reaction conditions, the macrocyclic systems bearing four sulfonyl groups or three sulfonyl and one sulfoxide group are available in high yields.

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