ChemInform Abstract: Inorganic-Organic Hybrid with One-Dimensional Face-Sharing Iodoplumbate Chain Showing Novel Dielectric Anomaly and Semiconductor Emission.

ChemInform ◽  
2014 ◽  
Vol 45 (37) ◽  
pp. no-no
Author(s):  
Yan-Jun She ◽  
Shun-Ping Zhao ◽  
Zheng-Fang Tian ◽  
Xiao-Ming Ren
Keyword(s):  
Dielectric Anomaly ◽  
One Dimensional ◽  
Organic Hybrid ◽  
Dimensional Face

scholarly journals Synthesis, structure, semiconductive and photoluminescent properties of [{Eu(NC5H4COOH)3(H2O)2}(1.5ZnCl4)·(2H2O)]n

2009 ◽  
Vol 74 (7) ◽  
pp. 755-764 ◽  
Author(s):  
Wen-Tong Chen ◽  
Xiao-Niu Fang ◽  
Qiu-Yan Luo ◽  
Ya-Ping Xu
Keyword(s):  
Hydrothermal Reaction ◽  
Isonicotinic Acid ◽  
Luminescence Spectra ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
One Dimensional ◽  
X Ray ◽  
Organic Hybrid ◽  
Hybrid Complex ◽  
A Cell

A novel bimetallic 4f-3d metal-isonicotinic acid inorganic-organic hybrid complex [{Eu(NC5H4COOH)3(H2O)2}(1.5ZnCl4)?(2H2O)]n (1) was synthesized via a hydrothermal reaction and structurally characterized by single- crystal X-ray diffraction. Complex 1 crystallizes in the space group C2/c of the monoclinic system with eight formula units in a cell: a = 23.878(8) ?, b = 20.573(6) ?, c = 15.358(5) ?, ? = 127.276(5)?, V = 6003(3) ?3, C18H23Cl6EuN3O10Zn1.5, Mr = 904.11 g/mol, ? = 2.001 g/cm3, S = 1.077, ?(MoK?) = 3.846 mm-1, F(000) = 3536, R = 0.0270 and wR = 0.0672. Complex 1 has a characteristic, one-dimensional polycationic chain-like structure. A photoluminescent investigation revealed that the title complex displays intense emissions in the orange and red regions. The luminescence spectra show that the red emission is stronger than the orange emission. Optical absorption spectra of 1 revealed the presence of an optical gap of 3.56 eV.

Investigation of thermochromic photoluminescent, dielectric and crystal structural properties for an inorganic–organic hybrid solid of [1-hexyl-3-methylimidazolium][PbBr3]

2016 ◽  
Vol 40 (10) ◽  
pp. 8664-8672 ◽  
Author(s):  
Kun-Ming Wan ◽  
Yuan-Bo Tong ◽  
Li-Li Li-Li ◽  
Yang Zou ◽  
Hai-Bao Duan ◽  
...  
Keyword(s):  
Structural Properties ◽  
Dielectric Anomaly ◽  
Organic Hybrid ◽  
Crystal Structural

An imidazolium-based bromoplumbate hybrid solid shows fascinating luminescence thermochromism, appealing dielectric anomaly and relaxation.

3d - 4f Heterometallic Complexes for the Construction of POM-based Inorganic - Organic Hybrid Compounds: from Nanoclusters to One-Dimensional Ladder-Like Chains

2010 ◽  
Vol 63 (9) ◽  
pp. 1389 ◽  
Author(s):  
Dongying Du ◽  
Junsheng Qin ◽  
Shunli Li ◽  
Yaqian Lan ◽  
Xinlong Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Transition Metal Complexes ◽  
Lanthanide Complexes ◽  
Copper Complexes ◽  
Heterometallic Complexes ◽  
Magnetic Studies ◽  
One Dimensional ◽  
Organic Hybrid ◽  
Hybrid Compounds ◽  
Polyanion Chain

Three polyoxometalate-based inorganic–organic hybrid compounds, namely nanoclusters [Cu(en)2H2O]3[(α-SiW11O39)Nd(H2O)(η2,μ-1,1)-CH3COO]·3.5H2O (1) and [Cu(en)2H2O]3[(α-SiW11O39)Sm(H2O)(η2,μ-1,1)-CH3COO]·3H2O (2), and 1D H2[Cu(en)2H2O]8[Cu(en)2]3[{(α-SiW11O39)Ce(H2O)(η2,μ-1,1)-CH3COO}4]·22H2O (3) (en = 1,2-ethylenediamine) have been isolated. 1 and 2 are isomorphic and consist of [(α-SiW11O39)Ln(H2O)(η2,μ-1,1)-CH3COO]6– polyanions modified by [Cu(en)2H2O]2+ fragments. In 3, [Cu(en)2H2O]2+ are grafted on [(α-SiW11O39)Ce(H2O)(η2,μ-1,1)-CH3COO]6– polyanions and further connected by [Cu(en)2]2+ groups, representing the first example in polyoxometalate chemistry of a 1D ladder-like polyanion chain consisting of monovacant Keggin-type polyanions, lanthanide complexes and transition metal complexes. In these compounds, copper complexes coordinate to not only terminal O atoms but also bridging O atoms of the polyanions. Magnetic studies of 1 and 3 reveal weak antiferromagnetic interactions exist in them.

ChemInform Abstract: One-Dimensional Magnetic Inorganic-Organic Hybrid Nanomaterials

ChemInform ◽  
2011 ◽  
Vol 42 (23) ◽  
pp. no-no
Author(s):  
Jiayin Yuan ◽  
Youyong Xu ◽  
Axel H. E. Mueller
Keyword(s):  
Hybrid Nanomaterials ◽  
One Dimensional ◽  
Organic Hybrid

One-dimensional photonic crystal slot waveguide for silicon-organic hybrid electro-optic modulators

2017 ◽  
Author(s):  
Hai Yan ◽  
Xiaochuan Xu ◽  
Chi-Jui Chung ◽  
Harish Subbaraman ◽  
Zeyu Pan ◽  
...  
Keyword(s):  
Photonic Crystal ◽  
Slot Waveguide ◽  
One Dimensional ◽  
Dimensional Photonic Crystal ◽  
Organic Hybrid ◽  
Electro Optic

scholarly journals One-dimensional photonic crystal slot waveguide for silicon-organic hybrid electro-optic modulators

2016 ◽  
Vol 41 (23) ◽  
pp. 5466 ◽  
Author(s):  
Hai Yan ◽  
Xiaochuan Xu ◽  
Chi-Jui Chung ◽  
Harish Subbaraman ◽  
Zeyu Pan ◽  
...  
Keyword(s):  
Photonic Crystal ◽  
Slot Waveguide ◽  
One Dimensional ◽  
Dimensional Photonic Crystal ◽  
Organic Hybrid ◽  
Electro Optic

scholarly journals One-dimensional magnetic inorganic–organic hybrid nanomaterials

2011 ◽  
Vol 40 (2) ◽  
pp. 640 ◽  
Author(s):  
Jiayin Yuan ◽  
Youyong Xu ◽  
Axel H. E. Müller
Keyword(s):  
Hybrid Nanomaterials ◽  
One Dimensional ◽  
Organic Hybrid
Sign in / Sign up

Export Citation Format

Share Document