ChemInform Abstract: One-Pot Synthesis and Applications of N-Heteroaryl Iodonium Salts.

ChemInform ◽  
2014 ◽  
Vol 45 (34) ◽  
pp. no-no
Author(s):  
Marcin Bielawski ◽  
Joel Malmgren ◽  
Leticia M. Pardo ◽  
Ylva Wikmark ◽  
Berit Olofsson
Keyword(s):  
One Pot ◽  
Iodonium Salts ◽  
One Pot Synthesis

One-Pot Synthesis and Conformational Analysis of 6-Membered Cyclic Iodonium Salts

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
Bronsted Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Iodonium Salts ◽  
Efficient Approach ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>

scholarly journals One-Pot Synthesis and Applications of N-Heteroaryl Iodonium Salts

ChemistryOpen ◽  
2014 ◽  
Vol 3 (1) ◽  
pp. 19-22 ◽  
Author(s):  
Marcin Bielawski ◽  
Joel Malmgren ◽  
Leticia M. Pardo ◽  
Ylva Wikmark ◽  
Berit Olofsson
Keyword(s):  
One Pot ◽  
Iodonium Salts ◽  
One Pot Synthesis

One-Pot Synthesis and Conformational Analysis of Six-Membered Cyclic Iodonium Salts

2020 ◽  
Vol 85 (14) ◽  
pp. 9161-9178
Author(s):  
Lucien D. Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris J. Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
One Pot ◽  
Iodonium Salts ◽  
One Pot Synthesis

scholarly journals One-Pot Synthesis and Conformational Analysis of 6-Membered Cyclic Iodonium Salts

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
Bronsted Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Iodonium Salts ◽  
Efficient Approach ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>

Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies

2016 ◽  
Vol 81 (5) ◽  
pp. 1998-2009 ◽  
Author(s):  
Thomas L. Seidl ◽  
Sunil K. Sundalam ◽  
Brennen McCullough ◽  
David R. Stuart
Keyword(s):  
One Pot ◽  
Iodonium Salts ◽  
One Pot Synthesis ◽  
Synthetic Studies

ChemInform Abstract: Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies.

ChemInform ◽  
2016 ◽  
Vol 47 (29) ◽  
Author(s):  
Thomas L. Seidl ◽  
Sunil K. Sundalam ◽  
Brennen McCullough ◽  
David R. Stuart
Keyword(s):  
One Pot ◽  
Iodonium Salts ◽  
One Pot Synthesis ◽  
Synthetic Studies

scholarly journals One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid

2018 ◽  
Vol 14 ◽  
pp. 849-855 ◽  
Author(s):  
Natalia Soldatova ◽  
Pavel Postnikov ◽  
Olga Kukurina ◽  
Viktor V Zhdankin ◽  
Akira Yoshimura ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Facile Synthesis ◽  
One Pot ◽  
Iodonium Salts ◽  
Wide Applicability ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts ◽  
Aryl Iodides

A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination–oxidation sequence.

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