ChemInform Abstract: One-Pot Synthesis of Various Xanthene Derivatives Using Ionic Liquid 1,3-Disulfonic Acid Imidazolium Hydrogen Sulfate as an Efficient and Reusable Catalyst under Solvent-Free Conditions.

ChemInform ◽  
2014 ◽  
Vol 45 (28) ◽  
pp. no-no ◽  
Author(s):  
Farhad Shirini ◽  
Asieh Yahyazadeh ◽  
Kamal Mohammadi
Keyword(s):  
Ionic Liquid ◽  
Solvent Free ◽  
Disulfonic Acid ◽  
Reusable Catalyst ◽  
Hydrogen Sulfate ◽  
One Pot ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
Xanthene Derivatives

An efficient and reusable ionic liquid catalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes under solvent-free conditions

RSC Advances ◽  
2014 ◽  
Vol 4 (68) ◽  
pp. 36031-36035 ◽  
Author(s):  
Anlian Zhu ◽  
Shukun Bai ◽  
Wei Jin ◽  
Ruixia Liu ◽  
Lingjun Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Synergetic Effect ◽  
Solvent Free ◽  
Reusable Catalyst ◽  
One Pot ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
To Come ◽  
The One ◽  
Catalytic Performances

Ionic liquid [DMEA][HSO4] was found to be an efficient and reusable catalyst for the one-pot synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes under solvent-free conditions. The excellent catalytic performances are believed to come from the synergetic effect of the cation and anion of the ionic liquid.

1, 1’-Sulfinyldiethylammonium Bis (Hydrogen Sulfate) as a Recyclable Dicationic Ionic Liquid Catalyst for the Efficient Solvent-free Synthesis of 3, 4-Dihydropyrimidin-2(1H)-ones via Biginelli Reaction

2020 ◽  
Vol 23 (2) ◽  
pp. 157-167
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Biginelli Reaction ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Hydrogen Sulfate ◽  
One Pot ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Dicationic Ionic Liquid

Objective: A facile and efficient method for synthesis of 3, 4-dihydropyrimidin-2(1H)-ones via Biginelli reaction catalyzed by a novel dicationic Brönsted acidic ionic liquid, [(EtNH2)2SO][HSO4]2, has been successfully developed. Material and Method:: 3, 4-Dihydropyrimidin-2(1H)-ones were synthesized through one-pot condensation of aromatic aldehydes, ethyl acetoacetate, and urea under solvent-free conditions using [(EtNH2)2SO][HSO4]2 as a novel catalyst. The progress of the reaction was monitored by thin-layer chromatography (ethyl acetate / n-hexane = 1 / 5). The products have been characterized by IR, 1H NMR, 13C NMR, and also by their melting points. Results: In this research, a library of dihydropyrimidinone derivatives was synthesized via Biginelli reaction under solvent-free conditions at 120oC using [(EtNH2)2SO][HSO4]2 as a catalyst. Various aromatic aldehydes, as well as heteroaromatic aldehydes, were employed, affording good to high yields of the corresponding products and illustrating the substrate generality of the present method. In addition, the prepared dicationic Brönsted acidic ionic liquid can be easily recovered and reused. Conclusion: 1, 1’-Sulfinyldiethylammonium bis (hydrogen sulfate), as a novel dicationic ionic liquid, can act as a highly efficient catalyst for the synthesis of 3, 4-dihydropyrimidin-2(1H)-ones under solvent-free conditions.

scholarly journals ZnO Nanoparticles: A Highly Effective and Readily Recyclable Catalyst for the One-Pot Synthesis of 1,8-dioxo-decahydroacridine and 1,8-dioxooctahydro-xanthene Derivatives

2017 ◽  
Vol 57 (1) ◽  
Author(s):  
Javad Safaei-Ghomi ◽  
Mohammad Ali Ghasemzadeh ◽  
Safura Zahedi
Keyword(s):  
Zno Nanoparticles ◽  
Environmentally Friendly ◽  
Recyclable Catalyst ◽  
Solvent Free ◽  
One Pot ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
Xanthene Derivatives ◽  
Highly Effective ◽  
The One

ZnO nanoparticles as a worthwhile and recyclable catalyst have been used for the one-pot synthesis of 1,8-dioxo-decahydroacridines and 1,8-dioxooctahydro-xanthenes via multi-component reactions under solvent-free conditions. The presented method is mild, environmentally friendly, inexpensive and highly effective to give the products in good to excellent yields.

ChemInform Abstract: TiO2 as a Reusable Catalyst for the One-Pot Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones under Solvent-Free Conditions.

ChemInform ◽  
2010 ◽  
Vol 41 (26) ◽  
pp. no-no
Author(s):  
Mohammad Zaman Kassaee ◽  
Hassan Masrouri ◽  
Farnaz Movahedi ◽  
Reza Mohammadi
Keyword(s):  
Solvent Free ◽  
Reusable Catalyst ◽  
One Pot ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
The One
Sign in / Sign up

Export Citation Format

Share Document