ChemInform Abstract: Asymmetric Mukaiyama Aldol Reactions Using Chiral Diamine-Coordinated Sn(II) Triflate: Development and Application to Natural Product Synthesis

ChemInform ◽  
2014 ◽  
Vol 45 (20) ◽  
pp. no-no
Author(s):  
Isamu Shiina
Keyword(s):  
Natural Product ◽  
Natural Product Synthesis ◽  
Aldol Reactions ◽  
Chiral Diamine ◽  
Mukaiyama Aldol

Lithium Aldol Reactions of α-Chloroaldehydes Provide Versatile Building Blocks for Natural Product Synthesis

Synthesis ◽  
2011 ◽  
Vol 2011 (12) ◽  
pp. 1946-1953 ◽  
Author(s):  
Robert Britton ◽  
Shira Halperin ◽  
Baldip Kang
Keyword(s):  
Natural Product ◽  
Building Blocks ◽  
Natural Product Synthesis ◽  
Aldol Reactions

scholarly journals The vinylogous Mukaiyama aldol reaction (VMAR) in natural product synthesis

2014 ◽  
Vol 31 (4) ◽  
pp. 563-594 ◽  
Author(s):  
Markus Kalesse ◽  
Martin Cordes ◽  
Gerrit Symkenberg ◽  
Hai-Hua Lu
Keyword(s):  
Natural Product ◽  
Aldol Reaction ◽  
Natural Product Synthesis ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol ◽  
Recent Developments

This review will provide an overview on the recent developments of polyketide synthesis using the vinylogous Mukaiyama aldol reaction for the construction of advanced intermediates. In general, four different motifs can be constructed efficiently using the recent developments of asymmetric variants of this strategy.

ChemInform Abstract: The Vinylogous Mukaiyama Aldol Reaction (VMAR) in Natural Product Synthesis

ChemInform ◽  
2014 ◽  
Vol 45 (30) ◽  
pp. no-no
Author(s):  
Markus Kalesse ◽  
Martin Cordes ◽  
Gerrit Symkenberg ◽  
Hai-Hua Lu
Keyword(s):  
Natural Product ◽  
Aldol Reaction ◽  
Natural Product Synthesis ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol

Recent applications of asymmetric organocatalytic annulation reactions in natural product synthesis

2021 ◽  
Author(s):  
Nengzhong Wang ◽  
Zugen Wu ◽  
Junjie Wang ◽  
Nisar Ullah ◽  
Yixin Lu
Keyword(s):  
Natural Products ◽  
Natural Product ◽  
Natural Product Synthesis ◽  
Natural Products Synthesis

A comprehensive and updated summary of asymmetric organocatalytic annulation reactions is presented; in particular, the applications of these annulation strategies to natural products synthesis are highlighted.

scholarly journals The Synthesis of Conjugated Bis-Aryl Vinyl Substrates and Their Photoelectrocyclization Reactions towards Phenanthrene Derivatives

Synthesis ◽  
2021 ◽  
Author(s):  
Jon D. Rainier ◽  
Xuchen Zhao
Keyword(s):  
Natural Product ◽  
Natural Product Synthesis ◽  
Mechanistic Studies ◽  
Efficient Strategy

AbstractThe photoelectrocyclization of conjugated vinyl biaryls has proven to be a valuable and efficient strategy for generating phenanthrene derivatives. Contained in this review is an overview of the mechanism for the transformation and a discussion of the reaction scope with a focus on the electrocyclization itself, rearomatization, and the application of the reaction in natural product synthesis.1 Introduction2 The Synthesis of Conjugated Vinyl Biaryls3 Mechanistic Studies4 Substrate Scope5 Applications6 Conclusions

Palladium-catalyzed cascade cyclizations involving C–C and C–X bond formation: strategic applications in natural product synthesis

2021 ◽  
Author(s):  
K. R. Holman ◽  
A. M. Stanko ◽  
S. E. Reisman
Keyword(s):  
Natural Product ◽  
Bond Formation ◽  
Natural Product Synthesis ◽  
Cascade Cyclizations ◽  
Palladium Catalyzed ◽  
Multiple Rings

This tutorial review highlights the use of palladium-catalyzed cascade cyclizations in natural product synthesis, focusing on cascades that construct multiple rings and form both C–C and C–X (X = O, N) bonds in a single synthetic operation.

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