ChemInform Abstract: Sulfuric Acid Functionalized Silica-Coated Magnetic Nanoparticles: Preparation and Application in Synthesis of Mono-, Di- and Tri[bis(6-aminopyrimidinyl)methanes].

ChemInform ◽  
2014 ◽  
Vol 45 (19) ◽  
pp. no-no
Author(s):  
Ali Reza Karimi ◽  
Zeinab Dalirnasab ◽  
Marzie Karimi ◽  
Fatemeh Bagherian
Keyword(s):  
Sulfuric Acid ◽  
Magnetic Nanoparticles ◽  
Functionalized Silica

Determination of Organophosphorous Pesticides in Environmental Water Samples Using Surface-Engineered C18 Functionalized Silica-Coated Core-Shell Magnetic Nanoparticles–Based Extraction Coupled with GC-MS/MS Analysis

2017 ◽  
Vol 100 (3) ◽  
pp. 804-809 ◽  
Author(s):  
Neha Srivastava ◽  
Supriya Kumari ◽  
Kishore Nair ◽  
Samsul Alam ◽  
Syed K Raza
Keyword(s):  
Magnetic Nanoparticles ◽  
Water Samples ◽  
Environmental Water ◽  
Environmental Water Samples ◽  
Core Shell ◽  
Aqueous Sample ◽  
Functionalized Silica ◽  
Method Performance ◽  
Ms Analysis

Abstract The present paper depicts a novel method based on magneticSPE (MSPE) for the determination of organophosphorus pesticides (OPs) such as phorate, malathion, and chlorpyrifos in environmental water samples. In this study, C18 functionalized silica-coated core-shell iron oxide magnetic nanoparticles (MNPs) were used as a surface-engineered magnetic sorbent for theselective extraction of pesticides from aqueous samples, followed by GC-MS and GC–tandem MS analysis for confirmative determination of the analytes. Various important method parameters, including quantity of MNP adsorbent, volume of sample, effective time for extraction, nature of the desorbing solvent, and pH of the aqueous sample, were investigated and optimized to obtain maximum method performance. Under the optimized instrumental analysis conditions, good linearity (r2 value ≥0.994) was achieved at the concentration range of 0.5–500 μg/L. Recoveries were in therange of 79.2–96.3 and 80.4–97.5% in selective-ion monitoring and multiple reaction monitoring (MRM) modes, respectively, at the spiking concentrations of 1, 5, and 10 μg/L. MRM mode showed better sensitivity, selectivity, and low-level detection (0.5 μg/L) of analytes. The novel MSPE method is a simple, cheap, rapid, and eco-friendly method for the determination of OPs in environmental water samples.

Magnetically recoverable porphyrin-based nanocatalysts for the effective oxidation of olefins with hydrogen peroxide: a comparative study

2020 ◽  
Vol 44 (44) ◽  
pp. 19385-19392
Author(s):  
Saeed Rayati ◽  
Dana Moradi ◽  
Fatemeh Nejabat
Keyword(s):  
Hydrogen Peroxide ◽  
Magnetic Nanoparticles ◽  
Comparative Study ◽  
Amide Bond ◽  
Functionalized Silica ◽  
Simple Method ◽  
Amine Functionalized ◽  
Oxidation Of Olefins

A simple method for the functionalization of magnetic nanoparticles, which is achieved by the attachment of metalloporphyrin onto the surface of amine functionalized silica-coated magnetic nanoparticles via an amide bond.

Effective uranium(vi) sorption from alkaline media using bi-functionalized silica-coated magnetic nanoparticles

RSC Advances ◽  
2015 ◽  
Vol 5 (70) ◽  
pp. 56658-56665 ◽  
Author(s):  
X. T. Chen ◽  
L. F. He ◽  
R. Z. Liu ◽  
C. Zhang ◽  
B. Liu ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Magnetic Nanoparticles ◽  
Sorption Capacity ◽  
Alkaline Media ◽  
Functionalized Silica ◽  
Magnetic Iron Oxide ◽  
Maximum Sorption Capacity ◽  
Oxide Composite ◽  
Maximum Sorption

A bi-functionalized magnetic iron oxide composite has been employed for uranium(vi) sorption from alkaline media. The maximum sorption capacity was observed at pH 9.0 with a capacity of 70.7 mg g−1atcU(vi)initial= 21.7 mg L−1.

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