ChemInform Abstract: [Te8][NbOCl4]2Containing an Infinite Chain-Like {[Te-Te-Te-(Te5)]2+}nPolycation.

ChemInform ◽  
2013 ◽  
Vol 44 (1) ◽  
pp. no-no
Author(s):  
Claus Feldmann ◽  
Dominic Freudenmann
Keyword(s):  
Infinite Chain

Insight into the formation of H-bonds propagating the monomeric zinc complexes of a tridentate reduced Schiff base to form an infinite chain

CrystEngComm ◽  
2021 ◽  
Author(s):  
Mainak Karmakar ◽  
Antonio Frontera ◽  
Shouvik Chattopadhyay
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Dft Calculations ◽  
Zinc Complexes ◽  
Infinite Chain ◽  
State Structure ◽  
Computational Tools ◽  
Solid State Structure ◽  
Reduced Schiff Base ◽  
Insight Into

The formation of an infinite 1D assembly is governed by the H-bonding interactions in the solid state structure of the two zinc complexes. It has been analyzed energetically using DFT calculations and several computational tools.

Coupled dynamics of populations supported by discrete sites and their continuum limit

2010 ◽  
Vol 466 (2121) ◽  
pp. 2561-2586 ◽  
Author(s):  
Timothy R. Field ◽  
Robert J. A. Tough
Keyword(s):  
Evolution Equation ◽  
Closed Form ◽  
Generating Function ◽  
Rate Equation ◽  
Continuum Limit ◽  
Infinite Chain ◽  
Migration Process ◽  
The Mean ◽  
The Continuum ◽  
Birth Death

The illumination of single population behaviour subject to the processes of birth, death and immigration has provided a basis for the discussion of the non-Gaussian statistical and temporal correlation properties of scattered radiation. As a first step towards the modelling of its spatial correlations, we consider the populations supported by an infinite chain of discrete sites, each subject to birth, death and immigration and coupled by migration between adjacent sites. To provide some motivation, and illustrate the techniques we will use, the migration process for a single particle on an infinite chain of sites is introduced and its diffusion dynamics derived. A certain continuum limit is identified and its properties studied via asymptotic analysis. This forms the basis of the multi-particle model of a coupled population subject to single site birth, death and immigration processes, in addition to inter-site migration. A discrete rate equation is formulated and its generating function dynamics derived. This facilitates derivation of the equations of motion for the first- and second-order cumulants, thus generalizing the earlier results of Bailey through the incorporation of immigration at each site. We present a novel matrix formalism operating in the time domain that enables solution of these equations yielding the mean occupancy and inter-site variances in the closed form. The results for the first two moments at a single time are used to derive expressions for the asymptotic time-delayed correlation functions, which relates to Glauber’s analysis of an Ising model. The paper concludes with an analysis of the continuum limit of the birth–death–immigration–migration process in terms of a path integral formalism. The continuum rate equation and evolution equation for the generating function are developed, from which the evolution equation of the mean occupancy is derived, in this limit. Its solution is provided in closed form.

On-site localization of excitations

2005 ◽  
Vol 5 (4&5) ◽  
pp. 335-349
Author(s):  
M.I. Dykman ◽  
L.F. Santos ◽  
M. Shapiro ◽  
F. .M. Izrailev
Keyword(s):  
Quantum Computer ◽  
Infinite Chain ◽  
Quantum Operations ◽  
Site Localization ◽  
Excitation State ◽  
Coupled Qubits

We demonstrate that, in a quantum computer with perpetually coupled qubits, all excitations can be confined to their sites (qubits) even without refocusing. The on-site localization is obtained by constructing a sequence of qubit energies that efficiently suppresses resonant hopping. The time during which a many-excitation state remains strongly localized in an infinite chain can exceed the reciprocal hopping frequency by $\agt 10^5$ already for a moderate bandwidth of qubit energies. The proposed energy sequence is also convenient for performing quantum operations on the qubits.

scholarly journals NEW TETRANUCLEAR AND MONONUCLEAR OXALATO ORGANOTIN (IV) COMPLEXES WITH MONOCYCLOHEXYLAMMONIUM AS ADVERSE CATION: SYNTHESIS AND INFRARED STUDY

2018 ◽  
Vol 23 (4) ◽  
Author(s):  
MODOU SARR ◽  
AMINATA DIASSE-SARR ◽  
LIBASSE DIOP
Keyword(s):  
Hydrogen Bonds ◽  
Infinite Chain ◽  
Intermolecular Hydrogen Bonds ◽  
Infrared Study ◽  
Supramolecular Architectures ◽  
Trigonal Bipyramidal

Eight new adducts and derivatives have been synthesized and studied by infrared. Discrete, layered or infinite chain structures are suggested with an oxalate behaving as a monodentate, bidentate, monochelating or bichelating ligand, the environment around the tin centres being tetrahedral, cis trigonal bipyramidal or octahedral. In all the studied compounds, supramolecular architectures may be obtained when intermolecular hydrogen bonds are considered.

scholarly journals CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n

2020 ◽  
Vol 26 (3) ◽  
pp. 212-217
Author(s):  
MODOU SARR ◽  
MOUHAMADOU BIRAME DIOP ◽  
AMINATA DIASSE-SARR ◽  
AI WANG ◽  
ULLRICH ENGLERT
Keyword(s):  
Crystal Structure ◽  
Infinite Chain ◽  
Monoclinic Space Group ◽  
Space Group ◽  
Axis Direction ◽  
Trigonal Bipyramidal ◽  
Triphenyltin Chloride

The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with Z = 4, a = 14.7091 (18) Å, b = 15.4133 (19) Å, c = 14.7639 (18) Å, β = 94.242 (2)° and V = 3338.0 (7) Å3. The structure consists of an infinite chain propagating along the crystallographic a-axis direction with bidentate formate anions. The O2SnC3 core is organized into a trans-trigonal bipyramidal like-arrangement.

scholarly journals Negative energy states in the Reissner–Nordström metric

2021 ◽  
pp. 2150120
Author(s):  
O. B. Zaslavskii
Keyword(s):  
Turning Point ◽  
High Energy ◽  
Negative Energy ◽  
Infinite Chain ◽  
White Hole ◽  
Negative Energy States ◽  
Energy Formula ◽  
High Energy Collisions ◽  
Energy States

We consider electrogeodesics on which the energy [Formula: see text] in the Reissner–Nordström metric. It is shown that outside the horizon there is exactly one turning point inside the ergoregion for such particles. This entails that such a particle passes through an infinite chain of black–white hole regions or terminates in the singularity. These properties are relevant for two scenarios of high energy collisions in which the presence of white holes is essential.

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