ChemInform Abstract: Nanolayered Manganese Oxides as Low-Cost, Easily Synthesized, Environmentally Friendly and Efficient Catalysts for Epoxidation of Olefins.

ChemInform ◽  
2012 ◽  
Vol 43 (34) ◽  
pp. no-no
Author(s):  
Mojtaba Amini ◽  
Mohammad Mahdi Najafpour ◽  
Sara Nayeri ◽  
Babak Pashaei ◽  
Mojtaba Bagherzadeh
RSC Advances ◽  
2012 ◽  
Vol 2 (9) ◽  
pp. 3654 ◽  
Author(s):  
Mojtaba Amini ◽  
Mohammad Mahdi Najafpour ◽  
Sara Nayeri ◽  
Babak Pashaei ◽  
Mojtaba Bagherzadeh

2020 ◽  
Vol 8 (4) ◽  
pp. 429-439
Author(s):  
Ying Tao ◽  
Rong Li ◽  
Ai-Bin Huang ◽  
Yi-Ning Ma ◽  
Shi-Dong Ji ◽  
...  

AbstractAmong the transition metal oxide catalysts, manganese oxides have great potential for formaldehyde (HCHO) oxidation at ambient temperature because of their high activity, nontoxicity, low cost, and polybasic morphologies. In this work, a MnO2-based catalyst (M-MnO2) with an interconnected network structure was successfully synthesized by a one-step hydrothermal method. The M-MnO2 catalyst was composed of the main catalytic agent, δ-MnO2 nanosheets, dispersed in a nonactive framework material of γ-MnOOH nanowires. The catalytic activity of M-MnO2 for HCHO oxidation at room temperature was much higher than that of the pure δ-MnO2 nanosheets. This is attributed to the special interconnected network structure. The special interconnected network structure has high dispersion and specific surface area, which can provide more surface active oxygen species and higher surface hydroxyl groups to realize rapid decomposition of HCHO.


2018 ◽  
Vol 2018 ◽  
pp. 1-12
Author(s):  
Donghui Yang ◽  
Yixin Zhao ◽  
Zhangxuan Ning ◽  
Zhaoheng Lv ◽  
Huafeng Luo

Drilling and blasting technology is one of the main methods for pressure relief in deep mining. The traditional method for blasting hole blockage with clay stemming has many problems, which include a large volume of transportation, excess loading time, and high labor intensity. An environmentally friendly blast hole plug was designed and developed. This method is cheap, closely blocks the hole, is quickly loaded, and is convenient for transportation. The impact test on the plug was carried out using an improved split Hopkinson pressure bar test system, and the industrial test was carried out in underground tunnel of coal mine. The tests results showed that, compared with clay stemming, the new method proposed in this paper could prolong the action time of the detonation gas, prevent premature detonation gas emissions, reduce the unit consumption of explosives, improve the utilization ratio, reduce the labor intensity of workers, and improve the effect of rock blasting with low cost of rock breaking.


2021 ◽  
Vol 18 ◽  
Author(s):  
Aparna Das

: In recent years, photocatalytic technology has shown great potential as a low-cost, environmentally friendly, and sustainable technology. Compared to other light sources in photochemical reaction, LEDs have advantages in terms of efficiency, power, compatibility, and environmentally-friendly nature. This review highlights the most recent advances in LED-induced photochemical reactions. The effect of white and blue LEDs in reactions such as oxidation, reduction, cycloaddition, isomerization, and sensitization is discussed in detail. No other reviews have been published on the importance of white and blue LED sources in the photocatalysis of organic compounds. Considering all the facts, this review is highly significant and timely.


2019 ◽  
Vol 45 (3) ◽  
pp. 3101-3110 ◽  
Author(s):  
Shuaibo Gao ◽  
Xin Li ◽  
Shuai Wang ◽  
Pengfei Xing ◽  
Jian kong ◽  
...  

2019 ◽  
Vol 6 (7) ◽  
pp. 190351 ◽  
Author(s):  
Shuangxi Zhou ◽  
Zhiling Du ◽  
Xiuwen Li ◽  
Yunhai Zhang ◽  
Yide He ◽  
...  

In this study, natural manganese oxides (MnO x ), an environmental material with high redox potential, were used as a promising low-cost oxidant to degrade the widely used dyestuff methylene blue (MB) in aqueous solution. Although the surface area of MnO x was only 7.17 m 2 g −1 , it performed well in the degradation of MB with a removal percentage of 85.6% at pH 4. It was found that MB was chemically degraded in a low-pH reaction system and the degradation efficiency correlated negatively with the pH value (4–8) and initial concentration of MB (10–50 mg l −1 ), but positively with the dosage of MnO x (1–5 g l −1 ). The degradation of MB fitted well with the second-order kinetics. Mathematical models were also built for the correlation of the kinetic constants with the pH value, the initial concentration of MB and the dosage of MnO x . Furthermore, several transformation products of MB were identified with HPLC-MS, which was linked with the bond energy theory to reveal that the degradation was initiated with demethylation.


2018 ◽  
Vol 28 (47) ◽  
pp. 1803266 ◽  
Author(s):  
Fenghua Liu ◽  
Binyuan Zhao ◽  
Weiping Wu ◽  
Haiyan Yang ◽  
Yuesheng Ning ◽  
...  

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