ChemInform Abstract: Detection and Structural Characterization of Oxo-chromium(V)-Sugar Complexes by Electron Paramagnetic Resonance

ChemInform ◽  
2012 ◽  
Vol 43 (16) ◽  
pp. no-no
Author(s):  
Luis F. Sala ◽  
Juan C. Gonzalez ◽  
Silvia I. Garcia ◽  
Maria I. Frascaroli ◽  
Sabine Van Doorslaer
Author(s):  
Luis Fábregas-Ibáñez ◽  
Maxx H. Tessmer ◽  
Gunnar Jeschke ◽  
Stefan Stoll

Dipolar electron paramagnetic resonance (EPR) experiments such as double electron--electron resonance (DEER) measure distributions of nanometer-scale distances between unpaired electrons, which provide valuable information for structural characterization of proteins and...


2009 ◽  
Vol 1199 ◽  
Author(s):  
Ebru Erünal ◽  
Rüdiger-A. Eichel ◽  
Jerome Acker ◽  
Hans Kungl ◽  
Michael J. Hoffmann

AbstractThe alkali niobate ferroelectrics ((K0.5Na0.5)NbO3, KNN) are promising candidates as alternatives for PZT (Pb(ZrxTi(1-x))O3) ceramics in piezoelectric technologies. In order to obtain dense compounds with desirable properties, CuO has been used as sintering aid. In this work, the defect chemistry of Cu2+ doped KNN was investigated by means of electron paramagnetic resonance (EPR). Copper is found to be incorporated as acceptor-type centers on B-site in the perovskite structure and, due to charge compensation, two kinds of mutually compensating defect dipoles are formed.


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