ChemInform Abstract: Synthesis of Benzimidazole-Fused Heterocycles by Intramolecular Oxidative C-N Bond Formation Using Hypervalent Iodine Reagents.

ChemInform ◽  
2012 ◽  
Vol 43 (8) ◽  
pp. no-no
Author(s):  
Noriki Kutsumura ◽  
Shinichi Kunimatsu ◽  
Kimiko Kagawa ◽  
Takashi Otani ◽  
Takao Saito
Keyword(s):  
Bond Formation ◽  
Hypervalent Iodine ◽  
Fused Heterocycles

Synthesis of Benzimidazole-Fused Heterocycles by Intramolecular Oxidative C-N Bond Formation Using Hypervalent Iodine Reagents

Synthesis ◽  
2011 ◽  
Vol 2011 (20) ◽  
pp. 3235-3240 ◽  
Author(s):  
Noriki Kutsumura ◽  
Takao Saito ◽  
Shinichi Kunimatsu ◽  
Kimiko Kagawa ◽  
Takashi Otani
Keyword(s):  
Bond Formation ◽  
Hypervalent Iodine ◽  
Fused Heterocycles

ChemInform Abstract: Hypervalent Iodine(III) Catalyzed Oxidative C-N Bond Formation in Water: Synthesis of Benzimidazole-Fused Heterocycles.

ChemInform ◽  
2015 ◽  
Vol 46 (5) ◽  
pp. no-no
Author(s):  
D. Nageswar Rao ◽  
Sk. Rasheed ◽  
Ram A. Vishwakarma ◽  
Parthasarathi Das
Keyword(s):  
Bond Formation ◽  
Hypervalent Iodine ◽  
Fused Heterocycles

Hypervalent iodine(iii) catalyzed oxidative C–N bond formation in water: synthesis of benzimidazole-fused heterocycles

RSC Advances ◽  
2014 ◽  
Vol 4 (49) ◽  
pp. 25600-25604 ◽  
Author(s):  
D. Nageswar Rao ◽  
Sk. Rasheed ◽  
Ram A. Vishwakarma ◽  
Parthasarathi Das
Keyword(s):  
Bond Formation ◽  
Hypervalent Iodine ◽  
Ambient Conditions ◽  
Fused Heterocycles

A diverse array of benzimidazole-fused heterocycles was synthesized by in situ generated hypervalent iodine(iii) catalyzed intramolecular oxidative C–N bond formation in water and under ambient conditions.

Formation of Carbon-Oxygen Bond Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions

2020 ◽  
Vol 17 ◽  
Author(s):  
Ayesha Jalil ◽  
Yaxin O Yang ◽  
Zhendong Chen ◽  
Rongxuan Jia ◽  
Tianhao Bi ◽  
...  
Keyword(s):  
Natural Products ◽  
Bond Formation ◽  
Building Blocks ◽  
Review Article ◽  
Hypervalent Iodine ◽  
Metal Free ◽  
Bioactive Natural Products ◽  
The Past ◽  
Oxygen Bond ◽  
Privileged Scaffolds

: Hypervalent iodine reagents are a class of non-metallic oxidants have been widely used in the construction of several sorts of bond formations. This surging interest in hypervalent iodine reagents is essentially due to their very useful oxidizing properties, combined with their benign environmental character and commercial availability from the past few decades ago. Furthermore, these hypervalent iodine reagents have been used in the construction of many significant building blocks and privileged scaffolds of bioactive natural products. The purpose of writing this review article is to explore all the transformations in which carbon-oxygen bond formation occurred by using hypervalent iodine reagents under metal-free conditions

Double C–H Activation for the C–C bond Formation Reactions

2018 ◽  
Vol 15 (7) ◽  
pp. 882-903 ◽  
Author(s):  
Jialin Liu ◽  
Xiaoyu Xiong ◽  
Jie Chen ◽  
Yuntao Wang ◽  
Ranran Zhu ◽  
...  
Keyword(s):  
Molecular Design ◽  
Bond Cleavage ◽  
Bond Formation ◽  
Hypervalent Iodine ◽  
Coupling Reactions ◽  
Bond Forming ◽  
Direct Functionalization ◽  
Catalyzed Reactions ◽  
Medium Ring ◽  
Bond Formation Reactions

Background: Among the numerous bond-forming patterns, C–C bond formation is one of the most useful tools for building molecules for the chemical industry as well as life sciences. Recently, one of the most challenging topics is the study of the direct coupling reactions via multiple C–H bond cleavage/activation processes. A number of excellent reviews on modern C–H direct functionalization have been reported by Bergman, Bercaw, Yu and others in recent years. Among the large number of available methodologies, Pdcatalyzed reactions and hypervalent iodine reagent mediated reactions represent the most popular metal and non-metal involved transformations. However, the comprehensive summary of the comparison of metal and non-metal mediated transformations is still not available. Objective: The review focuses on comparing these two types of reactions (Pd-catalyzed reactions and hypervalent iodine reagent mediated reactions) based on the ways of forming new C–C bonds, as well as the scope and limitations on the demonstration of their synthetic applications. Conclusion: Comparing the Pd-catalyzed strategies and hypervalent iodine reagent mediated methodologies for the direct C–C bond formation from activation of C-H bonds, we clearly noticed that both strategies are powerful tools for directly obtaining the corresponding pruducts. On one hand, the hypervalent iodine reagents mediated reactions are normally under mild conditions and give the molecular diversity without the presence of transition-metal, while the Pd-catalyzed approaches have a broader scope for the wide synthetic applications. On the other hand, unlike Pd-catalyzed C-C bond formation reactions, the study towards hypervalent iodine reagent mediated methodology mainly focused on the stoichiometric amount of hypervalent iodine reagent, while few catalytic reactions have been reported. Meanwhile, hypervalent iodine strategy has been proved to be more efficient in intramolecular medium-ring construction, while there are less successful examples on C(sp3)–C(sp3) bond formation. In summary, we have demonstrated a number of selected approaches for the formation of a new C–C bond under the utilization of Pd-catalyzed reaction conditions or hyperiodine reagents. The direct activations of sp2 or sp3 hybridized C–H bonds are believed to be important strategies for the future molecular design as well as useful chemical entity synthesis.

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

2011 ◽  
Vol 133 (41) ◽  
pp. 16410-16413 ◽  
Author(s):  
Xi Wang ◽  
Yuxuan Ye ◽  
Songnan Zhang ◽  
Jiajie Feng ◽  
Yan Xu ◽  
...  
Keyword(s):  
Bond Formation ◽  
Hypervalent Iodine

scholarly journals PIDA-mediated intramolecular oxidative C–N bond formation for the direct synthesis of quinoxalines from enaminones

RSC Advances ◽  
2019 ◽  
Vol 9 (14) ◽  
pp. 7718-7722 ◽  
Author(s):  
Hong Zhang ◽  
Jinhai Shen ◽  
Zhenhui Yang ◽  
Xiuling Cui
Keyword(s):  
Direct Synthesis ◽  
Bond Formation ◽  
Hypervalent Iodine ◽  
Mild Conditions

An expedient hypervalent iodine(iii)-mediated approach to obtain substituted quinoxalines from readily available enaminones has been developed under mild conditions.

Metal-Free Enantioselective Oxidative Arylation of Alkenes: Hypervalent-Iodine-Promoted Oxidative C−C Bond Formation

2016 ◽  
Vol 128 (51) ◽  
pp. 16029-16033 ◽  
Author(s):  
Mio Shimogaki ◽  
Morifumi Fujita ◽  
Takashi Sugimura
Keyword(s):  
Bond Formation ◽  
Hypervalent Iodine ◽  
Metal Free
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