ChemInform Abstract: A New Strategy for the Synthesis of Poly-Substituted 3-H, 3-Fluoro, or 3-Trifluoromethyl Pyridines via the Tandem C-F Bond Cleavage Protocol.

ChemInform ◽  
2011 ◽  
Vol 42 (5) ◽  
pp. no-no
Author(s):  
Zixian Chen ◽  
Jiangtao Zhu ◽  
Haibo Xie ◽  
Shan Li ◽  
Yongming Wu ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
New Strategy

ChemInform Abstract: Copper-Catalyzed Aerobic Oxidative Inert C-C and C-N Bond Cleavage: A New Strategy for the Synthesis of Tertiary Amides.

ChemInform ◽  
2015 ◽  
Vol 46 (11) ◽  
pp. no-no
Author(s):  
Xiuling Chen ◽  
Tieqiao Chen ◽  
Qiang Li ◽  
Yongbo Zhou ◽  
Li-Biao Han ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
New Strategy ◽  
Tertiary Amides

Copper-Catalyzed Aerobic Oxidative Inert CC and CN Bond Cleavage: A New Strategy for the Synthesis of Tertiary Amides

2014 ◽  
Vol 20 (38) ◽  
pp. 12234-12238 ◽  
Author(s):  
Xiuling Chen ◽  
Tieqiao Chen ◽  
Qiang Li ◽  
Yongbo Zhou ◽  
Li-Biao Han ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
New Strategy ◽  
Tertiary Amides

A New Strategy for the Synthesis of Poly-Substituted 3-H, 3-Fluoro, or 3-Trifluoromethyl Pyridines via the Tandem C−F Bond Cleavage Protocol

2010 ◽  
Vol 12 (19) ◽  
pp. 4376-4379 ◽  
Author(s):  
Zixian Chen ◽  
Jiangtao Zhu ◽  
Haibo Xie ◽  
Shan Li ◽  
Yongming Wu ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
New Strategy

Copper-Catalyzed Cleavage of Unstrained C–C Bonds for the Synthesis of 1-Acyloxy-2,2,6,6-tetramethylpiperidines from Cyclic or Acyclic Ketones

Synlett ◽  
2017 ◽  
Vol 28 (16) ◽  
pp. 2163-2168 ◽  
Author(s):  
Wang Zhou ◽  
Qijian Jiang ◽  
Luo Yang
Keyword(s):  
Bond Cleavage ◽  
New Strategy ◽  
Phenanthroline Monohydrate ◽  
Acyclic Ketones

A copper-catalyzed approach for the synthesis of 1-acyloxy-2,2,6,6-tetramethylpiperidines through the C–C bond cleavage of cyclic or acyclic ketones was developed. In this chemistry, a combination of CuCl2·2H2O, 1,10-phenanthroline monohydrate, and aniline was crucial for the formation of the desired products by the reaction of ketones with TEMPO. This research provides a new strategy for the further transformation of α-aryl cyclic or acyclic ketones.

Kinetic resolution of primary allylic amines via palladium-catalyzed asymmetric allylic alkylation of malononitriles

2015 ◽  
Vol 13 (19) ◽  
pp. 5367-5371 ◽  
Author(s):  
Yong Wang ◽  
Ya-Nan Xu ◽  
Guo-Sheng Fang ◽  
Hong-Jian Kang ◽  
Yonghong Gu ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Bond Cleavage ◽  
Allylic Alkylation ◽  
Allylic Amines ◽  
Asymmetric Allylic Alkylation ◽  
New Strategy ◽  
Palladium Catalyzed

A new strategy has been developed for the catalytic kinetic resolution of primary allylic amines via enantioselective C–N bond cleavage.

Strain-release C-C bond cleavage enables the [2,3]-sigmatropic rearrangement of tertiary allylamines

2021 ◽  
Author(s):  
Rui-Han Dai ◽  
Lu Han ◽  
Qi Wang ◽  
Shi-Kai Tian
Keyword(s):  
Bond Cleavage ◽  
Sigmatropic Rearrangement ◽  
New Strategy ◽  
Strain Release

A new strategy has been established for the [2,3]-sigmatropic rearrangement of quaternary allylammonium ylides, generated in situ from tertiary allylamines and a bicyclo[1.1.0]butane via strain-release C-C bond cleavage. A range...

Metal-Free Oxidative C=C Bond Cleavage of Electron-Deficient Enamines Promoted by tert-Butyl Hydroperoxide

Synlett ◽  
2017 ◽  
Vol 28 (12) ◽  
pp. 1481-1485 ◽  
Author(s):  
Mehdi Adib ◽  
Rahim Pashazadeh ◽  
Seyed Gohari ◽  
Fatemeh Shahsavari
Keyword(s):  
Double Bond ◽  
Bond Cleavage ◽  
Bond Formation ◽  
Butyl Hydroperoxide ◽  
Metal Free ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
New Strategy

A novel tert-butyl hydroperoxide (TBHP)-promoted oxidative C=C double-bond cleavage of enamines is described. Heating a solution of an electron-deficient enamine in chlorobenzene at 80 °C in the presence of TBHP for two hours led to cleavage of the C=C bond. This study offers a new strategy to carry out C=O double-bond formation by the use of TBHP.

scholarly journals Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

2014 ◽  
Vol 43 (23) ◽  
pp. 8081-8097 ◽  
Author(s):  
Josep Cornella ◽  
Cayetana Zarate ◽  
Ruben Martin
Keyword(s):  
Molecular Diversity ◽  
Bond Activation ◽  
Aryl Halide ◽  
Bond Cleavage ◽  
Cross Coupling ◽  
New Strategy ◽  
The Cross ◽  
Metal Catalyzed

This review highlights the prospective impact of simple ethers as aryl halide surrogates in the cross-coupling arena via C–O bond-activation.

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