ChemInform Abstract: Olefin Epoxidation by Hydrogen Peroxide Catalyzed by Molybdenum Complexes in Ionic Liquids and Structural Characterization of the Proposed Intermediate Dioxoperoxomolybdenum Species.

ChemInform ◽  
2010 ◽  
Vol 41 (52) ◽  
pp. no-no
Author(s):  
Matthew Herbert ◽  
Eleuterio Alvarez ◽  
David J. Cole-Hamilton ◽  
Francisco Montilla ◽  
Agustin Galindo
2018 ◽  
Vol 233 (7) ◽  
pp. 507-513 ◽  
Author(s):  
Philip A. Smith ◽  
Tyler L. Spano ◽  
Peter C. Burns

Abstract Trimethylglycine and betainium class ionic liquids were employed in synthesizing six uranyl-betaine coordination complexes: [(μ2-(CH3)N2C3H3(CH2COO))2 (UO2(Cl)((CH3)N2C3H3(CH2COO)))2] 2[N(SO2CF3)2] (1), [K][UO2(Cl)3((CH3)3NCH2COO)] (2), [(CH3)3NCH2COOH][UO2(Cl)3((CH3)3NCH2COO)]⋅H2O (3), [LiUO2(μ2-(CH3)3NCH2COO)4] 3[N(SO2CF3)2] (4) {(μ2-(CH3)3NCH2COO)UO2(NO3)2((CH3)3NCH2COO)}2 UO2(NO3)2, UO2(NO3)2(H2O)2⋅H2O (5), and UO2(Cl)2(H2O)(μ2-(CH3)3NCH2COO) (6). These complexes expound upon the variability of monocarboxyl-functionalized uranyl coordination complexes, providing an enhanced framework for investigations into the structural chemistry of analogous actinyl systems.


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pp. 486-497 ◽  
Author(s):  
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Mohd R. Razali ◽  
Craig M. Forsyth ◽  
Kate M. Nairn ◽  
Stuart R. Batten ◽  
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