ChemInform Abstract: Synthesis of Functionalized Indoles with a Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Atom Through an Enantioselective Friedel-Crafts Alkylation with β-Trifluoromethyl-α,β-enones.

ChemInform ◽  
2010 ◽  
Vol 41 (51) ◽  
pp. no-no
Author(s):  
Gonzalo Blay ◽  
Isabel Fernandez ◽  
M. Carmen Munoz ◽  
Jose R. Pedro ◽  
Carlos Vila
Keyword(s):  
Carbon Atom ◽  
Tertiary Carbon Atom ◽  
Tertiary Carbon

Preparation of diamantanedicarboxylic acids with carboxyl groups on one secondary and one tertiary carbon atom

1986 ◽  
Vol 51 (4) ◽  
pp. 867-871 ◽  
Author(s):  
Luděk Vodička ◽  
Jiří Burkhard ◽  
Josef Janků
Keyword(s):  
Carbon Atom ◽  
The Other ◽  
Carboxyl Groups ◽  
High Dilution ◽  
Tertiary Carbon Atom ◽  
Tertiary Carbon

Bromination of 3-diamantanecarboxylic acid leads to a mixture of bromodiamantanecarboxylic acids which on Koch-Haaf carboxylation at high dilution affords a mixture of diamantanedicarboxylic acids with one carboxyl on the secondary and the other on the tertiary carbon atom of the diamantane skeleton. At low dilution, the Koch-Haaf carboxylation gives predominantly 3,9-diamantanedicarboxylic acid.

Anchimerically assisted elimination and nucleophilic displacement at a tertiary carbon atom

1965 ◽  
Vol 6 (51) ◽  
pp. 4733-4735 ◽  
Author(s):  
A.M. Braun ◽  
C.E. Ebner ◽  
C.A. Grob ◽  
F.A. Jenny
Keyword(s):  
Carbon Atom ◽  
Tertiary Carbon Atom ◽  
Nucleophilic Displacement ◽  
Tertiary Carbon

Geometry at the aliphatic tertiary carbon atom: computational and experimental test of the Walsh rule

2004 ◽  
Vol 60 (1) ◽  
pp. 103-107 ◽  
Author(s):  
Stanislav Böhm ◽  
Otto Exner
Keyword(s):  
Carbon Atom ◽  
Experimental Test ◽  
Inductive Effect ◽  
Crystallographic Data ◽  
Geometrical Parameters ◽  
Tertiary Carbon Atom ◽  
Steric Crowding ◽  
Tertiary Carbon ◽  
Structural Database ◽  
The Mean

The geometrical parameters of molecules of 2-substituted 2-methylpropanes and 1-substituted bicyclo[2.2.2]octanes were calculated at the B3LYP/6-311+G(d,p) level. They agreed reasonably well with the mean crystallographic values retrieved from the Cambridge Structural Database for a set of diverse non-cyclic structures with a tertiary C atom. The angle deformations at this C atom produced by the immediately bonded substituent are also closely related to those observed previously in benzene mono derivatives (either as calculated or as derived from crystallographic data). The calculated geometrical parameters were used to test the classical Walsh rule: It is evidently true that an electron-attracting substituent increases the proportion of C-atom p-electrons in the bond to the substituent and leaves more s-electrons to the remaining bonds; as a consequence the C—C—C angles at a tertiary carbon are widened and the C—C bonds shortened. However, this rule describes only part of the reality since the bond angles and lengths are controlled by other factors as well, for instance by steric crowding. Another imperfection of the Walsh rule is that the sequence of substituents does not correspond to their electronegativities, as measured by any known scale; more probably it is connected with the inductive effect, but then only very roughly.

HALOGENATION OF HYDROCARBONS Chlorination of Olefins Containing an Unsaturated Tertiary Carbon Atom

1939 ◽  
Vol 31 (11) ◽  
pp. 1413-1419 ◽  
Author(s):  
J. Burger ◽  
W. Engs ◽  
H. P. A. Groll ◽  
G. Hearne
Keyword(s):  
Carbon Atom ◽  
Tertiary Carbon Atom ◽  
Tertiary Carbon

scholarly journals Antioxidant effectiveness of dehydrogenated p-phenylene diamines through NMR calculations

2016 ◽  
Vol 9 (2) ◽  
pp. 100-103 ◽  
Author(s):  
Ingrid Puškárová ◽  
Martin Breza
Keyword(s):  
Carbon Atom ◽  
Chemical Shifts ◽  
Aliphatic Chain ◽  
Aromatic Rings ◽  
Amine Nitrogen ◽  
Nmr Chemical Shifts ◽  
Tertiary Carbon Atom ◽  
Antioxidant Effectiveness ◽  
Tertiary Carbon ◽  
B3lyp Calculations

Abstract NMR shifts of N-phenyl-N’-alkyl-p-phenylenediamines (PPD) in vacuum were evaluated by B3LYP calculations using GIAO method. According to our previous studies, the Molar Antioxidant Effectiveness (AEM) of PPD antioxidants correlates with NMR chemical shifts of the amine nitrogen between aromatic rings (NA), the side aliphatic chain nitrogen (NB) and its neighboring tertiary carbon atom (CT) as well as of the hydrogens bonded to them. Our results indicate that the above mentioned chemical shifts correlate with increasing reactivity of dehydrogenated PPD antioxidants at these sites as well.

Mode of solvent participation in solvolysis reactions at a tertiary carbon atom

1975 ◽  
Vol 97 (1) ◽  
pp. 132-136 ◽  
Author(s):  
F. G. Bordwell ◽  
Paul F. Wiley ◽  
Thomas G. Mecca
Keyword(s):  
Carbon Atom ◽  
Tertiary Carbon Atom ◽  
Tertiary Carbon
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