ChemInform Abstract: Ligand-Free Palladium-Catalyzed Mizoroki-Heck-Type Reaction of Arylboronic Acids and Alkenes Using Silver Cation.

ChemInform ◽  
2010 ◽  
Vol 41 (44) ◽  
pp. no-no
Author(s):  
Eunjin Song ◽  
Jinhyung Park ◽  
Il-Kwon Oh ◽  
Hyun Min Jung ◽  
Sunwoo Lee
Keyword(s):  
Silver Cation ◽  
Type Reaction ◽  
Arylboronic Acids ◽  
Ligand Free ◽  
Palladium Catalyzed

scholarly journals Ligand-free Palladium-Catalyzed Mizoroki-Heck-type Reaction of Arylboronic Acids and Alkenes Using Silver Cation

2010 ◽  
Vol 31 (6) ◽  
pp. 1789-1792 ◽  
Author(s):  
Eun-Jin Song ◽  
Jin-Hyung Park ◽  
Il-Kwon Oh ◽  
Hyun-Min Jung ◽  
Sun-Woo Lee
Keyword(s):  
Silver Cation ◽  
Type Reaction ◽  
Arylboronic Acids ◽  
Ligand Free ◽  
Palladium Catalyzed

Ligand-Free Palladium-Catalyzed Carbonylative Suzuki Couplings of Vinyl Iodides with Arylboronic Acids under Substoichiometric Base Conditions

Synlett ◽  
2021 ◽  
Author(s):  
Zhiyuan Yang ◽  
Pei-Xue Gong ◽  
Junjie Chen ◽  
Jie Zhang ◽  
Xu Gong ◽  
...  
Keyword(s):  
Late Stage ◽  
Ambient Pressure ◽  
Complex Molecule ◽  
Arylboronic Acids ◽  
Simple Protocol ◽  
Ligand Free ◽  
Reaction Proceeds ◽  
Palladium Catalyzed ◽  
Vinyl Iodides

A ligand-free palladium-catalyzed carbonylation of vinyl iodides with arylboronic acids allowing for the synthesis of chalcones and α-branched enones has been established. This reaction proceeds smoothly under ambient pressure and temperature and even use of substoichiometric base renders the transformation to work well. Importantly, this mild, efficient, operationally simple protocol is suitable for the late-stage functionalization of an epiandrosterone-derived complex molecule.

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