ChemInform Abstract: Silver-Catalyzed Benzylation and Allylation of Tertiary Alkyl Bromides with Organozinc Reagents.

ChemInform ◽  
2010 ◽  
Vol 41 (42) ◽  
Author(s):  
Yukihiro Mitamura ◽  
Yoshihiro Asada ◽  
Kei Murakami ◽  
Hidenori Someya ◽  
Hideki Yorimitsu ◽  
...  
Keyword(s):  
Alkyl Bromides ◽  
Organozinc Reagents ◽  
Tertiary Alkyl

Silver-Catalyzed Benzylation and Allylation of Tertiary Alkyl Bromides with Organozinc Reagents

2010 ◽  
pp. n/a-n/a ◽  
Author(s):  
Yukihiro Mitamura ◽  
Yoshihiro Asada ◽  
Kei Murakami ◽  
Hidenori Someya ◽  
Hideki Yorimitsu ◽  
...  
Keyword(s):  
Alkyl Bromides ◽  
Organozinc Reagents ◽  
Tertiary Alkyl

Zn- and Cu-Catalyzed Coupling of Tertiary Alkyl Bromides and Oxalates to Forge Challenging C–O, C–S, and C–N Bonds

2021 ◽  
Vol 23 (3) ◽  
pp. 1005-1010
Author(s):  
Yuxin Gong ◽  
Zhaodong Zhu ◽  
Qun Qian ◽  
Weiqi Tong ◽  
Hegui Gong
Keyword(s):  
Alkyl Bromides ◽  
Tertiary Alkyl

scholarly journals Copper-catalyzed direct alkylation of heteroarenes

2017 ◽  
Vol 8 (5) ◽  
pp. 3465-3470 ◽  
Author(s):  
Cédric Theunissen ◽  
Jianjun Wang ◽  
Gwilherm Evano
Keyword(s):  
Alkyl Radicals ◽  
Alkyl Bromides ◽  
Tertiary Alkyl

An efficient and broadly applicable process is reported for the direct alkylation of heteroarene C–H bonds, based on the copper-catalyzed addition of alkyl radicals generated from activated secondary and tertiary alkyl bromides to a range of arenes, and their benzo-fused derivatives.

A Direct Functionalization of Tertiary Alkyl Bromides with O-, N-, and C-Nucleophiles.

ChemInform ◽  
2007 ◽  
Vol 38 (46) ◽  
Author(s):  
Petr Vachal ◽  
Joan M. Fletcher ◽  
William K. Hagmann
Keyword(s):  
Alkyl Bromides ◽  
Direct Functionalization ◽  
Tertiary Alkyl

Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides

Synthesis ◽  
2018 ◽  
Vol 50 (15) ◽  
pp. 2908-2914 ◽  
Author(s):  
Rui Shang ◽  
Yao Fu ◽  
Guang-Zu Wang
Keyword(s):  
Blue Light ◽  
Palladium Catalyst ◽  
Light Emitting Diodes ◽  
Oxidative Addition ◽  
Phosphine Ligands ◽  
Light Emitting ◽  
Alkyl Radicals ◽  
Alkyl Bromides ◽  
Palladium Catalyzed ◽  
Tertiary Alkyl

A palladium catalyst in combination with two types of phosphine ligands efficiently catalyzes direct C–H alkylation of heteroarenes with secondary and tertiary alkyl bromides under irradiation conditions. Irradiation of blue light-emitting diodes (blue LEDs) effectively excites phosphine-ligated palladium catalyst to facilitate oxidative addition with alkyl bromides, and also excites the alkylpalladium species to enable the generation of alkyl radicals to react with heteroarenes.

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