ChemInform Abstract: Tuning Structures and Properties of Coordination Polymers by the Noncoordinating Backbone of Bridging Ligands

ChemInform ◽  
2010 ◽  
Vol 41 (41) ◽  
pp. no-no
Author(s):  
Miao Du ◽  
Xian-He Bu
2015 ◽  
Vol 68 (6) ◽  
pp. 956 ◽  
Author(s):  
Ming-An Dang ◽  
Zi-Feng Li ◽  
Ying Liu ◽  
Gang Li

Three coordination polymers [Sr(p-H2MOPhIDC)2]n (1) (p-H3MOPhIDC = 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid), {[Cd2(p-HMOPhIDC)2(4,4′-bipy)]⋅H2O}n (4,4′-bipy = 4,4′-bipyridine) (2), and [Zn(p-HMOPhIDC)(4,4′-bipy)]n (3) have been solvothermally synthesized, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 indicates a three-dimensional framework, which can be simplified as a 6-connected lattice. Polymer 2 is also a three-dimensional framework, and contains mixed bridging ligands HMOPhIDC2– and 4,4′-bipy. Polymer 3 exhibits a sheet structure bearing infinite rectangles. The coordination modes of the p-H3MOPhIDC ligand, and the thermal and solid-state photoluminescence properties of the polymers have been investigated as well.


CrystEngComm ◽  
2014 ◽  
Vol 16 (11) ◽  
pp. 2144-2157 ◽  
Author(s):  
Liming Fan ◽  
Xiutang Zhang ◽  
Wei Zhang ◽  
Yuanshuai Ding ◽  
Weiliu Fan ◽  
...  

Hydrothermal reactions based on two trifunctional pyridinedicarboxylate carboxylates and transitional metal cations in the presence of three (bis)imidazole bridging ligands afford ten 2D and 3D coordination polymers.


CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7249-7259 ◽  
Author(s):  
Li-Na Zhu ◽  
Zhao-Peng Deng ◽  
Li-Hua Huo ◽  
Shan Gao

The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.


2013 ◽  
Vol 42 (8) ◽  
pp. 2765-2772 ◽  
Author(s):  
Pei-Chi Cheng ◽  
Wei-Cheng Lin ◽  
Feng-Shuen Tseng ◽  
Ching-Che Kao ◽  
Ting-Guang Chang ◽  
...  

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